Methyl ethyl carbinol

ETHYL METHYL CARBINOL (78-92-2) Forms explosive mixture with air (flash point... 

Ethyl-methyl carbinol secondary butyl alcohol—... 

There exist three isomers of phenyl-propyl alcohol, all of which have been prepared and described, and, although not yet introduced into commerce, may eventually be so. These are as follows Benzyl-methyl-carbinol, CgHj. CHj. CH(OH)CHg, boiling at 215° phenyl-ethyl-carbinol, CgHg. CH(OH)CH2. CHg, boiling at 221° and benzyl-dimethyl-carbinol, C Hg. C(OH)(CHg)2, melting at 21° and boiling at 225°. 

Phenyl methyl carbinol Acetophenone or ethyl- R A. K salt, H20 — 124(W) 138... 

ETHYL-5-(l-METHYLBUTYL)-2-THIOBARBITURIC ACID MONOSODIUM see PBT500 ETHYL 2-METHYLBUTYRATE see EMP600 ETHYL METHYLCARBAMATE see EMQ500 ETHYL-N-METHYLCARBAMATE see EMQ500 ETHYLMETHYL CARBINOL see BPW750 ETHYL METHYL CETONE (FRENCH) see MKA400... 

Sodio-2-methylpyrazine with methyl picolinate afforded a mixture containing 2-(pyridin-2 -ylcarbonylmethyl)pyrazine (42.6%) (24) and 2-pyridinylbis(pyrazinyl-methyl)carbinol (22.8%), and with ethyl formate gave only bis(pyrazinylmethyl> carbinol (642). 

Caproic Acetyl methyl carbinol Ethyl butyrate Ethanol... 

Chloromercuri methyl)-ethyl phenyl carbinol, 196. l-Chloromercuriinethyl-6-methyl-l 2-dihydrobenzofurane, 216. 

Ethyl alcohol ethyl hydroxide grain alcohol methyl carbinol. 

Synonyms Ethyl alcohol Grain alcohol Methyl carbinol Ethyl hydrate Cologne spirit EtOH Potato alcohol... 

B.2) (B.2) Ethanol, ethanol, ethyl alcohol, methyl carbinol 64-17-5] FEMA 2419... 

Ethyl hydrate—JBthylic alcohol—Methyl carbinol— Ftnic alcohol—AU cohol—vnne—O H.HO—46. 

Synonyms 2-Ethinylbutanol-2 Ethinylmethylethyl carbinol 3-Ethylbutinol 3-Ethylbutynol Ethyl ethynyl methyl carbinol... 

Acetyl methyl carbinol Benzyl chloride flavoring agent mfg., artificial fruit Ethyl caproate flavoring agent mfg., fruits Propionic acid... 

Acetyl methyl carbinol n-ButyrIc acid 1,4-Dioxane Ethyl acetate Isobutyric acid Isopropyl formate Methyl glycidyl ether Methyl propionate Propyl formate C4H8O2S Sulfolane C4H8O3... 

Carbinol kar-bo- n61, - nol [ISV, fir. obs. Gr Karbin methyl, fir. Gr karb-] (ca. 1885) n. (1) -CH2OH. Monovalent primary alcohol radical. It may be part ofi an aliphatic or an aromatic alcohol. For example, ethyl alcohol (C2H5OH) can be described as methyl carbinol, or benzyl alcohol (C6H5CH2OH) as phenyl carbinol. (2) It is sometimes used as a Syn methanol. 

Ethyl alcohol teihand, methyl carbinol, ethyl hydrate, grain alcohol)... 

The identity of the ethyl-amyl carbinol found in the oil has been settled by the preparation of the same body synthetically. Schimmel Co. heated normal caproic aldehyde with magnesium methyl-iodide, and thus obtained i-ethyl-n-amyl carbinol, which was found to possess characters substantially identical with those of the natural compound. 

Percentage Reduced to Carbinol 35.7, as phenyl methyl carbinol 26, as phenyl ethyl carbinol 43, as benzyl isopropyl carbinol 41, as phenyl n-propyl carbinol... 

Hydroxy-2-propyl)styrene [4-vinylphenyl dimethyl carbinol, a,a-dimethyl(4-vinyl)benzyl alcohol] and 4-(l-hydro ethyl)styrene [4-vinylphenyl methyl carbinol, o>-methyl(4-vinyl)benzyl alcohol] were synthesized according to Scheme IV by reacting 4-vinylphenylmagnesium chloride with acetone and acetaldehyde, respedively, purified by column chromatography, and subjected to radical polymerization with benzoyl peroxide (BPO) or 2,2 -azobis(isobu oni-trile) (AIBN) in tetrahydrofuran (THF) at 60 °C. The monomer 14) and polymer syntheses 15,16) can be found in the literature. In our polymerizations the monomer concentration was kept low (6 mL THF/g monomer) and the conversions were also kept relatively low ( 70 %) to avoid gelation. The unreacted monomers were removed by column chromatography and the polymers were purified by precipitation in water. Simple precipitation procedures alone did not remove the unreacted monomers. 

Fit securely to the lower end of the condenser (as a receiver) a Buchner flask, the side-tube carrying a piece of rubber tubing which falls well below the level of the bench. Steam-distil the ethereal mixture for about 30 minutes discard the distillate, which contains the ether, possibly a trace of unchanged ethyl benzoate, and also any biphenyl, CeHs CgHs, which has been formed. The residue in the flask contains the triphenyl carbinol, which solidifies when the liquid is cooled. Filter this residual product at the pump, wash the triphenyl-carbinol thoroughly with water, drain, and then dry by pressing between several layers of thick drying-paper. Yield of crude dry product, 8 g. The triphenyl-carbinol can be recrystallised from methylated spirit (yield, 6 g.), or, if quite dry, from benzene, and so obtained as colourless crystals, m.p. 162. ... 

Dimethyl ethyl carbinol (2-methy 1-2-butanol or amyl alcohol), CH3CHjCOH(CH3).2. From ethyl propionate and methyl magnesium iodide. Collect the tertiary alcohol at 100-102°. 

Methyl n-ptopyl carbinol (6) Cetyl alcohol (11) Ethyl celloBOlve (16) Butyl carbitol ... 

Toluene reacts with carbon monoxide and butene-1 under pressure in the presence of hydrogen fluoride and boron trifluoride to give 4-methyl-j iYbutyrophenone which is reduced to the carbinol and dehydrated to the olefin. The latter is cycHzed and dehydrogenated over a special alumina-supported catalyst to give pure 2,6- dim ethyl n aph th a1 en e, free from isomers. It is also possible to isomerize various dim ethyl n aph th a1 en es to the... 

Anhydrous stannous chloride, a water-soluble white soHd, is the most economical source of stannous tin and is especially important in redox and plating reactions. Preparation of the anhydrous salt may be by direct reaction of chlorine and molten tin, heating tin in hydrogen chloride gas, or reducing stannic chloride solution with tin metal, followed by dehydration. It is soluble in a number of organic solvents (g/100 g solvent at 23°C) acetone 42.7, ethyl alcohol 54.4, methyl isobutyl carbinol 10.45, isopropyl alcohol 9.61, methyl ethyl ketone 9.43 isoamyl acetate 3.76, diethyl ether 0.49, and mineral spirits 0.03 it is insoluble in petroleum naphtha and xylene (2). 

Methyl ethyl ketone peroxide Methyl formate Methyl iodide Methyl isoamyl acetate Methyl isobutyl carbinol Methyl isobutyl ketone (hexone)... 

---