Anions chlorides

I could be improved, including the need to incorporate water molecules and use a appropriate representation of the chloride anion. 

In the strongly basic medium, the reactant is the phenoxide ion high nucleophilic activity at the ortho and para positions is provided through the electromeric shifts indicated. The above scheme indicates theorpara substitution is similar. The intermediate o-hydroxybenzal chloride anion (I) may react either with a hydroxide ion or with water to give the anion of salicyl-aldehyde (II), or with phenoxide ion or with phenol to give the anion of the diphenylacetal of salicylaldehyde (III). Both these anions are stable in basic solution. Upon acidification (III) is hydrolysed to salicylaldehyde and phenol this probably accounts for the recovery of much unreacted phenol from the reaction. 

Silyl ethers serve as preeursors of nucleophiles and liberate a nucleophilic alkoxide by desilylation with a chloride anion generated from CCI4 under the reaction conditions described before[124]. Rapid intramolecular stereoselective reaction of an alcohol with a vinyloxirane has been observed in dichloro-methane when an alkoxide is generated by desilylation of the silyl ether 340 with TBAF. The cis- and tru/u-pyranopyran systems 341 and 342 can be prepared selectively from the trans- and c/.y-epoxides 340, respectively. The reaction is applicable to the preparation of 1,2-diol systems[209]. The method is useful for the enantioselective synthesis of the AB ring fragment of gambier-toxin[210]. Similarly, tributyltin alkoxides as nucleophiles are used for the preparation of allyl alkyl ethers[211]. 

Transfer of an electron from a sodium atom to a chlorine atom yields a sodium cation and a chloride anion both of which have a noble gas electron configuration... 

FIGURE 4 11 Combi nation of tert butyl cation and chloride anion to give tert butyl chloride In phase overlap between a vacant p orbital of (CHbIbC and a filled p orbital of Cr gives a C—Cl (T bond... 

The crystal structure of the adduct of titanium tetrachloride and the ester formed from ethyl 2-hydroxypropanoate (ethyl lactate) and acrylic acid has been solved. It is a chelated structure with the oxygen donor atoms being incorporated into the titanium coordination sphere along with the four chloride anions. 

FIGURE 4.10 Potential energy diagram for reaction of fert-butyl cation with chloride anion. 

In all chemical reactions, the reacting atoms or molecules pass through a state that is intermediate in structure between the reactant(s) and the product(s). Consider the transfer of a proton from a water molecule to a chloride anion ... 

In the middle structure, the proton undergoing transfer is shared equally by the hydroxyl and chloride anions. This structure represents, as nearly as possible, the transition between the reactants and products, and it is known as the transition state. ... 

Electrostatic potential map for i-phenyl-l-ethyl cation-chloride anion shows negatively-charged regions (in red) and positi vely-charged regions (in blue). 

Next, examine the structure of 1-phenyl-1-ethyl cation-chloride anion, an ion pair that is initially generated. What evidence is there for cai bon-chlorine bond cleavage Examine the electrostatic potential map for the ion pair. Which face of the cation is more available for attack How could the other enantiomer form ... 

The actual formylation process is preceded by the formation of dichlorocarbene 3 as the reactive species. In strongly alkaline solution, the chloroform is deproto-nated the resulting trichloromethide anion decomposes into dichlorocarbene and a chloride anion ... 

Dehydration of prednisolone acetate (175b) yields the corresponding 9,11 olefin. As a variation on the chemistry we have seen previously, this olefin is allowed to react with chlorine in the presence of lithium chloride. If this addition is assumed to proceed by the customary mechanism, the first intermediate should be the 9a,11a-chioronium ion. Axial attack by chloride anion from the 110 position will lead to the observed stereochemistry of the product dichlorisone (240). ... 

The purity of ionic liquids is a key parameter, especially when they are used as solvents for transition metal complexes (see Section 5.2). The presence of impurities arising from their mode of preparation can change their physical and chemical properties. Even trace amounts of impurities (e.g., Lewis bases, water, chloride anion) can poison the active catalyst, due to its generally low concentration in the solvent. The control of ionic liquid quality is thus of utmost importance. 

The ether-forming step is an S -like reaction of the alkoxide ion on the silicon atom, with concurrent loss of the leaving chloride anion. Unlike most Sn2 reactions, though, this reaction takes place at a tertiary center—a trialJkyl-substituted silicon atom. The reaction occurs because silicon, a third-row atom, is larger than carbon and forms longer bonds. The three methyl substituents attached to silicon thus offer less steric hindrance to reaction than they do in the analogous ferf-butyl chloride. 

This last design (chloride anion exchange) is very often specified when some form of dealkalization plant is under consideration. Selection usually is made on the grounds of operator safety and reduced risk of boiler corrosion. Although it may have the attraction of not creating any potential for acid handling or acid introduction into the FW line or not requiring a deaerator, these are mere diversions. 

The film-destructive anions are CF, T, CIO4, SO4, etc. for iron electrodes and in addition to these ions, NOJ, SCN , etc. for aluminum electrodes.19 In many cases, the film-destructive anions are the anions of strong acids the most well-known and studied anion is the chloride anion. 

This study includes an extended evaluation of the catalytic effect of chloride anions. 

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