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Chemical component proximate

Many chemical component-s present in such aerosols are relatively stable they can be measured long after (days, week.s, or more) the aero.sol has been collected on a filter or impactor plate, for example. Short-lived reactive and/or volatile species such as peroxides and aldehydes are not usually determined. This may make it difficult to evaluate the health and ecological effects of aerosols because chemically reactive chemical species tend to be the most active biochemically. The chemical components present in the particles collected on a filter or impactor plate may react with each other when they are in close proximity. Particle deposits in filters or on surfaces may also react with molecular components of the gases flowing over them. Chemical reactions between the gas and aerosol may not affect mea.surement.s of metallic elements but may modify chemical speciation (compound form) on the collector surface. All of these factors must be taken into account in selecting sampling and measurement methods for aerosol chemical properties. [Pg.174]

What counted as the most significant chemical components or principles of plants changed considerably around 1750. Whereas by 1700 chemists were almost exclusively concerned with the ultimate simple elements or principles of plants—apart from a few individual exceptions, such as Simon Boulduc—, after 1750 the majority of chemists became more interested in the compound components or proximate principles of plants. The increase in collective attention the compound components of plants received from 1750 on did not entirely replace the search for the ultimate principles of plants. Instead, chemists began to establish an order of analysis by distinguishing between two kinds of plant-chemical analysis first, the analysis of entire plants and the organized parts of plants, which aimed at separating the more compound or proximate principles of plants and, second, the further analysis of the proximate principles into their ultimate components or simple principles. Whereas the lat-... [Pg.221]

The volume of substance in a composite material that exists in a nonequilibrium state due to its proximity to an interface has been termed an interphase [1]. The interphase is a zone of distinct composition and properties formed by chemical or physical processes such as interdiffusion of mutually soluble components or chemical interaction between reactive species. [Pg.433]

There are many applications for silicone adhesives, sealants, or coatings where the condensation curing systems are not suitable. This is because they are relatively slow to cure, they require moisture to cure that can itself be in some cases uncontrollable, and they evolve by-products that cause shrinkage. Adhesives needed in automotive, electronics, microelectronics, micro electromechanical systems, avionic, and other hi-tech applications are usually confined to vei7 small volumes, which can make access to moisture difficult. Also, their proximity to very sensitive mechanical or electronic components requires a system that does not evolve reactive chemicals. [Pg.685]

With respect to the carrier mechanism, the phenomenology of the carrier transport of ions is discussed in terms of the criteria and kinetic scheme for the carrier mechanism the molecular structure of the Valinomycin-potassium ion complex is considered in terms of the polar core wherein the ion resides and comparison is made to the Enniatin B complexation of ions it is seen again that anion vs cation selectivity is the result of chemical structure and conformation lipid proximity and polar component of the polar core are discussed relative to monovalent vs multivalent cation selectivity and the dramatic monovalent cation selectivity of Valinomycin is demonstrated to be the result of the conformational energetics of forming polar cores of sizes suitable for different sized monovalent cations. [Pg.176]

In order to define this variety of food matrices, chemical composition differences that primarily influence chemical analytical measurements have to be considered. Major food components determining basic chemical make-up are the proximate composition of fat, protein, carbohydrate, ash, and moisture. Variations in ash content in general have a minor influence on analytical methods for other constituents and impact of moisture content can be controlled. Thus the major components influencing analytical performance are the relative levels of fat, protein, and carbohydrate. [Pg.211]

Scores Pla (Sample Diagnostic) The scores are the coordinates of the samples in the new coordinate system where the axes are defined by the principal components. These new axes are used to view the relevant variation in the data see m a smaller number of dimensions. The plot reveals how the samples arc rela d to each other given the measurements that have been made. Samples that are close to each other on a given score plot are similar with respect to the original measurements provided the plot displays a sufficient amount of the total variation. This mathematical proximity translates to chemical similaritySmeaningful measurements have been made. [Pg.53]

Cell damage induced by chemical carcinogens involves the conversion in the body of a proximate carcinogen (inert) to the ultimate carcinogen that is a reactive electrophilic compound. This ultimate carcinogen may then interact or, more frequently, combine covalently with intracellular components, such as DNA, RNA, phospholipids, or glutathione. [Pg.280]

Among several indicators of motional state of organic solids H linewidths has been used from very beginning of solid-state NMR. However, inherently low resolution of H MAS NMR spectra caused by the very strong homonuclear interactions and relatively low MAS speed lead to a very limited application of H MAS NMR for studies of mobility.1 A 2D wideline separation (WISE) experiment correlates carbon chemical shifts recorded under MAS with broad H lines.1,24 As a result a broad ll lines are separated in the components corresponding to the 13C sites in their close proximity. For mobile domains in a sample, the H - ll coupling are relatively weak which leads to relatively narrow 11 static lines. The opposite is observed for the rigid domains. [Pg.269]

A biosensor utilizes a biological component to translate the concentration of a specific analyte of interest into a signal detectable by some chemical or physical means (7). Successful operation of a biosensor requires that the biological component and the signal it transduces be localized to and concentrated within a region in close proximity to the detection system. Immobilization of enzymes within a polymeric matrix ensures concentration and localization of the enzymic reaction, and creates a convective barrier, thus preventing dilution and convective removal of the product species before it is detected. Enzymes immobilized on or near the detection system are frequently used as the... [Pg.278]


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See also in sourсe #XX -- [ Pg.76 , Pg.110 , Pg.216 , Pg.229 , Pg.230 , Pg.242 , Pg.285 , Pg.290 ]




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