Copper alloy coating

Lead azide tends to hydrolyze at high humidities or in the presence of materials evolving moisture. The hydrazoic acid formed reacts with copper and its alloys to produce the sensitive cupric azide [14215-30-6] Cu(N2)2- Appropriate protection must be provided by hermetic sealing and the use of noncopper or coated-copper metal. 

Nickel—copper alloys also are used as coated electrodes or filler alloys for welding purposes. Coinage is typically an alloy of 75 wt % Cu and 25 wt % Ni. 

Copper and copper alloys resist corrosion by most food products. Traces of copper may be dissolved and affect taste or metals are often tin coated. 

Base Metal Finishes. The low cost of base metal finishes obviates selective coating. Electro deposition is used for 0.5—5 p.m thick coatings of tin and tin—lead alloy, usually about 50 wt % Sn, 50 wt % Pb, on electronic connector contacts, on contacts at the edges of printed circuit boards, and on terminals. Sheet copper alloys that have been coated with tin—lead alloy are widely used for contacts that are stamped and then formed into the desired shapes, such as pins having a closed end and sockets. Aluminum connectors that have utility—industrial appHcations are more thickly coated, and hot-dipping in molten tin is common. 

Other decoratively plated coatings produced in quantity are copper and copper alloys. Copper-plated hardware for cabinetry, lighting fixtures, household trim, and other uses is protected using a top coat of clear lacquer. Copper plating finishes are available with a variety of post-treatments to simulate antique or mstic appearances. 

Six iron anodes are required for corrosion protection of each condenser, each weighing 13 kg. Every outflow chamber contains 14 titanium rod anodes, with a platinum coating 5 /tm thick and weighing 0.73 g. The mass loss rate for the anodes is 10 kg A a for Fe (see Table 7-1) and 10 mg A a for Pt (see Table 7-3). A protection current density of 0.1 A m is assumed for the coated condenser surfaces and 1 A m for the copper alloy tubes. This corresponds to a protection current of 27 A. An automatic potential-control transformer-rectifier with a capacity of 125 A/10 V is installed for each main condenser. Potential control and monitoring are provided by fixed zinc reference electrodes. Figure 21-2 shows the anode arrangement in the inlet chamber [9]. 

Striking of a smear or thin coating of alloy on rusty steel with a hammer. The glancing impact of stainless steel, mild steel, brass, copper-heryllium hronze, aluminium copper and zinc onto aluminium smears on rusty steel can initiate a thermite reaction of sufficient thermal energy to ignite flammahle gas/vapour-air atmosphere or dust clouds. 

Spiral-plate exchangers are fabricated from any material that can be cold worked and welded. Materials commonly used include carbo steel, stainless steel, nickel and nickel alloys, titanium, Hastelloys, and copper alloys. Baked phenolic-resin coatings are sometimes applied. Electrodes can also be wound into the assembly to anodically protect surfaces against corrosion. 

In general, just about any material that can be worked into the impeller design is available, including steel, stainless alloys, copper alloys, nickel and alloys, hard rubber, and lead, rubber and plastic coatings on impellers and shafts. 

Light, sandy, well-drained soil of high electrical resistivity is low in corrosivity and coated steel or bare stainless steels can be employed. It is unlikely that the whole pipe run would be in the same type of soil. In heavier or damp soils, or where the quality of back filling cannot be guaranteed, there are two major corrosion risks. Steel, copper alloys and most stainless steels are susceptible to sulfide attack brought about by the action of sulfate-reducing bacteria in the soil. SRB are ubiquitous but thrive particularly well in the anaerobic conditions which persist in compacted soil, especially clay. The mechanism of corrosion where SRB are involved is described in Section... 

Metals in contact with timber can be corroded by the acetic acid of the timber and by treatment chemicals present in it. Treatment chemicals include ammonium sulfate and ammonium phosphate flame-retardants. These are particularly corrosive towards steel, aluminum and copper alloys. Preservative treatments include copper salts which, at high timber moisture contents, are corrosive towards steel, aluminum alloys and zinc-coated items. 

Bare copper exposed indoors will slowly tarnish. Transparent lacquers may be used, however, to retain a bright surface without the need for frequent cleaning. Neither copper nor any copper alloy will remain bright and polished without maintenance or coating. 

Tinned copper and copper alloys Copper itself has a fair corrosion resistance but traces of copper salts are often troublesome and a tin coating offers a convenient means of preventing their formation. Thus copper wire to receive rubber insulation is tinned to preserve the copper from sulphide tarnish and the rubber from copper-catalysed oxidation, and also to keep the wire easily solderable. Vessels to contain water or foodstuffs, including cooking vessels, water-heaters and heat exchangers, may all be tinned to avoid copper contamination accompanied by possible catalysis of the oxidation of such products as milk, and discolouration in the form of, for example, green stains in water and food. 

Table 13.13 Thickness suggested for electrodeposited tin coatings on copper and copper alloys with at least 50% copper...

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