Cracking catalysts catalyst characterization

Zeolites as cracking catalysts are characterized hy higher activity and better selectivity toward middle distillates than amorphous silica-alumina catalysts. This is attrihuted to a greater acid sites density and a higher adsorption power for the reactants on the catalyst surface. 

Cracking catalysts are members of a broad class characterized by diameters of 30-150 im, density of 1.5 g/mL or so, appreciable expansion of the bed before fluidization sets In, minimum bubbling velocity greater than minimum fluidizing velocity, and rapid disengagement of bubbles. 

T. H. Tsai, J. W. Lane, and C. S. Lin Temperature-Programmed Reduction for Solid Materials Characterization, Alan Jones and Brian McNichol Catalytic Cracking Catalysts, Chemistry, and Kinetics,... 

World-Wide there is approximately 1000 tons of fluid cracking catalyst manufactured each day. Of this, about 35% contains some form of aluminum deficient zeolite Y, one whose SiOz/AlaOa ratio exceeds 5.5 1, and whose performance is generally characterized by enhanced olefin formation and higher gasoline research and motor octane number. The aluminum deficient... 

Characterization of Dual-Function Cracking Catalyst Mixtures... 

The catalyst chosen for this study was a low metal, equilibrium, commercial zeolite-containing cracking catalyst obtained from Phillips Petroleum Company. No specific characterization of the catalyst is available. 

In response to recent federal and local environmental concerns (e.g., industrial emission controls and lead phase-out) and to the growing interest of refiners in cracking residual fuels, researchers have generated new families of cracking catalysts. There is now a need to review the merits of these newly developed materials. This volume contains contributions from researchers involved in the preparation and characterization of cracking catalysts. Other important aspects of fluid catalytic cracking, such as feedstocks and process hardware effects in refining, have been intentionally omitted because of time limitations and should be treated separately in future volumes. 

Bayraktar, O., and Kugler, E. Characterization of Coke on Equilibrium Fluid Catalytic Cracking Catalysts by Temperature-Programmed Oxidation. Applied Catalysis A General 233 (2002) 197-213. 

Translation of Laboratory Fluid Cracking Catalyst Characterization Tests to Riser Reactors... 

Laser Raman and X-ray Photoelectron Characterization of V-Contaminated Components of Fluidized Cracking Catalysts... 

The characterization of petroleum cracking catalysts, with which a third of the world s crude oil is processed, presents a formidable analytical challenge. The catalyst particles are in the form of microspheres of 60-70 micron average diameter which are themselves composites of up to five different micron and submicron sized phases. In refinery operation the catalysts are poisoned by trace concentrations of nickel, vanadium and other contaminant metals. Due to the replacement of a small portion of equilibrium catalyst each day (generally around 1% of the total reactor inventory) the catalyst particles in a reactor exist as a mixture of differing particle ages, poisoning levels and activities. 

The technique of Imaging Secondary Ion Mass Spectrometry (SIMS) has proven to be very well suited to the characterization of fluidized petroleum cracking catalysts (FCC).(1-4) The ability to view... 

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