Anion, name origin

Figure 21 indicates the anion interstitial currents through the layers. The coordinate system is chosen to be the same as that already utilized for cation interstitial diffusion, namely that illustrated in Fig. 18. Because all anion interstitials originate at the oxygen interface, the anion interstitial currents decrease in magnitude in the order i + 1, i, i — 1,. . . , as noted in Fig. 21. The difference current Jf(ai) — J VI serves to increase the thickness...

Fluorescence and phosphorescence are emission processes which originate directly or indirectly (see 5 section ll.B) from the electronically excited singlet state and triplet state, respectively, produced by charge-transfer processes (Eqs. 1 and 2). Many publications deal with such charge-transfer transitions by diffuse reflectance spectroscopy (DRS) (2-6) showing the link between the latter technique and photoluminescence. It is worthwhile to recall that the emergence of the coordination chemistry of solid-state anions, namely, of surface lattice oxide ions, has almost entirely been based on the results of both photoluminescence and DRS analyses (7, 66). For some catalytic systems, vibrational structures can be detected (see Section IV.B) with an associated vibrational constant, which may be determined directly and independently by IR or Raman spectroscopy, evidencing the relation between these spectroscopies and photoluminescence (33, 34). 

Acid Dyes. These water-soluble anionic dyes ate appHed to nylon, wool, sUk, and modified acryHcs. They ate also used to some extent for paper, leather, food, and cosmetics. The original members of this class aU had one or mote sulfonic or catboxyHc acid groups in thein molecules. This characteristic probably gave the class its name. Chemically, the acid dyes consist of azo (including preformed metal complexes), anthraquiaone, and ttiaryHnethane compounds with a few azHie, xanthene, ketone imine, nitro, nitroso, and quHiophthalone compounds. 

If the complex has an overall negative charge (an anionic complex), the suffix -ate is added to the stem of the metal s name. If the symbol of the metal originates from a Latin name (as listed in Appendix 2D), then the Latin stem is used. For example, the symbol for iron is Fe, from the Latin ferrum. Therefore, any anionic complex of iron ends with -ferrate followed by the oxidation number of the metal in Roman numerals ... 

The retro Diels-Alder reaction is strongly accelerated when an oxide anion substituent is incorporated at positions 1 and 2 of the six-membered ring which has to be cycloreversed, namely at one terminus carbon of the original diene or at one sp carbon of the dienophile [51] (Equation 1.22). 

Free cyanide is the primary toxic agent in the aquatic environment. Free cyanide refers to the sum of molecular HCN and the cyanide anion (CN ), regardless of origin. In aqueous solution with pH 9.2 and lower, the majority of the free cyanide is in the form of molecular HCN. The chemical names for HCN include hydrogen cyanide, hydrocyanic acid, cyanohydric acid, and prussic acid. 

This nuance of the original Sr I mechanism may thus occur in quite a number of cases. Nomenclature purists may consider it necessary to find other symbols to name this mechanism and, presumably, to question the adequacy of the 1 in this case. Beyond symbols, if the Sr I mechanism is viewed as an outer sphere electron-transfer-induced nucleophilic substitution , a possible designation of the mechanism under discussion might be dissociative electron-transfer-induced nucleophilic substitution . The original designation of these reactions as nucleophilic reactions proceeding via anion radical intermediates (Komblum, 1975) would still apply to both nuances of the mechanism since, in the present case, RNu is an essential intermediate in the reaction, even if RX is not. 

This system is additive and was developed originally to name coordination compounds, although it can be used in other circumstances when appropriate. For a discussion, see the Nomenclature of Inorganic Chemistry, Chapter 10. The compound to be named is considered as a central atom together with its ligands, and the name is developed by assembling the individual names of the constituents. This system has also been applied to name oxoacids and the related anions. Coordination names for oxoanions are cited in the examples throughout the text, and they are presented in detail in Section 4.4.5 (p. 69). 

While the selective interactions of functionalised calixarenes with cations have been studied broadly for almost three decades, the application of cal-ixarene-based receptors for anion recognition is a relatively new research topic [2]. This review is focused on recent developments in the design and synthesis of calixarene-based anion receptors. Although the name calixarene was originally designated only for phenol-formaldehyde derivatives 1, recently many structural variations and mutations have been formed. Some of them, such as calixpyrroles [3], are widely used for anion recognition nevertheless, this review is restricted only to classical calixarenes 1 and newly discovered thiacalix-arenes 2 [4]. 

---