Bentonite clay, properties

Features Improved cure fimes generally used in combination with bentonite clay Properties Cationic BFP 74 [Am. Ingreds.]... 

A variety of additives are used to control the properties of wetting and dispersion of pigments, flow, Hthography, and mb-off of inks. These additives belong to classes of materials such as surfactants, bentonite clays, alkyds, functional resins, polymers, etc. 

For the most part, additives control the appHcation or theological properties of a paint. These additives include materials for latex paints such as hydroxyethylceUulose, hydrophobicaHy modified alkah-soluble emulsions, and hydrophobicaHy modified ethylene oxide urethanes. Solvent-based alkyd paints typically use castor oil derivatives and attapulgite and bentonite clays. The volume soHds of a paint is an equally important physical property affecting the apphcation and theological properties. Without adequate volume soHds, the desired appHcation and theological properties may be impossible to achieve, no matter how much or many additives are incorporated into the paint. 

Bentonite is an impure clay that is formed by weathering of volcanic tuffs. It contains a high content of montmorillonite. Bentonites exhibit properties such as ability to swell, ion exchange, and thixotropy. Properties can be modified by ion exchange, for example, exchange of earth alkali metals to alkali metals. The specific surface can be modified with acid treatment. Organophilic properties can be increased by treatment with quaternary ammonia compounds. 

P. M. Bauer, D. J. Hanlon, and W. R. Menking. Process for producing bentonite clays exhibiting enhanced solution viscosity properties. Patent US 5248641, 1993. 

Clays used in foundries include hydrous alumina silicates, known as bentonites. Their properties provide cohesion and plasticity in the green state and also high strength when dried. There are three clays that are commonly used in foundries western bentonite [sodium bentonite, burnout point 1290°C (2350°F)], southern bentonite [calcium bentonite, burnout point 1065°C (1950°F)], and fire clay [kaolinite, burnout point 1425°C (2600°F)]. 

For compacted, low-permeability soil liners, the U.S. EPA draft guidance recommends natural soil materials, such as clays and silts. However, soils amended or blended with different additives (e.g., lime, cement, bentonite clays, and borrow clays) may also meet the current selection criteria of low hydraulic conductivity, or permeability, and sufficient thickness to prevent hazardous constituent migration out of the landfill unit. Therefore, U.S. EPA does not exclude compacted soil liners that contain these amendments. Additional factors affecting the design and construction of CCLs include plasticity index (PI), Atterburg limits, grain sizes, clay mineralogy, and attenuation properties. 

Geothermal cements are also employed to fix the steel wellbore casing in place and tie it to the surrounding rock (8). These are prepared as slurries of Portland cement (qv) in water and pumped into place. Additional components such as silica flour, perlite, and bentonite clay are often added to modify the flow properties and stability of the cement, and a retarder is usually added to the mixture to assure that the cement does not set up prematurely. Cements must bond well to both steel and rock, be noncorrosive, and water impermeable after setting. In hydrothermal applications, temperature stability is critical. Temperature cycling of wellbores as a result of an intermittent production schedule can cause rupture of the cement, leading to movement and, ultimately, failure of the wellbore casing. 

In this chapter, the relationship of geological origins and interfacial properties of bentonite clay will be reviewed first. Then we will discuss the migration of water-soluble substances in rocks and soil, and the effect of sorption on the migration. A linear model will be derived by which the quantity of ion sorbed on rocks can be estimated when the mineral composition and sorption parameters of the mineral components are known. Surface acid-base properties of soils will be discussed, and the sorption of an anion (cyanide ion) will be shown on different soils and sediments. 

RELATIONSHIP BETWEEN INTERFACIAL PROPERTIES AND GEOLOGICAL ORIGIN OF BENTONITE CLAY... 

Bentonite rocks have many uses in the chemical and oil industries and also in agriculture and environmental protection. The usefulness of bentonite for each of these applications is based on its interfacial properties. These properties are determined by geological origin, chemical and mineral composition (especially montmorillonite content), and particle size distribution, and they include the specific surface area (internal and external), cation-exchange capacity (CEC), acid-base properties of the edge sites, viscosity, swelling, water permeability, adsorption of different substances, and migration rate of soluble substances in bentonite clay. 

Some physieal-mechanieal properties of nanocomposites produced by in situ method, and also produeed via melt blending polyethyleneterephthalate with organomodified montmorillonite (nalchikit-M), educed from bentonite clay of Gerpegezh field (Russia, KBR) and from eommercial clay bentonite-128. 

At lowest shear stresses the behavior of bentonite clays may be the same as that of a solid-like system with high viscosity, which is consistent with the Kelvin model and corresponds to region I. The investigation of relaxation properties of coagulation structures forming in these moderately concentrated dispersions of bentonite clays revealed the existence of an elastic aftereffect at low shear stresses. This aftereffect is related to mutual coorientation of anisometric particles that are capable of taking part in rotational Brownian motion without any rupture of contacts. Consequently, the nature of elastic aftereffect is entropic. In such systems high viscosities are related... 

The achieved data clearly demonstrate that the different interactions of bentonite clay and polyphenol with Al or Fe hydrolytic products led to the formation of aggregates with peculiar surface properties and physical-chemical behavior, with particular reference to the P sorption/desorption phenomena. 

We here showed that for bentonite clay, we can determine the nano-scale material properties such as diffusion coefficient and viscosity by molecular dynamics (MD) simulation and extend the microscale characteristics to the macroscale behavior by the multiscale homogenization analysis (HA) method. A seepage flow and diffusion problem is treated. The micro/macro problem can be simulated well by this procedure if we know the microscale geometrical characteristics. 

Rheopectic fluids. These fluids are quite rare in occurrence and exhibit a reversible increase in shear stress with time at a constant rate of shear. Examples are bentonite clay suspensions, certain sols, and gypsum suspensions. In design procedures for thixotropic and rheopectic fluids for steady flow in pipes, the limiting flow-property values at a constant rate of shear are sometimes used (S2, W3). 

---