Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Channel problem

This approach proved accurate and convenient for the analysis of the narrow resonances the results presented in this work have been obtained without employing this trick because the limited dimensions of this single-channel problem are easily handled by the standard method. [Pg.370]

This map can have negative as well as positive features, and yet its calculation involves only that of the positive map qmi, thus avoiding the issue of extending the MaxEnt method to two-channel problems. [Pg.18]

Selected entries from Methods in Enzymology [vol, page(s)] Analysis, software for, 207, 717 barrier models, 207, 818 closed and open time estimation, 207, 755 data acquisition, 207, 747 modal behavior analysis, 207, 757 multiple channel problem, 207, 756 single-channel [extraction of kinetic information, 207, 765 measurement in tissue slices, 207, 220] synaptic, resolution improvement in patch clamp recording, 207, 216 whole-cell recording in calcium channel, 207, 181 fluctuation analysis, 207, 192. [Pg.375]

Let us for a moment consider the three channel problem depicted in Fig. 20.1. We have just discussed the case in which Wt < 0 for all i, i.e. the region below the lowest limit. The quantum defect surface defined by Eq. (20.12) is a two dimensional surface inscribed in a cube of length Av, = 1 on a side. Now let us consider the region between the first and second ionization limits, where channel 1 is open. Since is a continuum wave the r — boundary condition does not... [Pg.419]

Fig. 21.2 Quantum defect surface for the two channel problem showing r, or equivalently r, the phase shift in the open channel, channel 1, divided by — n. The Vj axis is reversed to... Fig. 21.2 Quantum defect surface for the two channel problem showing r, or equivalently r, the phase shift in the open channel, channel 1, divided by — n. The Vj axis is reversed to...
Above the 6p1/2 limit the Ba 6p3/2nd J = 3 states accessible from the bound 6snd D2 states and the linear combination of continua into which they autoionize can be treated as a two channel problem. Below the 6p1/2 limit we must use the three channels of Eq. (21.17). In the region below the Ba+ 6p1/2 limit the / = 3 wavefunction is given by... [Pg.440]

Takatsuka and Gordon (21a) have developed a "full collision" formulation of photodissociation which describes a multichannel process on the repulsive surface for both direct and indirect events. The scattering wavefunctions that are used to generate the T-matrix and the FC overlaps are not zeroth-order uncoupled functions, but solutions of the coupled-channel problem. [Pg.101]

To capture the essence of the Feshbach resonance phenomenon, we will need to understand what happens to the ground vibrational state 4>o(R) of the ground electronic state, also depicted in Figure 1.13, because of the interaction with the continuum of states excited electronic state. The physical process described above can be formulated as a two coupled channels problem where the solution irg(R) in the closed channel (the ground state) depends on the solution ire(R) in the open channel (the excited state) and vice-versa. The coupled Schrodinger equations read... [Pg.28]

H-D. Meyer, Analytically continued S-matrix potentials defined as a sum of exponentials. 1. The single channel problem, J. Phys. B 16 (1983) 2265. [Pg.160]

Lester, W.A., Jr. (1976). The N coupled-channel problem, in Dynamics of Molecular Collisions, Part A, ed. W.H. Miller (Plenum Press, New York). [Pg.397]

I Here there are two different possibilities. If the physics is such that E, n 1) is a solution of a single-channel problem, then its coordinate space representation can a(ways be written [8] as... [Pg.141]

This type of reactor is very widely used because it is one of the simplest to construct and it is cheap. Sampling and analysis of the product streams are generally easy, but they can be difficult to obtain effectively at low conversions. Isothermality of the reactor is generally attainable, particularly at low heat release. Residence-time distribution measurements can be difficult because of channeling problems, but this can be somewhat reduced by running the reactor vertically rather than horizontally. [Pg.151]

The first mode of operation described above possesses certain shortcomings. There is a tendency towards channeling and backmixing of liquid which makes true countercurrent operation impossible. Good design can minimize these channeling problems.5,36,9S An alternative to this mode of operation is a three-phase spouted-bed column. The hydrodynamics (i.e., pressure drop, bed expansion, and the liquid holdup) of this type of column have been studied by Vukovic et... [Pg.311]

Petroleum production from subterranean reservoirs can be increased by injecting water as liquid or steam. Various chemicals have been added to the water or steam to increase volumetric sweep efficiency. One alternative is the use of emulsions which serve as diverting agents to correct the override and channeling problems that occur during fluid injection. Laboratory results show that it may be possible to control channeling and steam override with an emulsion blocking technique. The emulsion can be formed with the aid of a surfactant mixture or by use of natural surfactants that exist in some crude oils. Core-... [Pg.405]

The internal solutions are matched at r = a to solutions of the scattering problem in the external region. Here it is a simple coupled-channels problem in which exchange and target-correlation terms are negligible. The matching matrix is the R matrix. [Pg.197]

Channel problems 2. The acetylcholine receptor channel can also undergo mutation leading to fast channel... [Pg.561]

Developmental work in chemical nomenclature, limited at times, is far from being the only work done by the ACS nomenclature committee. At the present time our committee conceives that it can best be useful by (1) channeling problems which arise so that... [Pg.59]

For a single-channel problem, only one term in the sum in Eq. (56) is to be considered. On the other hand, it is not unusual for multichannel chemical reactions to have a multiexponential form of reaction probability. Reduction to a single exponential form can depend on individual cases under study. For our cluster system, in which various isotropic properties dominate due to the identical particle composition (see Ref. 39), it is quite likely that there are very many critical points that are topologically equivalent or energetically similar to each other. In these cases, averaging should work. In the two familiar means over variables (X i = 1,2,..., M ... [Pg.64]

Having described the approaches to the internal and channel problems we now can describe the iteration procedure ... [Pg.515]

Since the ACFs are fibrous materials that can be easily molded and woven, filters can be designed that do not have the setding and channeling problems of the conventional granular and powder ACs [1]. Due to their low hydrodynamic resistance, they can be used as thin cloths for the treatment of high flow of gases, very useful for control of gas-phase pollution [2]. [Pg.432]

The CCCC method is applicable to many-channel problems involving multiply coupled open continue as well as close channels. [Pg.287]

Here all matrix elements in the two-level equations (section B2.2.8.4) are included, except the back coupling F yterm which provides the influence of the inelastic charmel on the elastic channel and is required to conserve probability. Distortion of the elastic and outgoing inelastic waves by the averaged (static) interactions V.. and respectively is therefore included. The two-state equations can then be decoupled and effectively reduced to one-channel problems. An analogous static-exchange distortion approximation, where exchange between the incident and one of the target particles also follows from the two-level treatment. [Pg.2045]

W. A. Lester, Jr., The N coupled-channel problem, Modern Theoretical Chemistry, Vol. I (W. H. Miller, ed.), Plenum Press, New York, 1976, p. 1 D. Secrest, Rotational excitation I The quantal treatment, in Atom-Molecule Collision Theory (R. B. Bernstein, ed.), Plenum Press, New York, 1979. [Pg.55]

The simplest model is the following the diabatic potentials are constant with V2 - Vx = A > 0 and the diabatic coupling is V e R where A = 2V0. Recently, Osherov and Voronin obtained the quantum mechanically exact analytical solution for this model in terms of the Meijer function (38). In the adiabatic representation this system presents a three-channel problem at E > V2 > Vu since there is no repulsive wall at R Rx in the lower adiabatic potential. They have obtained the analytical expression of a 3 X 3 transition matrix. Adding a repulsive potential wall at R Rx for the lower adiabatic channel and using the semiclassical idea of independent events of nonadiabatic transition at Rx and adiabatic wave propagation elsewhere, they derived the overall inelastic nonadiabatic transition probability Pl2 as follows ... [Pg.494]

Channel problems 2. The acetylcholine receptor charmel can also undergo mutation leading to fast channel syndrome (PCS), with clinical manifestations similar to those of slow charmel syndrome (SCS). What would the recordings of ion movement look like in this syndrome Again, suggest a biochemical explanation. [Pg.369]


See other pages where Channel problem is mentioned: [Pg.196]    [Pg.418]    [Pg.823]    [Pg.58]    [Pg.329]    [Pg.419]    [Pg.419]    [Pg.424]    [Pg.429]    [Pg.436]    [Pg.166]    [Pg.197]    [Pg.561]    [Pg.1762]    [Pg.180]    [Pg.508]    [Pg.513]    [Pg.514]    [Pg.389]    [Pg.380]    [Pg.75]    [Pg.113]    [Pg.297]    [Pg.369]   
See also in sourсe #XX -- [ Pg.19 , Pg.118 ]




SEARCH



The problem of detecting small Cl -channels

© 2024 chempedia.info