Brown iron oxides

Transparent brown iron oxides are produced by precipitating iron(II) salt solutions with dilute alkali (sodium hydroxide or sodium carbonate) and oxidizing with air. Only two-thirds of the precipitated iron hydroxide, oxide hydrate, or carbonate is oxidized. Alternatively, the iron oxides can be produced by complete oxidation of... 

In the extraction of iron, the oxide is reduced to metallic iron. On the other hand, the oxidation of iron to produce the brown iron oxide commonly known as rust is the opposite reaction to the production of the metal from the oxide. The extraction of iron from the oxide, must be conducted with utmost careful control of the conditions, such that the backward reaction is prevented. 

Fe salt solutions are precipitated and oxidized to black or brown iron oxide. 

I n this sense, fouling means deposition of reactor debris on the particles. Scale, rust, and other corrosion products arc all possibilities, in addition to chemical components from up-stream units. Particles removed from reactors often have red-brown iron oxide crusts on the outside. Calcium compounds are also found. The most severe cases occur in processing coal and coal-derived liquids, which contain large amounts of inorganic mineral matter. 

The penetrability of plasticized PE films containing MTet VCI towards iron ions was estimated in [5,6] visually judging by the color of 0.01 N aqua solution of Na2S04 with immersed steel electrodes sealed with the inhibited film. The samples were kept in the electrolyte at room temperature for three months. The Na2S04 solution did not change its color from the yellow-green hues characteristic of bivalent and trivalent iron solutions during the specified time. The film material averted the removal of iron cations from the zone of the electrochemical reaction and small amounts of corrosion products in the form of brown iron oxides remained beneath the film. 

Galvanic Cell Formation When dissimilar metals are in contact in an electrolyte, a galvanic cell is established because of the electrochemical potential difference (24). The consequence of the galvanic cell is the corrosion of the less noble metal. For example, when copper is in contact with iron in the presence of an electrolyte, the iron anode will corrode to generated Fe " " ions, which on further reaction with oxygen forms brown iron oxide while oxygen reduction occurs at the copper cathode. The reactions are... 

Red and brown Iron oxide provides a dull red or brown pigmentation, depending on the iron s oxidation state Cadmium/selenium compounds are also used for reds. 

Burnt sienna. See Iron oxide brown Iron oxide red... 

See also Cl 77492 Cl 77499 Ferric oxide Ferrous oxide Iron oxide black Iron oxide brown Iron oxide red Iron oxide yellow Iron oxide yellow monohydrate... 

Deposits of brown iron oxide flakes on plants and stones in the water indicate a water source with high iron content flowing into the surface water. Often... 

Metallic brown See brown iron oxide pigment. 

Validation of the cleaning process has to be done before operating. As difficult to clean objects utensils contaminated with zinc oxide paste (if desired with 3 % brown iron oxide) can be recommended. The validation should be repeated periodically, e.g. yearly, or at any time utensils are not clean after washing up or when new utensils are introduced. Results should be documented. 

Single-phase brown oxides of iron can be synthesized by controlled oxidation of black iron oxides. Different tones of brown can be prepared by controlling the oxidation process, and hence controlling the amount of Fe Og (red). Synthetic brown iron oxide is also synthesized by calcination of a-FeOOlT with controlled quantities of manganese compounds. These pigments are not widely used in... 

Metallic Brown See Brown Iron Oxide Pigment. 

For products for outdoor use, such as bottles and shipping crates made from HDPE, the following pigments are recommended white opac (rutile Ti02 after-treated), yellow (cadmium yellow, nickel titanium yellow, chrome titanium yellow), red (cadmium red, iron oxide red), blue (cobalt blue, ultramarine blue), green (cobalt green, chrome oxide green), brown (iron oxide brown, chrome iron brown), black (carbon black-furnace). 

See 1.1 and 1.2 above for white residue brown, iron oxide is corrosion product or precipitate due to oxygen... 

Most of the browns used in the coatings industry are brown iron oxide colors. These are essentially combinations of red and black iron oxides, offering very good coverage, excellent durability, good resistance to light and alkalies. They are suitable for both water- and solvent-based paints and either interior or exterior finishes. 

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