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E-lycopene

Clearly, the control of gene expression at the transcriptional level is a key regulatory mechanism controlling carotenogenesis in vivo. However, post-transcriptional regulation of carotenoid biosynthesis enzymes has been found in chromoplasts of the daffodil. The enzymes phytoene synthase (PSY) and phytoene desaturase (PDS) are inactive in the soluble fraction of the plastid, but are active when membrane-bound (Al-Babili et al, 1996 Schledz et al, 1996). The presence of inactive proteins indicates that a post-translational regulation mechanism is present and is linked to the redox state of the membrane-bound electron acceptors. In addition, substrate specificity of the P- and e-lycopene cyclases may control the proportions of the p, P and P, e carotenoids in plants (Cunningham et al, 1996). [Pg.266]

CUNNINGHAM F X Jr, POGSON B, SUN Z, MCDONALD K A, DELLAPENNA D and GANTT E (1996) Functional analysis of the (3 and e lycopene cyclase enzymes of Arabidopsis reveals a mechanism for control of cyclic carotenoid formation . Plant Cell, 8, 1613-26. [Pg.275]

Breitenbach, J., Vioque, A., and Sandmann, G., Gene sll0033 from Synechocystis 6803 encodes a carotene isomerase involved in the biosynthesis of aU-E lycopene,... [Pg.393]

Diet Increased risk associated with high-meat and high-fat diets. Decreased intake of 1, 25-dihydroxyvitamin D, vitamin E, lycopene, and /Tcarotene increases risk. [Pg.1358]

Other agents, including selenium, vitamin E, lycopene, green tea, nonsteriodal anti-inflammatory agents, isoflavones, and statins, are under investigsation for prostate cancer and show promise. Selenium is a naturally occurring trace element that is an essential nutrient in the human diet.8 However, none of these agents is currently recommended for routine use outside a clinical trial. [Pg.1359]

Figure 4.7 shows the structures of important carotenoids (all-E) lutein, (all-E) zeaxanthin, (all-E) canthaxanthin, (all-E) p-carotene, and (all-E) lycopene. Employing a self-packed C30 capillary column, the carotenoids can be separated with a solvent gradient of acetone water=80 20 (v/v) to 99 1 (v/v) and a flow rate of 5 pL min, as shown in Figure 4.8 (Putzbach et al. 2005). The more polar carotenoids (all-E) lutein, (all-E) zeaxanthin, and (all-E) canthaxanthin elute first followed by the less polar (all-E) p-carotene and the nonpolar (all-E) lycopene. Figure 4.9 shows the stopped-flow II NMR spectra of these five carotenoids. The chromatographic run was stopped when the peak maximum of the compound of interest reached the NMR probe detection volume. Figure 4.7 shows the structures of important carotenoids (all-E) lutein, (all-E) zeaxanthin, (all-E) canthaxanthin, (all-E) p-carotene, and (all-E) lycopene. Employing a self-packed C30 capillary column, the carotenoids can be separated with a solvent gradient of acetone water=80 20 (v/v) to 99 1 (v/v) and a flow rate of 5 pL min, as shown in Figure 4.8 (Putzbach et al. 2005). The more polar carotenoids (all-E) lutein, (all-E) zeaxanthin, and (all-E) canthaxanthin elute first followed by the less polar (all-E) p-carotene and the nonpolar (all-E) lycopene. Figure 4.9 shows the stopped-flow II NMR spectra of these five carotenoids. The chromatographic run was stopped when the peak maximum of the compound of interest reached the NMR probe detection volume.
FIGURE 4.7 Structures of important carotenoids (all-E) lutein, (all-/ ) zeaxanthin, (all-E) canthaxanthin, (all-E) P-carotene, and (all-E) lycopene. [Pg.65]

Kanasawud and Crouzet have studied the mechanism for formation of volatile compounds by thermal degradation of p-carotene and lycopene in aqueous medium (Kanasawud and Crouzet 1990a,b). Such a model system is considered by the authors to be representative of the conditions found during the treatment of vegetable products. In the case of lycopene, two of the compounds identified, 2-methyl-2-hepten-6-one and citral, have already been found in the volatile fraction of tomato and tomato products. New compounds have been identified 5-hexen-2-one, hexane-2,5-dione, and 6-methyl-3,5-heptadien-2-one, possibly formed from transient pseudoionone and geranyl acetate. According to the kinetics of their formation, the authors concluded that most of these products are formed mainly from all-(E) -lycopene and not (Z)-isomers of lycopene, which are also found as minor products in the reaction mixture. [Pg.225]

Figure 73. The carotenoid biosynthetic pathway. Enzymes are named according to the designation of their genes Ccs, capsanthin-capsorubin synthase CrtL-b, lycopene-b-cyclase CrtL-e, lycopene-e-cyclase CrtR-b, b-ring hydroxylase, CrtR-e, e-ring hydroxylase DMADP, dimethylallyl diphosphate GGDP, geranylgeranyl diphosphate Ggps, geranylgeranyl-diphosphate synthase IDP, isopentenyl diphosphate Ipi, IDP isomerase Pds, phytoene desaturase Psy, phytoene synthase Vde, violaxanthin de-epoxidase Zds, z-carotene desaturase Zep, zeaxanthin epoxidase. (From van den Berg and others 2000.)... Figure 73. The carotenoid biosynthetic pathway. Enzymes are named according to the designation of their genes Ccs, capsanthin-capsorubin synthase CrtL-b, lycopene-b-cyclase CrtL-e, lycopene-e-cyclase CrtR-b, b-ring hydroxylase, CrtR-e, e-ring hydroxylase DMADP, dimethylallyl diphosphate GGDP, geranylgeranyl diphosphate Ggps, geranylgeranyl-diphosphate synthase IDP, isopentenyl diphosphate Ipi, IDP isomerase Pds, phytoene desaturase Psy, phytoene synthase Vde, violaxanthin de-epoxidase Zds, z-carotene desaturase Zep, zeaxanthin epoxidase. (From van den Berg and others 2000.)...
The main peak at 35 min belongs to all-E lycopene (82%, peak 6). Furthermore, peak 1 can be assigned to all-E (3-carotene, whereas peaks 2-5 belong to various Z and ZZ lycopene stereoisomers, as summarised in Table 5.2.1. Thereby, the peak assignment can be proven by recording stopped-flow LC-NMR spectra as shown in Figures 5.2.5 and 5.2.6 (see below). [Pg.132]

The acquisition of a two-dimensional (2D) NMR spectrum gives the advantage of obtaining information about both the chemical shifts values 8 and the coupling system of each proton (the 2D plot allows us to establish the assignments of such coupling systems). Figure 5.2.5 depicts the stopped-flow 2D COSY NMR spectrum of all-E lycopene from a tomato extract. This was recorded within 24 h with a total of 280 increments and 256 transients. [Pg.135]

Figure 5.2.5 Stopped-flow COSY NMR spectrum of all-E lycopene from a tomato peel extract... Figure 5.2.5 Stopped-flow COSY NMR spectrum of all-E lycopene from a tomato peel extract...
Lycopene is a red pigment found in tomatoes, watermelon, papaya, guava, and pink grapefruit. An antioxidant like vitamin E, lycopene contains many conjugated double bonds—double bonds separated by only one single bond—that allow jt electron density to delocalize and give the molecule added stability. In Chapter 16 we learn about such conjugated unsaturated systems. [Pg.570]

Z-isomers con tribute up to about 50% of total plasma lycopene content [16, 20]. Schierle et al. [8] and others [26] found the 5-Z-isomer to be the next most abundant form after all-E-lycopene (Fig. 3). It should be noted that some analytical methods are unable to resolve the 5-Z- and all-E-lycopene isomers because of congruency in the UV/ Vis spectra (e.g., from photo-diode array detection) used for identification (Fig. 3, insert). 13-Z-, 15-Z-, and 9-Z-Lycopene isomers are also detectable in human plasma at low concentrations, typically less than 5% of the all-E compound. [Pg.259]

Figure 3 Pattern of lycopene isomers in a human blood sample. (Insert) Photo-diode array detection spectra of all-E-lycopene and 5-Z-lycopene. (From Ref. 8.)... Figure 3 Pattern of lycopene isomers in a human blood sample. (Insert) Photo-diode array detection spectra of all-E-lycopene and 5-Z-lycopene. (From Ref. 8.)...
Fig. 5.3 Carotenoid biosynthesis in maize endosperm. Compounds IPP, isopentenyl pyrophosphate FPP, famesyl pyrophosphate GGPP, geranylgeranyl pyrophosphate DMAPP, dimethallyl pyrophosphate. Carotenoid biosynthetic pathway enzymes PSY, phytoene synthase PDS, phytoene desaturase ZDS, zetacarotene desaturase ISO, carotene isomerase LCY-B, lycopene beta cyclase LCY-E, lycopene epsilon cyclase HYD-B, beta-carotene hydroxylase HYD-E, alpha-carotene hydroxylase Isonrenoid biosynthetic pathway enzymes IPPI (IPP isomerase) GGPPS (GGPP synthase). Structures are not representative of the geometrical isomer substrates (e.g. Z-phytoene is a bent structure). Fig. 5.3 Carotenoid biosynthesis in maize endosperm. Compounds IPP, isopentenyl pyrophosphate FPP, famesyl pyrophosphate GGPP, geranylgeranyl pyrophosphate DMAPP, dimethallyl pyrophosphate. Carotenoid biosynthetic pathway enzymes PSY, phytoene synthase PDS, phytoene desaturase ZDS, zetacarotene desaturase ISO, carotene isomerase LCY-B, lycopene beta cyclase LCY-E, lycopene epsilon cyclase HYD-B, beta-carotene hydroxylase HYD-E, alpha-carotene hydroxylase Isonrenoid biosynthetic pathway enzymes IPPI (IPP isomerase) GGPPS (GGPP synthase). Structures are not representative of the geometrical isomer substrates (e.g. Z-phytoene is a bent structure).
CUNNINGHAM JR., F. X., POGSON, B., SUN, Z., MCDONALD, K. A., DELLAPENNA, D., GANTT, E., Functional analysis of the P and E lycopene cyclase enzjmies of Arahidopsis reveals a mechanism for control of cyclic carotenoid formation. Plant Cell 1996,8,1613-1626. [Pg.109]

CY-E (Lycopene s-cyclase) LCY-B/CYC-B (Lycopene -cyclase) i LOY-B/OYC-B(Lyccpenep-Q,da ) rCaro< < xl/LCY CYCB (Lycopene p[Pg.2859]


See other pages where E-lycopene is mentioned: [Pg.274]    [Pg.186]    [Pg.66]    [Pg.66]    [Pg.67]    [Pg.192]    [Pg.137]    [Pg.138]    [Pg.256]    [Pg.2854]    [Pg.3887]    [Pg.457]   
See also in sourсe #XX -- [ Pg.492 ]




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