Brass composition

The patented wire is again cleaned with acid, rinsed, and brass plated just before the second drawing. The brass acts as a drawing lubricant and as well as an adhesive to mbber. The brass composition is typically 60—70% copper with 2inc as the remainder. The patented, brass-plated wire is drawn into filaments of 0.15—0.38 mm diameter. 

What steel and brass compositions and what surface roughness values were used for the discs ... 

The brass composition and also its surface composition are important, and adhesion is only obtained within rather narrow limits of copper percentages (roughly 65 -75%) and oxide film thickness. In other words, the surface preparation of the brass is very important. 

Effect of Brass Composition and Plating Weight on Brass Reactivity and Adhesion... 

TABLE E.5 Wrought-Brasses—Standard Designations for Wrought Brasses (Composition as Maximum % Uniess indicated as Range or Minimum)... 

The composition of the builders in an alkaline cleaner is dependent on the metal substrate from which the soil is to be removed. For steel (qv) or stainless steel aggressive, ie, high pH, alkaline salts such as sodium or potassium hydroxide can be used as the main alkaline builder. For aluminum, zinc, brass, or tin plate, less aggressive (lower pH) builders such as sodium or potassium siUcates, mono- and diphosphates, borates, and bicarbonates are used. 

Phosphorized deoxidized arsenical copper (alloy 142 (23)) is used for heat exchangers and condenser tubes. Copper-arsenical leaded Muntz metal (alloy 366), Admiralty brass (alloy 443), naval brass (alloy 465), and aluminum brass (alloy 687), all find use in condensers, evaporators, ferrules, and heat exchanger and distillation tubes. The composition of these alloys is Hsted in Table 5. 

Steel, copper, and brass fiber may have a variety of aspect ratios, shape, ie, straight versus curved fibers and cross-sectional geometry, surface roughness, and chemical compositions. Fibers having tight specifications in terms of cleanliness, chemical composition, and aspect ratio ate necessary. The fibers are usually machined from larger metallic forms. 

Table 16 illustrates the property enhancements and tradeoffs seen when tin is added to a copper—zinc brass base composition. The most commonly used alloys for electrical connectors are the Cu—10 Zn—Sn brasses, such as C411, C422, and C425. These lower level zinc—tin alloys offer good corrosion resistance along with the good formabiHty, conductivity, and strength levels of brass. 

Admiralty Brass and Naval Brass are 30 and 40% zinc alloys, respectively, to which a 1% tin addition has been added. Resistance to dezincification of Cu—Zn alloys is increased by tin additions. Therefore, these alloys are important for thein corrosion resistance in condenser tube appHcations. In these, as weU as the other higher zinc compositions, it is common to use other alloying additives to enhance corrosion resistance. In particular, a small amount (0.02—0.10 wt %) of arsenic (C443), antimony (C444), or phosphoms (C445) is added to control dezincification. When any of these elements are used, the alloy is referred as being "inhibited." For good stress corrosion resistance, it is recommended that these alloys be used in the fiiUy annealed condition or in the cold worked plus stress reHef annealed condition. 

Certain conditions, ultimately dictated by economics, make the substitution of more resistant materials a wise choice. Stainless steels (not sensitized) of any grade or composition do not form tubercles in oxygenated water neither do brasses, cupronickels, titanium, or aluminum. However, each of these alloys may suffer other problems that would preclude their use in a specific environment. 

In any specific environment, only certain alloys are affected. Substitution of more resistant materials does not always necessitate major alloy compositional changes. Adding as little as a few hundredths of a percent of arsenic, for example, can markedly reduce dezincification in cartridge brass. Antimony and phosphorus additions up to 0.1% are similarly efficacious. 

Substances such as brass, wood, sea water, and detergent formulations are mixtures of chemicals. Two samples of brass may differ in composition, colour and density. Different pieces of wood of the same species may differ in hardness and colour. One sample of sea water may contain more salt and different proportions of trace compounds than another. Detergent formulations differ... 

Changes observed in the composition of the rubber/brass interphase correlated well with results of adhesion tests carried out on brass-plated steel wires embedded in blocks of rubber [46]. The force required to pull the wires out of the blocks decreased steadily as vulcanization temperature increased. This effect was especially pronounced when the specimens were aged at elevated temperature and humidity for several days before the wires were pulled out of the rubber blocks. 

Single-phase a-brasses are susceptible to stress-corrosion cracking in the presence of moist ammonia vapour or certain ammonium compounds Here the predominant metallurgical variable is alloy composition, and in... 

Turner, M. E.., Further Studies on the Influence of Water Composition on the Dezincihcation of Duplex Brass Fittings , Proc. Soc. Water Treat. Exam., 14, 81 (1965) C.A., 63, 15984e Frade, G. and Lacombe, P., Influence of Intergranular Diffusion in the Kinetics of Dezincihcation of 70/30 Brasses Without Additions at 450-900 C , Compt. Rend., 260, 5022 (1965) C.A., 63, 5323c... 

Many workershave investigated the residual stresses introduced by different working processes in brasses of various compositions and the... 

However, whilst the effects of change in alloy composition upon stress-corrosion cracking susceptibility in the present context may be partly due to their effect upon stacking-fault energy, this does not constitute a complete explanation, since alloying may have significant effects upon electrochemical parameters. The effect of the zinc content of brasses upon their filming characteristics has already been mentioned, while in more recent... 

It is hardly surprising that the preparation of surfaces of plain specimens for stress-corrosion tests can sometimes exert a marked influence upon results. Heat treatments carried out on specimens after their preparation is otherwise completed can produce barely perceptible changes in surface composition, e.g. decarburisation of steels or dezincification of brasses, that promote quite dramatic changes in stress-corrosion resistance. Similarly, oxide films, especially if formed at high temperatures during heat treatment or working, may influence results, especially through their effects upon the corrosion potential. 

Brass deposits normally contain 70-80% copper and 30-20% zinc the colour does not normally match solid brass of the same composition and may, moreover, vary with the operating conditions and solution composition. 

---