Compensated probes

An Orion research digital ion analyzer 510 equipped with a temperature compensation probe was used for all pH measurements. A Hewlett-Packard diode array 8452A spectrophotometer with a thermostatted cell compartment was employed for UV-vis spectra and for kinetic measurements. All C NMR spectra were recorded by use of a Varian 400 XL spectrophotometer. Elemental analyses were performed by E and R Microanalytical Laboratories. A VG 70-SE mass spectrometer with fast atom bombardment was used. 

The operation is quite simple One sets the frequency to the lowest value, adjusts the gain and phase to the desired sensitivity using a special calibration standard discussed below and performs a zero-compensation on a defect free zone of the standard. Now one is ready to test. As one slides the probe across the surface of an aluminum structure, a signal response will be indicative of the presence of corrosion or of the presence of a subsurface edge. 

Figure 5 shows the display in the measure mode. It consists of a detailed A-scan window and a number of smaller windows for display parameters and inspection parameters. The A-scan display may be used as a stand-alone tool or as a tool for measuring parameters required for a specific inspection, e.g. probe parameters, reference echoes, and depth compensation with automatic transfer to the data set. 

The software contains features such as TCG- compensation, information on probe rotation, compensations for object geometry and can provide a choice of A-, B- and C-scan images while scanning. 

As an example, a series of transient hole-bnming spectra obtained with a chirp-compensated continuum probe with a light-harvesting protein is shown in figure B2.1.7 [112]. As the probe delay increases, tire initially... 

The probe design includes provisions to compensate for temperature variations. This feature is not totally successful. The most reliable results are obtained in constant-temperature systems. 

Leakage current monitor - this can be connected perma-nently for continuous reading or periodic monitoring. The normal practice is to measure only periodically for a short period to take average measurements on an hourly, daily, monthly or yearly basis. When not connected permanently, the instrument can also be used as a portable kit to monitor the condition of other arresters installed in the vicinity. Field probe - to compensate the third harmonic of the system voltage to make the IZnO free from the third harmonic of the system voltage. This method of /r measurement therefore provides more accurate and closer monitoring of the arrester. 

The analyst has two practical means of measuring the energy distribution of X rays emitted from the specimen energy-dispersive spectrometry and wavelength dispersive spectrometry. These two spectrometers are highly complementary the strengths of each compensate for the weaknesses of the other, and a well-equipped electron probe instrument will have both spectrometers. 

Small probed regions down to 1-2 pm are possible using microscope lenses. Lasers can supply as much pump power as needed to compensate for weaker signals, but a limit is reached when sample heating or nonlinear optically induced processes become significant. 

Various ion-optical tricks have to be used to compensate for the spread of energies of the extracted ions, which limit mass resolution unless corrected for. In the latest version of the atom probe (Cerezo et at. 1988), spatial as well as compositional information is gathered. The hole in the imaging screen is dispensed with and it is replaced by a position-sensitive screen that measures at each point on the screen the time of flight, and thus a compositional map with extremely high (virtually atomic) resolution is attained. Extremely sophisticated computer control is needed to obtain valid results. 

The resistance of a thermistor is achieved in a similar manner to the measurement of metallic probes. The advantage of thermistors is that their resistance is usually high, and the compensation for the measurement wire resistance is not so critical. 

For various reasons, this type of anemometer is not a suitable instrument for practical measurements in the industrial environment. The thin wire probe is fragile and sensitive to contamination and is unsuited to rough industrial environments. The wire temperature is often too high for low-velocity measurements because a strong natural convection from the wire causes errors. Temperature compensation, to correct for ambient air temperature fluctuations may not be available or may not cover the desired operating range. 

A calibration facility must produce the desired velocity range for the meter to be calibrated. The air temperature should be kept constant over the test to ensure constant density. For thermal anemometers, velocity calibration only is not sufficient. They should also be checked for temperature compensation. In the case of omnidirectional probes, sensitivity to flow direction should be tested. In the case of low-speed (thermal) anemometers, their self-convection error should be measured, and, for instruments measuring flow fluctuation (turbulence), dynamic characteristics testing should be carried out as well. ... 

The Nernst equation shows that the glass electrode potential for a given pH value will be dependent upon the temperature of the solution. A pH meter, therefore, includes a biasing control so that the scale of the meter can be adjusted to correspond to the temperature of the solution under test. This may take the form of a manual control, calibrated in 0 C, and which is set to the temperature of the solution as determined with an ordinary mercury thermometer. In some instruments, arrangements are made for automatic temperature compensation by inserting a temperature probe (a resistance thermometer) into the solution, and the output from this is fed into the pH meter circuit. 

Check whether the instrument supplied is equipped for automatic temperature compensation, and, if so, that the temperature probe (resistance thermometer) is available. If it is not so equipped, then the temperature of the solutions to be used must be measured, and the appropriate setting made on the manual temperature control of the instrument. 

As in molecular chemistry, an alternative path to compensate for electron deficiency is the formation of multiple bonds, through 7r-interactions, as in unsaturated and aromatic molecular systems. Our work in Houston focuses on probing the efficacy of the ZintI concept in rationaUzing stoichiometries, crystal structures and chemical bonding of complex electron-poof ZintI phases that exhibit novel i-systems. Their chemical bonding is reflected by their unusual crystal structures related to unsaturated hydrocarbons [53]. 

In RF discharges one has to compensate for the RF voltage component across the probe sheath. This is done with a pickup element, situated close to the probe tip, which should be in the plasma bulk as well. Compensating electronics within the probe is usually designed to work at a prescribed RF frequency, and cannot be used at other frequencies. 

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