Calcium sulfate from waste

Calcilox A process for converting calcium sulfate/sulfite wastes from flue-gas desulfurization into a disposable, earthy material, by use of a proprietary inorganic additive made from blast furnace slag. Developed by Dravo Corporation of Pittsburgh, PA. 

Sintema A process for stabilizing the calcium sulfate/sulfite waste produced by FGD so that it may be used for landfill. The waste is mixed with ash from a coal-fired power station, pelletized, and sintered. Developed in the 1970s by Battelle Columbus Laboratories, OH, under contract with Industrial Resources. See also Fersona. 

Guillini A process for making gypsum from the waste product from the Wet Process for making phosphoric acid. The waste is heated with water in an autoclave this removes impurities and converts the calcium sulfate dihydrate to the hemi-hydrate. 

Hard" water contains impurities dissolved in it, such as chalk, and when ordinary soap is put into hard water, a precipitate, or scum, forms. This is not only unattractive, it is also wasteful, since it prevents the soap from doing its job until all the chemicals causing the scum have been pushed out of the water. One of the main chemical ingredients of hard water is calcium sulfate. 

Fig. 1. Schematic flowsheet of uranium processing (acid leach and ion exchange) operation. Numbers refer to the numbers that appear in the boxes on the flowsheet. Operations (3), (6), (9), and (11) may be done by thickening or filtration. Most often, thickeners are used, followed by filters. The pH of the leach slurry <4) is elevated to reduce its corrosive effect and to improve the ion-exchange operation on the uranium liquor subsequently separated, In tile ion exchange operation (7), resin contained in closed columns is alternately loaded with uranium and then eluted. The resin adsorbs the complex anions, such as UC fSO 4-. in which the uranium is present in the leach solution. Ammonium nitrate is nsed for elution, obtained by recycling the uranium filtrate liquor after pH adjustment. Iron adsoibed with the uranium is eluted with it. Iron separation operation (8) is needed inasmuch as the iron hydroxide slurry is heavily contaminated with calcium sulfate and coprecipitated uranium salts. Therefore, the slurry is recycled to the watering stage (3). Washed solids from 1,6). the waste barren liquor from (7), and the uranium filtrate from (11) are combined. The pH is elevated to 7.5 by adding lime slurry before the mixture is pumped to the tailings disposal area. (Rio Algom Mines Limited, Toronto)...

Units called flue gas desulfurisation (FGD) units are being fitted to some power stations throughout the world to prevent the emission of sulfur dioxide gas. Here, the sulfur dioxide gas is removed from the waste gases by passing them through calcium hydroxide slurry. This not only removes the sulfur dioxide but also creates calcium sulfate, which can be sold to produce plasterboard (Figure 11.25). The FGD units are very expensive and therefore the sale of the calcium sulfate is an important economic part of the process. 

There is no current commercial biologic process for the production of succinic acid. In past laboratory systems, when succinic acid has been produced by fermentation, lime is added to the fermentation medium to neutralize the acid, yielding calcium succinate (2). The calcium succinate salt then precipitates out of the solution. Subsequently, sulfuric acid is added to the salt to produce the free soluble succinic acid and solid calcium sulfate (gypsum). The acid is then purified with several washings over a sorbent to remove impurities. The disposal of the solid waste is both a directly economic and an environmental concern, as is the cost of the raw materials. Some key process-related problems have been identified as follows (1) the separation of dilute product streams and the related costs of recovery, (2) the elimination of the salt waste from the current purification process, and (3) the reduction of inhibition to the product succinic acid on the fermentation itself. Acetic acid is also a byproduct of the fermentation of glucose by Anaerobiospirillium succiniciproducens almost 1 mol of acetate will be produced for every 2 mol of succinate (3). Under certain cultivation conditions by a mutant Escherichia coli, lesser amounts of acetate can be produced (4,5). This byproduct will also need to be separated. 

Coupled with the energy consumption is the environmental effect from production of these binders. For every ton of phosphoric acid, 5 ton of phosphogypsum (calcium sulfate) is produced [15]. This waste can be recycled into value-added products such as gypsum board, but often there is a radioactivity issue. Some phosphogypsum contains radium and emanates radon gas. At the present time, such waste can only be disposed in a landfill. 

Land pollution from mining wastes and disposal of scrubber sludge, i.e., calcium sulfate... 

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