Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Normal metals

Metal soaps are composed of a metal and acid portion suppHed as solutions in solvent or oil. The general formula for a metal soap is (RCOO). In the case of neutral soaps, x equals the valence of the metal M. Acid soaps contain free acid (positive acid number) whereas neutral (normal) soaps contain no free acid (zero acid number) that is, the ratio of acid equivalents to metal equivalents is greater than one in the acid soap and equal to one in the neutral soap. Basic soap is characterized by a higher metal-to-acid equivalent ratio than the normal metal soap. Particular properties are obtained by adjusting the basicity. [Pg.217]

Interest in physical properties of quasicrystals is growing. Thus, a recent comment (Thiel and Dubois 2000) analyses the implications of the fact that decagonal quasicrystals have very much higher electrical resistivity, by orders of magnitude, than do their constituent metals, and moreover that resistivity decreases with rising temperature. For one thing, it seems that the concentration of highly mobile free electrons is much lower in such quasicrystals than in normal metals. [Pg.417]

A composite concrete slab or a stressed-skin system can also provide a roof diaphragm, but the latter may severely restrict the provision of subsequent roof penetrations. Concrete roof slabs are unusual, due to the greatly increased mass over the more normal metal decking/in-sulation/waterproof membrane or insulated metal decking options. [Pg.43]

Cobalt in its normal metallic form involves resonance between the two following sexivalent structures, in the ratio 35 65, as indicated by the saturation moment 1-71 magnetons ... [Pg.382]

Composition HfCg so to HfCg 99. Composition rarely reaches stoichiometry and HfC is normally metal rich. [Pg.240]

Non-rotating models at very low metallicity are believed to present the following differences with respect to normal metal rich stars ... [Pg.314]

As we said before, the contact resistance between normal metals should theoretically vary as T-1. Experimental results show dependence as T l [88], but also with larger exponents. For example, in the contact between Au/Au and Cu/Cu the contact resistance varies as T 13 [89], It is to be remarked that the Au/Au contact shows a thermal resistance 20 times smaller than that of the Cu/Cu contact (probably because of the presence of copper oxides). [Pg.113]

Tunneling electric current through the normal metal insulator superconductor junction is accompanied with heat flow out of normal metal when property voltage is biased. The phenomenon enables cooling of electrons and phonons (under special conditions) in the region below 1K. At lower bath temperatures, two parasitic heat sources decrease refrigerator performance ... [Pg.185]

As the flexibility of the macrocycle increases, then mismatch hole-size effects are expected to be moderated. In any case, as discussed in Chapter 1, a metal ion which is too large for the cavity may be associated with folding of a flexible macrocycle thereby allowing normal metal-ligand bond distances to be achieved. However, this is not always the case, and a number of examples of unfolded macrocyclic complexes containing compressed metal-donor distances are known (Henrick, Tasker Lin-doy, 1985). [Pg.186]

Hipps KW, Peter S (1989) Line shape in normal metal tunneling spectroscopy. J Phys Chem... [Pg.213]

Sequence for Metallic Lacquers The sequence when producing normal metallic lacquers differs from the sequence when producing uni lacquers to the extent that in this case no pre-dispersion or dispersion has to take place. The production sequence is the same as the production sequence when producing uni lacquers beginning with the dose spinners until the filling procedure (see Figures 4.6 and 4.7). [Pg.70]

Silica-based monolithic columns (Figure 9) are generally prepared using sol-gel technology. This involves the preparation of a sol solution and the gelation of the sol to form a network in a continuous liquid phase within the capillary. The precursors for the synthesis of these monoliths are normally metal alkoxides that react readily with water. The most widely used are alkoxysilanes such as tetramethoxysilane (TMOS) and TEOS. [Pg.454]

Today, just about all mercury is produced via the reduction of cinnabar (HgS) by using a reducing agent, such as oxygen, iron, or calcium oxide (CaO). The resulting mercury vapor is passed through water where it liquefies (changes into its normal metallic state and sinks to the bottom of the water bath) while all the impurities float to the surface. [Pg.169]

The opening of a band gap at in the superconducting state can also be interpreted within this framework. The charge carriers of a superconducting state are not individual electrons as in the normal metallic state but electrons coupled in pairs, the so-called Cooper pairs, having opposite wave vectors. Hence, Cooper pairs are described by product functions (p k)(p —k)). Following the discussion given above. [Pg.77]

Among many fascinating properties, quasicrystals with high structural quality, such as the icosahedral AlCuFe and AlPdMn alloys, have unconventional conduction properties when compared with standard intermetallic alloys. Their conductivities can be as low as 450-200 (Qcm) [7]. Furthermore the conductivity increases with disorder and with temperature, a behaviour just at the opposite of that of standard metal. In a sense the most striking property is the so-called inverse Mathiessen rule [8] according to which the increases of conductivity due to different sources of disorder seems to be additive. This is just the opposite that happens with normal metals where the increases of resistivity due to several sources of scattering are additive. Finally the Drude peak which is a signature of a normal metal is also absent in the optical conductivity of these quasicrystals. [Pg.536]


See other pages where Normal metals is mentioned: [Pg.252]    [Pg.16]    [Pg.415]    [Pg.218]    [Pg.2324]    [Pg.644]    [Pg.195]    [Pg.16]    [Pg.361]    [Pg.925]    [Pg.373]    [Pg.90]    [Pg.759]    [Pg.42]    [Pg.111]    [Pg.345]    [Pg.60]    [Pg.185]    [Pg.185]    [Pg.242]    [Pg.330]    [Pg.199]    [Pg.195]    [Pg.36]    [Pg.17]    [Pg.267]    [Pg.56]    [Pg.124]    [Pg.270]    [Pg.380]    [Pg.459]    [Pg.212]    [Pg.663]    [Pg.681]    [Pg.682]   
See also in sourсe #XX -- [ Pg.184 , Pg.206 , Pg.208 , Pg.238 , Pg.251 , Pg.264 ]




SEARCH



© 2024 chempedia.info