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Epoxy resins cured with isocyanates

Casting Oxazolidone Resin Films. To explore further the structural property relationships in epoxy resins cured with isocyanate, a series of films were cast, and then IR absorption spectra and softening behaviour examined. [Pg.269]

Ho et al (1996) examined polyol or polysiloxane thermoplastic polyurethanes (TPUs) as modifiers in cresol-formaldehye novolac epoxy resins cured with phenolic novolac resin for computer-chip encapsulation. A stable sea-island dispersion of TPU particles was achieved by the epoxy ring-opening with isocyanate groups of the urethane prepolymer to form an oxazolidone. The flexural modulus was reduced by addition of TPU and also the Tg was increased due to the rigid oxazolidone structure. Mayadunne et al (1999) extended this work to a series of phenol- and naphthol-based aralkyl epoxy resins. [Pg.365]

Isocyanates. Whereas polyamines and thiols cure epoxy compounds via their epoxy groups, isocyanates cross-link high molecular mass epoxy resins via their hydroxyl groups to form polyurethanes. The reaction takes place at ambient temperature. These combinations cure more rapidly and at lower temperature than epoxy resins cured with polyamines. [Pg.72]

Nonetheless, for the more than 50 years since the first publication in this field, NIPUs still do not have sufficiently broad application. This can be explained by certain features of these materials. Cyclic carbonate (CC) groups interact with aliphatic and cycloaliphatic polyamines at ambient temperatures more slowly than isocyanates with hydroxyl groups. The rate of this reaction is comparable to the rate of curing epoxy resins (ER) with amines. At the same time, the CCs react only with primary amino groups, in contrast to the ERs, which react with primary and with secondary amino groups. This results in a decrease in cross-linking density of the polymer network. [Pg.152]

More recent efforts have focused on developments that create true hybrids. For example, blocked isocyanate prepolymers have been mixed with epoxy resins and cured with amines [68-70]. These blocked prepolymers will react initially with the amines to form amine-terminated prepolymers that cross-link the epoxy resin. Several blocked isocyanates are commercially available. The DESMOCAP (Bayer) llA and 12A products are isocyanates (believed to be blocked with nonylphenol) used as flexibilizing agents for epoxy resins. ANCAREZ (trademark. Pacific Anchor, Inc.) 2150 is a blocked isocyanate epoxy blend used as an adhesion promoter for vinyl plastisols. A one-package, heat-cured hybrid adhesive was reported consisting of isophorone diisocyanate, epoxy resin, and a dispersed solid curative based on the salt of ethylenediamine and bisphenol A [71]. Urethane amines are offered commercially that can be used with epoxy resins to develop hybrid adhesive systems [72]. [Pg.708]

The GMA clear coatings have outstanding exterior durability, hence their acceptance in the automotive sector (see Fig. 2). Pigmented GMA acrylic powders have not foimd widespread use in market areas other than automotive, eg, architectural applications. Hydroxyl functional acrylic resins cured with blocked isocyanates or uretdione-based curatives have also found use in automotive applications and their exterior durability is only somewhat less than that of the GMA acrylic powders (50). Carboxyl functional acrylic resins are also commercially available. They can be cured with TGIC for exterior applications or with bisphenol A epoxy resins. The latter combinations are sometimes called acrylic-epoxy hybrid coating powders and are noted for their excellent hardness, stain, and chemical resistance. They find use primarily in appliance coatings (79). [Pg.1355]

The traditional crosslinking technologies utilized in the coatings market range from hydroxyl functional binders—acrylics or poly(esters)—crosslinked with melamines (IK) or isocyanates (2K) to drying oils that cure through oxidation of the unsaturated bonds, to epoxy resins crosslinked with amino resins (amido amines, amines, etc.). [Pg.265]

Reaction with isocyanates also provides a route to carbamates, which serve as masked amines (eq 8) or as diamines for epoxy resin curing. Carbamates of o-NBA possess moderate antitumor activity. ... [Pg.288]

Curing an epoxy resin by reaction with an isocyanate... [Pg.679]

Shih et al. [60] studied the modification of a novolac-type epoxy resin with PDMS to overcome brittleness and poor impact resistance. This kind of resin is typically cured via their epoxy functions. The authors also introduced isocyanate monofunctionalized PDMS. Hence, the common treatment with MDA (4,4 -methylene dianiline) not only cured the resin on the one hand, but also made it possible to form the branched copolymer. Mechanical and thermal analyses showed that an optimum in isocyanate-terminated PDMS content was required to reach good thermal and physical properties and low moisture absorption. [Pg.126]

Epoxy-urethane adhesives provide properties when cured that are similar to those of epoxynylon adhesives except they offer a major improvement in moisture resistance. Isocyanate monomers and prepolymer react with the hydroxyl groups on epoxy resins to give tough,... [Pg.131]

Blocked isocyanate prepolymers have been mixed with epoxy resins and cured with amines.18,19 These blocked prepolymers will initially react with the amines to form amine-terminated prepolymers that crosslink the epoxy resin. Urethane amines are also offered commercially for use with epoxy resins to develop hybrid adhesive systems.20... [Pg.133]

Adhesives which are meant to cure at temperatures of 120 or 171°C require curatives which are latent at room temperature, but react quickly at the cure temperatures. Dicyanodiamide [461-58-5], (TH INI is one such latent curative for epoxy resins. It is insoluble in the epoxy at room temperature but rapidly solubilizes at elevated temperatures. Other latent curatives for 171°C are complexes of imidazoles with transition metals, complexes of Lewis acids (eg, boron trifluoride and amines), and diaminodiphenylsulfone, which is also used as a curing agent in high performance composites. For materials which cure at lower temperatures (120°C), these curing agents can be made more soluble by alkylation of dicyanodiamide. Other materials providing latency at room temperature but rapid cure at 120°C are the blocked isocyanates, such as the reaction products of toluene diisocyanate and amines. At 120°C the blocked isocyanate decomposes to regenerate the isocyanate and liberate an amine which can initiate polymerization of the epoxy resin. Materials such as Monuron can also be used to accelerate the cure of dicyanodiamide so that it takes place at 120°C. [Pg.232]

The application of microwave irradiation to cure isocyanate/epoxy resins in the presence of N-(2-hydroxyalkyl)trialkylammonium halides was claimed to impart accelerations to both curing and post-curing kinetics with respect to conventional hot-air heating [122]. More recently, Parodi et al. presented further development of new class of catalysts that endow aromatic isocyanate/epoxy and aliphatic or cycloaliphatic epoxy/anhydride systems with a particular efficiency for microwave processability [123]. The catalysts belong to the family of N-(cyano-alkoxy-alkyl)trialkylammonium halides, of the general formula ... [Pg.247]

These are two-pack cold-cure coatings and can be a blend of acrylic and epoxy resins for use with ferrous and non-ferrous metals as well as plastics. Designed to be applied by spraying to suitably pre-treated surfaces they are available as an isocyanate-free alternative to two-pack polyurethane systems. [Pg.231]


See other pages where Epoxy resins cured with isocyanates is mentioned: [Pg.394]    [Pg.251]    [Pg.344]    [Pg.251]    [Pg.1363]    [Pg.232]    [Pg.450]    [Pg.105]    [Pg.119]    [Pg.121]    [Pg.13]    [Pg.70]    [Pg.450]    [Pg.132]    [Pg.232]    [Pg.384]    [Pg.323]    [Pg.695]    [Pg.532]    [Pg.916]    [Pg.223]    [Pg.569]    [Pg.35]    [Pg.306]    [Pg.77]    [Pg.103]    [Pg.741]    [Pg.37]    [Pg.38]    [Pg.215]    [Pg.142]    [Pg.231]    [Pg.282]    [Pg.134]   
See also in sourсe #XX -- [ Pg.266 ]




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Cured epoxy resins

Curing epoxy

Epoxy cured

Isocyanates, curing

Resins curing

Resins, cure

With isocyanates

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