Corrosion testing electrochemical

Key words corrosion inhibition, rare earth metal inhibitors, corrosion testing, electrochemical methods, surface analytical technique. 

Specifics on the type of biological attack. This must be done by some other method such as chemical analysis of the solution (plus consideration given to limitations to the use of these several electrochemical techniques for MIC studies, noted previously under Corrosion Testing Laboratoiy Tests and subsequent subsections). 

France, W. D. and Greene, N. D., Some Effects of Ex(>erimental Procedures on Controlled Potential Corrosion Tests of Sensitised Austenitic Stainless Steel , Corros. Sci., 10,379(1970) Tedmon, C. S. (Jr.), Intergranular Corrosion of Austenitic Stainless Steel , J. Electrochem. Soc., 118, 192(1971)... 

Wilde, B. E. and Williams, E., On the Correspondence Between Electrochemical and Chemical Accelerated Pitting Corrosion Tests , J. Electrochem. Soc., 117, 775 (1970)... 

A detailed and well-referenced account of electrochemical methods of testing has been written by Dean, France and Ketcham in a section of the book by Ailor. ASTM G5 1987 outlines standard methods for making potentiostatic and potentiodynamic anodic polarisation measurements and ASTM G3 1974 (R1981) gives conventions applicable to electrochemical measurements in corrosion testing. 

In view of the electrochemical nature of corrosion, it has seemed reasonable to many investigators to assume that suitable accelerated corrosion tests could be made by observing the response to electrolytic stimulation of the corrosion processes, or by attaching particular significance to the results of quickly made electrode potential and current measurements. 

Williams, D. E., The Analysis of Current and Potential Fluctuations in Corroding Systems , Proc. Electrochemical Corrosion Testing, Ferrara, 10-14 September 1985 DECHEMA, (1986)... 

Test method for sandwich corrosion test Recommended practice for preparing, cleaning, and evaluating corrosion test specimens Practice for aqueous corrosion testing of samples of zirconium and zirconium alloys Test method for corrosion testing of products of zirconium, hafnium and their alloys in water at 633 K or in steam at 673 K [metric] Recommended practice for conventions applicable to electrochemical measurements in corrosion testing... 

FIG. 25-14 Schematic diagram of the electrochemical cell used for crevice corrosion testing. Not shown are three hold-down screws, gas inlet tube, and external thermocouple tube. 

Absolute correlations between service performance and electrochemical measurements do not appear frequently in the literature. Based on 300 test systems. Bacon and coworkers (, correlated electrochemical resistance with exposure time. Recently, Mills ( also observed a correlation between salt fog corrosion and electrochemical resistance. We have found open circuit potential measurements to be extremely useful for the routine evaluation of high-nitrile polymer-based photocured coatings. 

Epelboln, I. Gabrlelll, C. Keddan, M. Takenoutl, H. In "Electrochemical Corrosion Testing" Mansfeld, F. ... 

ASTM G 3-89, Standard Practice for Conventions Applicable to Electrochemical Measurements in Corrosion Testing, American Society for Testing and Materials, Philadelphia, PA, USA, 1989, pp 56-64. 

It is preferable to carry out laboratory corrosion tests and to validate the data with service tests for the selection of materials. It is needless to note that the chosen test method be reliable and cost effective. Some of the test methods in use in industry are service tests, field tests, laboratory tests, and rapid electrochemical methods such as potentiodynamic polarization, linear polarization, electrochemical impedance and electrochemical noise. 

The preferred order of corrosion testing and its reliability is service tests > field tests > laboratory tests. It is not always possible to carry out service tests and hence it is recommended that coordinated corrosion testing involving a combination of (i) laboratory test and field test or (ii) rapid electrochemical tests and weight loss, or any other combination that is suitable be carried out. 

Thompson, N.G., Payer, J.H., DC Electrochemical Test Methods, in Corrosion Testing Made Easy, B.C. Syrett (ed.), NACE International, Houston, TX, USA, pp. 72-77, 1998. 

Figure 5.25 Comparison of the results from stress corrosion tests with those from polarization curves at fast and slow potential sweep rates for different carbonate-bicarbonate solutions, indicating the extent to which the experimentally observed cracking range can be predicted from electrochemical measurements.8...

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