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Ethanol overview

Lussier [71] has given an overview of Uniroyal Chemical s approach to the analysis of compounded elastomers (Scheme 2.2). Uncured compounds are first extracted with ethanol to remove oils for subsequent analysis, whereas cured compounds are best extracted with ETA (ethanol/toluene azeotrope). Uncured compounds are then dissolved in a low-boiling solvent (chloroform, toluene), and filler and CB are removed by filtration. When the compound is cured, extended treatment in o-dichlorobenzene (ODCB) (b.p. 180 °C) will usually suffice to dissolve enough polymer to allow its separation from filler and CB via hot filtration. Polymer identification was based on IR spectroscopy (key role), CB analysis followed ASTM D 297, filler analysis (after direct ashing at 550-600 °C in air) by means of IR, AAS and XRD. Antioxidant analysis proceeded by IR examination of the nonpolymer ethanol or ETA organic extracts. For unknown AO systems (preparative) TLC was used with IR, NMR or MS identification. Alternatively GC-MS was applied directly to the preparative TLC eluent. [Pg.36]

Chapter one is an overview of the energy evolution. It introduces the technology and emission issues, safety, and alternative fuels such as natural gas, hydrogen gas, methanol, ethanol and fuel cell power. [Pg.8]

Practically all available iodinated extracellular X-ray contrast agents have been encapsulated into liposomes using different lipids and methods of preparation. Table 1 gives a short and intentionally incomplete overview of some of the approaches. The first liposomal contrast agent preparation that was tested in humans contained diatrizoate [48]. The injected dose was up to 0.5 ml kg k The preparation was effective even in plain radiography where lesions down to 0.8-1.0 cm could be detected in patients. However, adverse events such as fever and hyperthermia, which occurred in 30% of the patients, limited further use. We have incorporated iopromide into MLVs that were prepared from phosphatidyl choline (PC), cholesterol and stearic acid at a molar ratio of 4 5 1 using the ethanol-evaporation technique [44]. The liposomes can be stored freeze-dried and they are reconstituted before use by... [Pg.182]

Isolation and Assays of Enzymes or Substances Resulting in Formation or Removal of Oxygen Radicals Biological sources of Of, 105, 59 overview of superoxygenase, 105, 61 methods for the study of superoxide chemistry in nonaqueous solutions, 105, 71 generation of superoxide radicals in aqueous and ethanolic solutions by vacuum-UV photolysis, 105, 81. [Pg.535]

The fifth paper, "A Separative Bioreactor Direct Product Capture and pH Control," presented by Seth Snyder of the Argonne National Laboratory, reviewed development and performance of a novel bioreactor incorporating electrodeionization to simultaneously produce and separate products from both enzymatic and microbially mediated reactions. The sixth paper, " Optimization of Xylose Fermentation in Spent Sulfite Liquor by Saccharomyces cerevisiae 259ST," presented by Steven Helle of the University of British Columbia, provided an overview of an approach to fermentation optimization utilized to identify key process variables limiting use of the SSL for commercial ethanol production. [Pg.450]

In the current context, we will use the term alcohol not in its chemical sense in which there are many different alcohols with various (often poorly investigated) metabolic fates. This overview will be confined to the variable elements of ethanol metabolism. [Pg.234]

Rare earth /3-diketonate complexes usually are synthesized using the RE chloride and ammonium or sodium /S-diketonate in water or ethanol solvent. Rare earth chlorides are preferred over nitrate or acetates due to the lower coordination power of chloride anion. Binnemans, Mehrotra, Thompson , Joshi and Manas give an overview of the synthesis of rare earth ion complexes with /S-diketonate ligands including different RE +-(1,3-diketonate) coordination compounds. [Pg.136]

Kirchner s book 1127 gave an overview on the TLC of antihistamines, and Boonen 1128] also dealt with the separation of various antihistamines using plain silica and a mixture of ethanol/acetic acid/water (5 3 2). Recent experiments used metal ion impregnated silica layers to improve the separation of antihistamines 1129-1311. Antihistamines are easily visualised by iodine vapour. Separation of seven antihistamines on plain silica as well as metal ion impregnated silica with a benzene/butanol/acetic acid/water (7 8 5 2) mixture is shown in Table 10.18. Metal ion impregnation improved the separation of these antihistamines, especially when two or more stationary phases were used for parallel separations. [Pg.499]

Additionally, in a survey overview on the effectiveness of handwashing and hand disinfection for the removal of nosocomial pathogens from heavily contaminated hands, 0.5% CHG in 70% isopropanol was most effective, followed by 70% ethanol and, to a lesser extent, 40% isopropanol [5], Comparison of the efficacy of 62% ethanol, 70% isopropanol, and benzylalkonium chloride-based hand sanitizers using the healthcare personnel handwash protocol indicated that all three had equivalent efficacy at greater than 2-log reduction after the first wash, whereas the benzylalkonium chloride hand sanitizer demonstrated residual efficacy. [Pg.127]

Figure 7.1. Overview of the biochemical routes leading to glycerol, pyruvate, and ethanol. Furthermore, valine biosynthesis and diacetyl formation are shown, which may be bypassed by introduction of a heterologous a-acetolactate decarboxylase that directly converts a-acetolactate to acetoin. GPDl and GPD2, glycerol dehydrogenases 1 and 2 ADHl, alcohol dehydrogenase 1 ILV2, acetolactate synthetase ID/5, acetolactate reductoisomerase [Refs in 502]. Figure 7.1. Overview of the biochemical routes leading to glycerol, pyruvate, and ethanol. Furthermore, valine biosynthesis and diacetyl formation are shown, which may be bypassed by introduction of a heterologous a-acetolactate decarboxylase that directly converts a-acetolactate to acetoin. GPDl and GPD2, glycerol dehydrogenases 1 and 2 ADHl, alcohol dehydrogenase 1 ILV2, acetolactate synthetase ID/5, acetolactate reductoisomerase [Refs in 502].
Lynd, L.R. (1996) Overview and evaluation of fuel ethanol from cellulosic biomass technology, economics, the... [Pg.388]

The use of renewable feedstocks (i.e., biomass) in the production of fuels and value-added chemicals has attracted major interest from researchers and governments because of the anticipated shortages of traditional petrochemical industrial feedstocks [199]. An excellent overview of the milestones relating to the use of bioderived alcohols in the synthesis of higher value chemicals was recently presented by Hutchings et al. [200]. In this area as well, particle size effects can be identified yet care must be taken, as illustrated by a recent paper by Simakova et al. [201], which showed a bimodal Au particle size effect in the catalytic activity of Au-TiOj system in the gas-phase oxidation of ethanol. [Pg.271]


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See also in sourсe #XX -- [ Pg.401 , Pg.402 ]

See also in sourсe #XX -- [ Pg.401 , Pg.402 ]




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