CIELAB

The quantitative measurement of pigment or pigmented system deterioration upon exposure to heat or light used to be expressed by visual numerical standards. In modem times color differences are expressed in the CIELAB system which has become the leading method for color characterization (8). 

In the process of testing, color deviations are expressed ia the CIELAB system which projects total color differences either on the axes of the rectangular LAB or the equivalent polar LHC system (26). In either case tested samples must fall within acceptable ranges or limits estabhshed versus a standard by the pigment manufacturer and accepted by the pigment user. 

In color technology and measurement, both types of approaches are used. Color printing, for example, generally employs three colors (usually plus black), and the ever useful CIE system was founded on experiments in which colors were matched by mixtures of three primary colors, often blue, green, and red. Yet transmitted television signals are based on the opponent system, with one intensity and two color-balance signals, as are the modern representations of color, such as the CIELAB and related color spaces based on red-green and yeUow-blue opponent axes. 

The 1976 CIELAB Color Space. Defiaed at the same time as the CIELUV space, the CIELAB space, propedy designated CIE E i , is a nonlinear transformation of the 1931 CIE X, Y, Z space. It also uses the metric lightness coordinate E, together with ... 

This transformation results in a three-dimensional space that follows the opponent color system with +a as red, —a as green, +5 as yellow, and — b as blue. CIELAB is closely related to the older Adams-Nickerson, modified Adams-Nickerson, and other spaces of the Y,a,b type, which it replaced (1,3). 

The CIELAB coordinates either in that form or in the form discussed below, are the most commonly used color descriptors in... 

The 1976 CIE Metric Color Spaces. Both the CIELUV and CIELAB spaces can have their Cartesian coordinates converted to cylindtical coordinates, called metric or hue-angle coordinates, with E unchanged. These coordinates are designated CIE LYC h and CIE LYC, b, respectively. 

Hunter L,a,b and Other Color Spaces. The CIELAB and CIELUV color spaces were the outgrowth of a large and complex group of interrelated early systems and have replaced essentially all of them except for the 1942 Hunter Y,a,b group of color spaces (3). This was the earliest practical opponent-based system which is still widely used. In this system, for illuminant C and the 2° standard observer ... 

Color Difference Assessment. Color difference scales include those of Judd-Hunter, Macadam, Adams-Nickerson, ANLAB, and ANLAB40. AH of these have limitations in some way or another they are described in most texts (1 4). Each appHes only to the precise conditions used in thek determination and interconversion is not possible. Modifications of CIELAB in the metric form such as the CMC(1 c) system (14) promise improved performance for the future. 

In the CIELAB and CIELUV color spaces, the difference between a batch sample and a reference standard designated with a subscript s, can be designated by its components, eg, AAL = L — L. The three-dimensional total color differences are given by EucHdian geometry as the 1976 CIE lYa b and 1976 CIE lYu Y color difference formulas ... 

There are instances in which one manufacturer may designate a bluish red dye as Red 4B and another manufacturer uses Violet 2R for the same dye. To resolve such a problem the manufacturers pattern leaflets should be consulted. These show actual dyed pieces of cloth so the colors of the dyes in question can be compared directly in the actual appHcation. Alternatively, colors can be specified in terms of color space coordinates. The Cielab system is becoming the standard in this system the color of a dye is defined by three numbers, the L, a, and b coordinates (see Color). 

Color Difference Evaluation. Shade evaluation is comparable in importance to relative strength evaluation for dyes. This is of interest to both dye manufacturer and dye user for purposes of quaUty control. Objective evaluation of color differences is desirable because of the well-known variabihty of observers. A considerable number of color difference formulas that intend to transform the visually nonuniform International Commission on Illumination (CIE) tristimulus color space into a visually uniform space have been proposed over the years. Although many of them have proven to be of considerable practical value (Hunter Lab formula, Friele-MacAdam-Chickering (FMC) formula, Adams-Nickerson formula, etc), none has been found to be satisfactorily accurate for small color difference evaluation. Correlation coefficients for the correlation between average visually determined color difference values and those based on measurement and calculation with a formula are typically of a magnitude of approximately 0.7 or below. In the interest of uniformity of international usage, the CIE has proposed two color difference formulas (CIELAB and CIELUV) one of which (CIELAB) is particularly suitable for appHcation on textiles (see Color). 

The frame-grabbed interferograms with a resolution of 512 pixels by 512 lines are first transformed from RGB to CIELAB color space and they are then converted to the him thickness map using appropriate calibration and a color... 

The CIELAB system (1976) strictly standardizes the light source and the observer. CIE recommends three standard sources, A is an incandescent lamp, and B and C are lamps provided with different two-cell Davis-Gibson liquid hlters that simulate noon daylight and average daylight, respectively. Since the main object of the system is to obtain colorimetric results for normal tri-chromats (people with normal color vision), the standard observer must represent the human population with normal... 

Three attributes characterize color hue, lighmess (or value), and saturation (or chroma) and they are graphically represented in color solids (e.g., Munsell solid. Hunter solid). The Munsell Color Notation is a rapid, portable, widespread, and economical system of color determination. However, as it depends on sensory evaluation by panels, many laboratories prefer when possible to replace human judgment by instrumental techniques that are easier to handle. The CIELAB established by the Commission International d Eclairage (CIE) has become widely used with the availability of reflectance spectrophotometric instrumentation. 

Gonnet, J.R, Colour effects of co-pigmentation of anthocyanins revisited. 1. A colorimetric definition using the CIELAB scale. Food Chem., 63, 409, 1998. 

The changes that occur after the heat processing of food systems are often monitored by different parameters, such as total carotenoid content (and therefore isomerization and oxidation are underestimated), individual carotenoids (overall changes may be missed), and CIELAB color parameters (no information on carotenoid degradation mechanism). The data given in Table 12.3 reflects the influence of matrix composition, food state (liquid or solid), and measured parameter on the carotenoid degradation kinetics. 

CIE color system, 7 304. See also Commission Internationale de l clairage (CIE) chromacity diagrams, 7 313-315 standard illuminants, 7 315-316 CIEDE200 color difference equation, 7 322 CIELAB, 7 304 CIELAB Color Space, 7 320 CIELAB color values, of flax fiber, 11 614t Cielab dye nomenclature system, 9 244 CIELAB Metric Color Spaces, 7 320 CIELAB system, 19 428, 451 CIELUV Color Space, 7 319-320 CIE Standard Observer, 7 311-312 Cigarette filters... 

In colorimetric terms, color differences are generally characterized by the distance between two colors in one of the color notation systems, most commonly the CIELAB system. The difference determined in this way represents the total color difference. Since a color is characterized by three quantities, a color difference can also be expressed in terms of three difference components (that is, differences in the color coordinates) and thus described in greater detail. Visually equal color differences between almost equal colors may, upon colorimetric measurement, be considered distinct if the colors of one pair differ strongly from those of the other pair. The formulas for color differences are further elaborated in order to remedy this defect. 

After all differences in tinctorial strength are accounted for, any remaining deviation is due to the inherent difference in shade between the two pigments and cannot be eliminated by simply adapting the amounts. It is useful to describe the remaining color difference by referring to the CIELAB system. 

Color Index Name Temperature effect in CIELAB units Fastness to overpainting on a fastness scale from 1 to 5 Bleed resistance on a fastness scale from 1 to 5... 

DIN 6174 Farbmetrische Bestimmung von Farbabstanden bei Korperfarben nach der CIELAB-Formel. ISO 7724-3-1984 Paints and varnishes - Colorimetry, Part 3 Calculation of colour differences, 1. ed. 

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