Electron dose, maximum

Increase the maximum electron dose that the specimen can withstand ... 

DEPTH PROFILE. The secondary electrons produced by ionization processes from an incident beam of high-energy electrons are randomly directed in space. Spatial "equilibrium" is achieved only after a minimum distance from the surface of a polymer in contact with a vacuum or gaseous environment (of much lower density). Consequently, the absorbed radiation dose increases to a maximum at a distance from the surface (2 mm for 1 MeV electrons) which depends on the energy of the electrons. The energy deposition then decreases towards zero at a limiting penetration depth. 

It is intriguing that analysis of the volcano curve predicts that the apex of the curve occurs at AH(H2)ads = 0 (formally, AG = 0) [26]. This value corresponds to the condition D(M-H) = 1/2D(H-H), that is, forming an M-H bond has the same energetic probability as forming an H2 molecule. This condition is that expressed qualitatively by the Sabatier principle of catalysis and corresponds to the situation of maximum electrocatalytic activity. Interestingly, the experimental picture shows that the group of precious transition metals lies dose to the apex of the curve, with Pt in a dominant position. It is a fact that Pt is the best catalyst for electrochemical H2 evolution however, its use is made impractical by its cost. On the other hand, Pt is the best electrocatalyst on the basis of electronic factors only, other conditions being the same. 

For example, when the mixed solution of Ag(CN)2 and Au(CN)2 is irradiated by y-radiolysis at increasing dose, the spectrum of pure silver clusters is observed first at 400 nm, because Ag is more noble than Au due to the CN ligand. Then, the spectrum is red-shifted to 500 nm when gold is reduced at the surface of silver clusters in a bilayered structure [102], as when the cluster is formed in a two-step operation [168] (Table 5). However, when the same system is irradiated at a high dose rate with an electron beam, allowing the sudden (out of redox thermodynamics equilibrium) and complete reduction of all the ions prior to the metal displacement, the band maximum of the alloyed clusters is at 420 nm [102]. 

Similarly, at moderate dose rate for the couple Au Cl4, Ag, gold initially appears at 520 nm. Therefore, Ag ions essentially act as an electron scavenger, and as an electron relay toward more noble gold ions as far as gold ions are not totally reduced. Then silver-coated gold clusters are formed and the maximum is shifted to 400 nm, which is that of silver (Fig. 11) [102]. But at higher y- or EB dose rate (irradiation time of a few seconds), the electron transfer is too slow to compete with coalescence and the spectrum of alloyed clusters... 

The dose distribution in the materials is given as a depth-dose curve. An example of the curve is illustrated in Fig. 4 obtained with the irradiation of electron from 0.5 to 1.0 MeV using cellulose triacetate (CTA) film dosimeter [12]. The existence of the maximum dose is an important characteristic of the depth-dose curve. Irradiation from two opposite sides by using two accelerators was proposed in order to give better uniformity in water [13]. The uniform irradiation is also important for flue gas treatment. Better efficiency of NO removal was proved with both-side irradiation by using three accelerators for coal-fired flue gas than single-side irradiation at the same dose [14]. 

The prevulcanization of natural rubber in latex form has also been a subject of much investigation. The cross-linking mechanism is not yet fully understood, but the water apparently plays a major role in it. Irradiation results in the cross-linking of the rubber molecules and in coarsening of the latex particles. A process of cross-linking of natural rubber latex has been developed to the point that it can be used for an industrial-scale application. The irradiation is performed in aqueous media by electron beam without a prorad (sensitizer) at a dose of 200 kGy (20 Mrad) or in the presence of n-butyl acrylate at considerably lower doses, typically 15 kGy. The cross-linked film exhibits physical properties comparable to those obtained from sulfur cured (vulcanized) film. As an alternative, the addition of a variety of chloroal-kanes makes it possible to achieve a maximum tensile strength with radiation doses of less than 5 Mrad (50 kGy). ... 

Process parameters involve line speed if dose rate and line speed are combined, the dose delivered to the product to be cured can be calculated. A processor-specific yield factor depends on the relationship between the beam current and line speed. The dose-speed capacity of a processor is given by the product of the line speed and the delivered dose at maximum electron beam power.27... 

Absolute dosimetry with the electron accelerator is less accurate than with the cobalt-60 source since penetration of the electron is a variable— directly proportional to the energy of the beam and inversely proportional to the density of the material. The absorbed dose varies with depth (18) and is about 60% of maximum at the surface with a steady increase to a maximum at about one-third of the total penetration depth. At about two-thirds of the total penetration, the dose is equivalent to that absorbed at the surface. Therefore, if all parts of the sample are to receive the same minimum dose, the useful penetration is approximately two-thirds of the total, or about 0.33 gram per square centimeter per m.e.v. 

Figure 15.19 shows the relationship between the percentage of height decrease (A) calculated from surface profile measurements and the electron beam dose for both fluorinated and nonfluorinated polyimides. The surface profile between the irradiated and nonirradiated areas was measured. The film shrinks because of electron beam irradiation, and the maximum shrinkage reaches up to 0.4% at the film surface. 

K. They noted a decay over timescales 95 and < 35 ns, respectively, which was attributed to geminate ion-pair recombination (see Fig. 33). The decay of the optical absorption is independent of the dose of radiation received and continues for about lps. Rather than displaying a dependence on time as eqn. (153), i.e. at f 3/2, the experimental results are more nearly represented by either at f 1 decay to an optical density about one tenth of the maximum or by a decay as t 1/2 to zero absorption. These effects may be the recombination of ions within a spur (or cluster of ion-pairs), which is more nearly like a homogeneous reaction. The range of electrons in propane at 100 K is 10 nm [334] and the extrapolated diffusion coefficient is 10 11 m2 s 1 [320]. The timescale of recombination is 10 ps. The locally greater concentration of ions within a spur probably leads to a faster rate of reaction and is consistent with the time-scale of the reaction observed. Baxendale et al. [395] observed the decay of the infrared optical absorption of the solvated electron in methylcyclo-hexane at 160 K. They noted that the faster decay occurring over < 50 ns was independent of dose and depended on time as t 1/2, i.e. the reaction rate decays as t 3/2, see eqn. (153). It was attributed to recombination of... 

The MEBRF can be operated over a range of flow rates from 60 to 160 gpm. The maximum absorbed dose delivered by the electron beam depends on the flow rate an application requiring a dose of 1290 krad would limit... 

Microsomal reduction of chromium(VI) can also result in the formation of chromium(V), which involves a one-electron transfer from the microsomal electron-transport cytochrome P450 system in rats. The chromium(V) complexes are characterized as labile and reactive. These chromium(V) intermediates persist for 1 hour in vitro, making them likely to interact with deoxyribonucleic acid (DNA), which may eventually lead to cancer (Jennette 1982). Because chromium(V) complexes are labile and reactive, detection of chromium(V) after in vivo exposure to chromium(VI) was difficult in the past. More recently, Liu et al. (1994) have demonstrated that chromium(V) is formed in vivo by using low-frequency electron paramagnetic resonance (EPR) spectroscopy on whole mice. In mice injected with sodium dichromate(VI) intravenously into the tail vein, maximum levels of chromium(V) were detected within 10 minutes and declined slowly with a life time of about 37 minutes. The time to reach peak in vivo levels of chromium(V) decreased in a linear manner as the administered dose levels of sodium... 

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