Capacity choice

An overview of capillary gas chromatography is presented. Selected environmental applications, such as PCB s in water, PAH s in airborne particulate matter, and TCDD s at the part-per-trillion level illustrate the separation and analysis of complex mixtures. The chromatographic performance, characteristics, and trade-offs of packed and capillary columns are described in terms of permeability and efficiency, sample capacity, choice of stationary phase, high temperature capabilities, quantitative accuracy, and the development of GC separation methods. 

The paper [36] su ests that balancing expected profit with downside risk causes capacity choices to value the benefit of flexible resources in the supply network. 

Table 4.2 Capacity choices and associated expected profit...

Given this service level, the optimal capacity choice... 

This example shows the close interaction between information, lead time, and capacity choice in the presence of demand uncertainty. In the absence of information, capacity buffers are optimal. However, lower lead times may permit better demand information, thus leading to a better match between demand levels and capacity. This enables additional capacity to be planned when there is an upside potential associated with high demand and simultaneously lower capacity when demand levels are anticipated to be low. The net result is a higgler profitability with lowered average capacity levels. 

Capacity Choice to Maintain Service Lead Time... 

Cachon, G. and M. Lariviere. 1999. Capacity choice and allocation strategic behavior and supply chain performance. Management Science. Vol.45, 1091-1108. 

Cachon, G.P. and M.A. Lariviere, Capacity Choice And Allocation Strategic Behavior And Supply Chain Performance, Management Science, 45, 8 (1999(b)), 1091-1108. 

The search for a suitable adsorbent is generally the first step in the development of an adsorption process. A practical adsorbent has four primary requirements selectivity, capacity, mass transfer rate, and long-term stabiUty. The requirement for adequate adsorptive capacity restricts the choice of adsorbents to microporous soUds with pore diameters ranging from a few tenths to a few tens of nanometers. 

The wisest fan choice is frequently not the cheapest fan. A small fan operates well on its curve but may not have adequate capacity for maximum flow control, future needs, or process upset conditions. It may be so lightly constmcted that it is operating near its peak speed with no provision for speed increases in the future, if needed. As fan size is increased, efficiency generally improves and wheel speed is lower. These factors decrease operating cost and provide reserve capacity for the future. However, it is also possible to oversize a fan and impair its performance. 

Oxidation of methanol to formaldehyde with vanadium pentoxide catalyst was first patented in 1921 (90), followed in 1933 by a patent for an iron oxide—molybdenum oxide catalyst (91), which is stiU the choice in the 1990s. Catalysts are improved by modification with small amounts of other metal oxides (92), support on inert carriers (93), and methods of preparation (94,95) and activation (96). In 1952, the first commercial plant using an iron—molybdenum oxide catalyst was put into operation (97). It is estimated that 70% of the new formaldehyde installed capacity is the metal oxide process (98). 

Viscosity Glassifications. The general ISO iatemational viscosity classification system for iadustrial oils is given ia Table 4 from ASTM D2422 (American National Standard Z11.232). For high speed machines, ISO viscosity-grade 32 turbiae and hydrauHc oils are a common choice. ISO grades 68 and 100 are appHed for more load capacity ia slower speed machines where power loss and temperature rise are less of a question. 

Magnesium metal can be manufactured by electrolytic and metaHothermic reduction. The method of choice depends on several variables including raw material availabiUty, location, and integration into other chemical faciUties. Producers and corresponding capacities are shown in Table 2 (see also... 

Among the properties sought in the solvent are low cost, avadabihty, stabiUty, low volatiUty at ambient temperature, limited miscibility in aqueous systems present in the process, no solvent capacity for the salts, good solvent capacity for the acids, and sufficient difference in distribution coefficient of the two acids to permit their separation in the solvent-extraction operation. Practical solvents are C, C, and alcohols. For industrial process, alcohols are the best choice (see Amyl alcohols). Small quantities of potassium nitrate continue to be produced from natural sources, eg, the caUche deposits in Chile. 

Flexible Tube. The simplicity of design and the absence of seals and valves make the flexible tube or peristaltic pump a good choice for low capacity and low pressure appHcations in the pharmaceutical industry or wherever shear-sensitive or moderately abrasive fluids are pumped. Because of the continuous flexing of the tube, the tube material of constmction presents a challenge regarding life cycle. For the same reason, pressures are kept relatively low. 

The reduction ia tetraethyl lead for gasoline production is expected to iacrease the demand for petroleum alkylate both ia the U.S. and abroad. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used. However, concerns over the safety or potential regulation of hydrofluoric acid seem likely to convince more refiners to use the sulfuric acid process for future alkylate capacity. 

Cell-Free Hemoglobin. Hemoglobin seems to be the logical choice for a red cell substitute because of its high capacity to carry oxygen (Fig. 

Extraction and Extractive Distillation. The choice of an extraction or extractive distillation solvent depends upon its boiling point, polarity, thermal stabiUty, selectivity, aromatics capacity, and upon the feed aromatic content (see Extraction). Capacity, defined as the quantity of material that is extracted from the feed by a given quantity of solvent, must be balanced against selectivity, defined as the degree to which the solvent extracts the aromatics in the feed in preference to paraffins and other materials. Most high capacity solvents have low selectivity. The ultimate choice of solvent is deterrnined by economics. The most important extraction processes use either sulfolane or glycols as the polar extraction solvent. 

---