Caustic relations

Increases in U.S. demand for caustic soda have been unpredictably high in the last few years. Between 1987 and 1989, the annual increase in demand was about 3% (6). However, the caustic soda market is mature and new areas of significant growth have not surfaced in recent years. The unexpected recent demand is generally related to two factors the pick-up in the U.S. economy after the slump of 1986 and pulp mills operating at fiiU capacity, leading to less efficient caustic use. 

Lithium ion is commonly ingested at dosages of 0.5 g/d of lithium carbonate for treatment of bipolar disorders. However, ingestion of higher concentrations (5 g/d of LiCl) can be fatal. As of this writing, lithium ion has not been related to industrial disease. However, lithium hydroxide, either dHectly or formed by hydrolysis of other salts, can cause caustic bums, and skin contact with lithium haHdes can result in skin dehydration. Organolithium compounds are often pyrophoric and requHe special handling (53). 

Much of the equipment used in the recovery system is identical with or closely related to equipment used in other chemical industries. This includes multiple-effect evaporators, and forced-circulation concentrators, causticizing equipment, and lime kiln. The function and nature of equipment essentially unique to the kraft recovery system are discussed herein. 

One of the most exciting discoveries related to quinone/hydroquinone chemistry is thek synthesis by biosynthetic routes (12,13). Using bacterial enzymes to convert D-glucose [50-99-7] (7) to either 1,2- or l,4-ben2enediol allows the use of renewable raw material to replace traditional petrochemicals. The promise of reduced dependence on caustic solutions and the use of transition-metal catalysts for thek synthesis are attractive in spite of the scientific and economic problems still to be solved. 

This dissociated zircon is amenable to hot aqueous caustic leaching to remove the siHca in the form of soluble sodium siHcate. The remaining skeletal stmcture of zirconia is readily washed to remove residual caustic. Purity of this zirconia is direcdy related to the purity of the starting zircon since only siHca, phosphate, and trace alkaHes and alkaline earth are removed during the leach. This zirconia, and the untreated dissociated zircon, are both proposed for use in ceramic color glazes (36) (see Colorants for ceramics). 

Many related processes use charged membranes and/or EMF. Electrodialytic water dissociation (water splitting), diffusion dialysis, Donnan dialysis, and electrolysis are related processes. Electrowsis (chlorine-caustic) is a process of enormous importance much of which is processed through very special membranes. 

Even though some refiners have reported that caustic reduces corrosion, others have reported increased corrosion. The authors believe that for the reported MEA and DEA systems a temporary beneficial effect occurs related to high CO2 loadings in these solutions. The effect is only temporary. 

Consider an aqueous caustic soda solution whose molarity mi = 5.0 kmol/m (20 wt.% NaOH). This solution is to be used in >scH(t>ing H2S from a gaseous waste. The operating range of interest is 0.0 < xi kmoUn ) < 5.0. Derive an equilibrium relation for this chemical absorption over the operating range of interest. 

It is useful to relate the molarity of the aqueous caustic soda (mi = S.O kmol NaOH/m ) to the other reactive species. Once the reactions shut, the composition of NaOH will decrease. However, it is possible to relate the molarity of the solution to the concentration of the reactive species at any reaction coordinate. Suppose that after a certain extent of reaction (8. IS) and (8.16) an analyzer is placed in the solution to measure the compositions of OH, HS and S with the measured... 

An interesting relation exists between the two gioups of acids. It has been found that, on heating /dy-acids with caustic soda solution, a shifting of the double link on the /3-position takes place,... 

For example, if tube failure occurs due to caustic gouging corrosion, the root causes are most likely related to the effects resulting from the availability offree sodium hydroxide in the BW, coupled with the development of localized caustic concentration. Control generally requires a twofold approach to remove the causes of this particular problem ... 

The presence of free caustic does not automatically lead to caustic gouging corrosion, caustic embrittlement, or other related problems. 

Perhaps the most important waterside problems relate to the likelihood of boiler surface deposits and their control. High concentrations of caustic or salines only occur if porous deposits are present. It is much better to remove the cause of deposition problems than to try to manage their effects, and modem iron and silica transport polymers, together with improved cleaning protocols, have done much to limit deposition in large boilers. 

Photocopies of journal articles relating to the Unipet process for the recycling of PETP developed by United Resource Recovery Corp. Details are given of the process which enables contaminated PETP to be recycled by the use of caustic soda which reacts with the PETP to yield ethylene glycol and terephthalic acid, followed by heating and evaporation of the EG which reduces organic impurities to carbon dioxide and water and leaves solid terephthalic salt. Its implications for the industry are also discussed. 

Upper respiratory tract irritation bas been observed in bumans at estimated exposure levels of between 0.04 and 0.4 mg silver/m for less than 1 to greater than 10 years. Irritant effects are considered to be related to tbe caustic properties of tbe various silver compounds, ratber than tbe silver itself. 

Arfwedson prepared lithium acetate, ignited it, and noted the insolubility of the resulting lithium carbonate in water and its action on platinum. He also prepared and studied the bicarbonate, sulfate, nitrate, chloride, tartrate, borate, hydroxide, and a double sulfate which he reported as lithium alum. He mentioned that lithium hydroxide is much less soluble than the other caustic alkalies and that it has a greater saturation capacity [lower equivalent weight] than they. Because of its ability to form deliquescent salts with nitric and hydrochloric acids, Arfwedson recognized the close relation between the new alkali and the alkaline earths, especially magnesia. 

Perhaps the most significant benzopyridine fungicides are the normal metal chelate compounds derived from 8-hydroxyquinoline (33), itself manufactured from quinoline by sulfonation/caustic fusion. Applications of (33) have been reviewed (56CRV217). Related compounds include quinacetol sulfate (34) (B-77MI20901) and halacrinate (35) (B-77MI20901). 

In an important paper entitled Experiments upon magnesia alba) quicklime, and other alcaline substances, published in 1755,1 J. Black first made clear the relations between caustic alkali and mild alkali that is, between the alkali hydroxides and alkali carbonates. These relations were not understood by the early chemists. They believed the mild alkalies and alkaline earths—that is, the carbonates of the alkalies and alkaline earths—to be elementary substances that the causticity of lime was due to the union of fire-matter or phlogiston with elemental chalk and the conversion of mild alkali into caustic alkali, with the simultaneous regeneration of chalk, by boiling the former with caustic lime, was due simply to the transfer of the phlogiston or fire-matter from the lime to the mild alkali. Otherwise expressed Quicklime=Chalk-f Fire-matter. J. Black proved this hypothesis to be untenable. H. L. Duhamel du Monceau 2 had shown nine years earlier in a memoir Diverses experiences sur la chaux, that limestone loses weight when calcined and regains it little by little on exposure to air. 

Black repeated these experiments, using chalk instead of magnesia, and showed in the same way, and with fairly accurate quantitative data, that quicklime differed from chalk in the same way that his calcined magnesia differed from mild magnesia. Although it was not possible to drive off the fixed air from alkalies, to form caustic alkalies, yet he recognized that a similar relation must exist between them, as between chalk and quicksilver. ... 

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