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Benzylic methyl

The student should note that ketones in class (1), t.c., those having the >CO group in the side chain, will form additive compounds with sodium bisulphite only if this >CO group is not directly joined to the benzene ring acetophenone therefore will not form such compounds, whereas benzyl methyl ketone, CaHsCHjCOCH, will do so. Many quinones, particularly ortho quinones such as phenanthraquinone, form additive compounds with sodium bisulphite. [Pg.257]

Propiophcnone Benzyl methyl ketone Benzyl ethyl, Benzophenone. p Chloro- ... [Pg.540]

Ph.CH2.OMe, Ph.(CH2)2.0Me, Ph.(CH2)3.0Me (2-3, 3-4, 1-3), does not decrease steadily, but goes through a maximum. These two circumstances point to a specific -interaction in nitrations of the ethers with acetyl nitrate which is important with benzyl methyl ether, more important with methyl phenethyl ether, and not important with methyl phenpropyl ether. This interaction is the reaction with dinitrogen pentoxide already mentioned, and the variation in its importance is thought to be due to the different sizes of the rings formed in the transition states from the different ethers. [Pg.102]

The argtiments of Norman and his co-workers seem to give affirmative answers to the first and second of these questions, but it is doubtful if the available data further require such an answer for the third question. It can be argued that the crucial comparison made between the behaviour of benzyltrimethylammonium ion and protonated benzyl methyl ether is invalid, and that it is possible to interpret the results in terms of nitration by the nitronium ion, modified by protonation of the oxygen atom of the ether a case for the possible involvement of the nitro-nium ion in specific interaction leading to o-substitution has been made. ... [Pg.103]

Two moles of diphenylacetylene insert into the benzyl methyl sulfide complex 481 to afford the eight-membered heterocycle 482[440j. The cinnolinium Salt 483 is prepared by the insertion of alkynes into the azobenzene com-plex[44l]. [Pg.89]

Methamphetannne is a notorious street drug One synthesis involves reductive amination of benzyl methyl ketone with methylamine What is the structure of methamphetamine ... [Pg.968]

Section 27 16 Carboxyl groups are normally protected as benzyl methyl or ethyl esters Hydrolysis m dilute base is normally used to deprotect methyl and ethyl esters Benzyl protecting groups are removed by hydrogenolysis... [Pg.1151]

SuIfona.tlon, Sulfonation is a common reaction with dialkyl sulfates, either by slow decomposition on heating with the release of SO or by attack at the sulfur end of the O—S bond (63). Reaction products are usually the dimethyl ether, methanol, sulfonic acid, and methyl sulfonates, corresponding to both routes. Reactive aromatics are commonly those with higher reactivity to electrophilic substitution at temperatures > 100° C. Tn phenylamine, diphenylmethylamine, anisole, and diphenyl ether exhibit ring sulfonation at 150—160°C, 140°C, 155—160°C, and 180—190°C, respectively, but diphenyl ketone and benzyl methyl ether do not react up to 190°C. Diphenyl amine methylates and then sulfonates. Catalysis of sulfonation of anthraquinone by dimethyl sulfate occurs with thaHium(III) oxide or mercury(II) oxide at 170°C. Alkyl interchange also gives sulfation. [Pg.200]

The type of synthesis in which the two-atom fragment supplies C-5 + C-6 is uncommon but useful in preparing pyrimidine- and 5,6,7,8-tetrahydroquinazoline-2,4-diamines. Thus, dicyandiamide (S78) with benzyl methyl ketone (S77) yields 6-methyl-5-phenylpyrimidine-2,4-diamine (S79), or with acetophenone it yields 6-phenylpyrimidine-2,4-diamine (62JOC2708). Likewise, with cyclohexanone it yields the tetrahydroquinazolinediamine (SSO) and by using N- substituted dicyandiamides, 2- and/or 4-alkylamino groups may be introduced (65JOC1837). [Pg.111]

Adenine, 9-y3-D-arabinofuranosyl-occurrence, 5, 602 as pharmaceutical, 1, 160 Adenine, N -benzoyl-glycosylation, 5, 536 Adenine, 1-benzyl-benzylation, 5, 530 Adenine, 3-benzyl-benzylation, 5, 530 N NMR, 5, 515 synthesis, 5, 594 Adenine, 6-benzyl- N NMR, 5, 515 Adenine, 7-benzyl-benzylation, 5, 530 Adenine, N -benzyl-methylation, 5, 530 occurrence, 5, 602... [Pg.512]

Imidazolidin-2-one, l-(5-nitro-2-thiazolyl)-pharmacological activity, 6, 328 Imidazolidin-4-one, l-aryl-3-phenyl-2-thioxo- C NM S, 355 Imidazolidinones C NMR, 5, 355 Imidazolidin-2-ones nucleophilic displacement, 5, 428 polymers, 1, 279-280 reactivity, 5, 376 synthesis, 5, 466, 471 Imidazolidin-4-ones synthesis, 5, 468 Imidazoline, 2-alkyl-synthesis, 5, 463 Imidazoline, 2-amino-applications, 5, 498 Imidazoline, 2-aryl-synthesis, 5, 463 Imidazoline, 2-methyl-synthesis, 5, 487 Imidazoline, 2-nitroamino-synthesis, 5, 471 2-Imidazoline, 2-arylamino-tautomerism, 5, 368 2-Imidazoline, 1-benzyl-methylation, 5, 425 2-Imidazoline, 1,2-diaryl-synthesis, 5, 463... [Pg.657]

Penicillin V—see Penicillin, phenoxymethyl-, 7, 300 Penicilloate, benzyl-, 7, 303 Penicilloate, D-a-benzyl-a-methyl ester, 7, 303 Penillamine, benzyl-, 7, 303 Penillic acid, benzyl-, 7, 303 Penilloaldehyde, benzyl-, 7, 303 Penilloic acid, benzyl-, 7, 303 Penillonic acid, benzyl-methyl ester, 7, 303 1,2,3,4,6-Pentaazaindene nomenclature, 1, 18 Pentadeca-5,10-dienols synthesis, 1, 428 Pentadienol, tetrachloro-2H-pyran synthesis from, 3, 740 Pentadienonitrile, 5-(l,2-benzoselenazol-3-yl)-X-ray diffraction, 6, 334 Penta-2,4-dienonitrile, 5-(dimethylamino)-2-(2-thienyl)-... [Pg.738]

This method was also used to prepare the benzyl, methyl, ethyl, and p-methoxybenzyl derivatives. A polymeric version of the reagent was also described. [Pg.328]

Carbocations can also be generated during the electrolysis, and they give rise to alcohols and alkenes. The carbocations are presumably formed by an oxidation of the radical at the electrode before it reacts or diffuses into solution. For example, an investigation of the electrolysis of phenylacetic acid in methanol has led to the identification of benzyl methyl ether (30%), toluene (1%), benzaldehyde dimethylacetal (1%), methyl phenylacetate (6%), and benzyl alcohol (5%), in addition to the coupling product bibenzyl (26%). ... [Pg.727]

C6H5CH2CCH3 -F HOCH2CH2OH — Benzyl methyl ketone Ethylene glycol... [Pg.722]

Section 27.16 Carboxyl groups are normally protected as benzyl, methyl, or ethyl esters. [Pg.1151]

There exist three isomers of phenyl-propyl alcohol, all of which have been prepared and described, and, although not yet introduced into commerce, may eventually be so. These are as follows Benzyl-methyl-carbinol, CgHj. CHj. CH(OH)CHg, boiling at 215° phenyl-ethyl-carbinol, CgHg. CH(OH)CH2. CHg, boiling at 221° and benzyl-dimethyl-carbinol, C Hg. C(OH)(CHg)2, melting at 21° and boiling at 225°. [Pg.128]

The Md NMR spectrum of /)-bromotoluene, shown in Figure 15.15, displays many of the features just discussed. The aromatic protons appear as two doublets at 7.02 and 7.45 8, and the benzylic methyl protons absorb as a sharp singlet at 2.29 8. Integration of the spectrum shows the expected 2 2 3 ratio of peak areas. [Pg.536]

This procedure represents a simple and unique route to certain pyran-4-ones. The reaction can be applied also to benzyl methyl ketone and diethyl ketone the corresponding pyran-4-ones are obtained in yields of 48% and 26%, respectively. [Pg.56]

In the case of the condensation of benzyl methyl sulfoxide with bcnzaldchydc (40% yield), the diastereomeric ratio of four enantiomeric (S-sulfinyl alcohols after immediate workup is 41 19 8 32 . [Pg.644]

C8H10O2S, Benzyl methyl sulfone [(Methylsulfonyl)methyl]benzene ... [Pg.98]

Formation of optically active sulphoxides was found to occur during oxidation of sulphides in the presence of chiral catalysts. Thus, the oxidation of benzyl methyl sulphide... [Pg.291]


See other pages where Benzylic methyl is mentioned: [Pg.559]    [Pg.317]    [Pg.673]    [Pg.743]    [Pg.100]    [Pg.102]    [Pg.166]    [Pg.240]    [Pg.241]    [Pg.695]    [Pg.695]    [Pg.722]    [Pg.756]    [Pg.539]    [Pg.539]    [Pg.583]    [Pg.583]    [Pg.314]    [Pg.695]    [Pg.695]    [Pg.756]    [Pg.14]    [Pg.259]    [Pg.39]    [Pg.490]    [Pg.227]   
See also in sourсe #XX -- [ Pg.229 ]




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1 - benzyl - 5 - formyl - 2 - methyl

1 -Benzyl-2,4-dialkyl-5-hydroxy-methyl

1,2,3 triazole benzyl methyl ketone

2- Benzyl-3-methyl-pyrazole 1 -oxide

2-Methyl-3-benzyl-6,7 -dimethoxy-3,4-dihydro

2-Propanone, 1-phenyl- [Benzyl methyl

2-Propanone, 1-phenyl- [Benzyl methyl ketone

3-Benzyl-5- -4-methyl-1,3-thiazolium chloride

3-Benzyl-5-methyl-2-pyrazinamine

3-Benzyl-5-methyl-2-pyrazinamine 1-oxide

3-benzyl-2-methyl- -trifluoromethanesulfonate

4- Methoxy- benzyl methyl

4- Methoxy- benzyl methyl ketone

4-Benzyl-2-methyl-1 -phthalazinone

4-benzyl-2-methyl-5 -oxazolone

4-benzyl-3,5-dioxo-2-methyl

6- Benzyl-3-methyl-3-nitro

6-Amino-5-benzyl-3-methyl-2 pyrazinone

6-Benzyl-3-methyl-1,2,4-triazolo

A-Methyl benzyl alcohol

A-Methyl benzyl cation/methanol adducts

Aromatic systems protonated benzyl methyl

Benzyl 2-Methyl Propionate

Benzyl 3-Methyl Butyrate

Benzyl alcohol, o-methyl

Benzyl carbinyl hypochlorites methyl-substituted photolysis

Benzyl cations a-methyl

Benzyl chloride reaction with methyl acrylate

Benzyl methyl amine

Benzyl methyl carbonate

Benzyl methyl carbonate reactions with

Benzyl methyl disulfide

Benzyl methyl ether

Benzyl methyl ether, cleavage

Benzyl methyl ether, hydrogenolysis

Benzyl methyl ether, substituted

Benzyl methyl ketone formation

Benzyl methyl ketone, 2-hydroxylation

Benzyl methyl malonate

Benzyl methyl sulfate

Benzyl methyl sulfone

Benzyl methyl sulphide

Benzyl methyl sulphone

Benzyl-cthyl-methyl

Benzyl-methyl-propyl

Chloro methyl benzyl ether

Chromatographic Separation of Benzyl Alcohol and Methyl Benzoate

Ether, benzyl methyl deprotonation

Ether, benzyl methyl oxidation

Ethers benzyl methyl, formation

Ethers, benzyl methyl reductive cleavage

Ethyl 1 - benzyl - 2 - methyl - 4 -

Fructofuranoside, benzyl methyl

L-Benzyl-5-methyl

M-Methyl benzyl chloride

Methyl 2,3,4-tri-O-benzyl-a-D-glucopyranosid

Methyl [benzyl 2-

Methyl [benzyl 2-

Methyl benzyl alcohol

Methyl benzyl carbinol

Methyl benzyl ketone

Methyl benzyl methacrylate

Methyl substitution benzyl carbinyl hypochlorite photolysis

Methylal acid benzyl ester

P-Methyl benzyl alcohol

Palladium benzyl methyl

Photolysis methyl substituted-benzyl carbinyl

Pyrrole 3 - acetyl - 1 - benzyl - 2 - methyl 4 -

Pyrrole, 2-benzyl-5-methyl

Ruthenium tetroxide benzyl methyl ether

Sulfide, benzyl methyl

Sulfide, benzyl methyl chlorination

Sulfon 4-Amino-benzyl)-methyl

Sulfoxide, benzyl methyl

Sulfoxide, benzyl methyl carbanion

Tolyl carbinol (p-methyl benzyl alcohol)

Vinyl benzyl methyl ether

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