Acetic acid -, methyl ester

Chemical Designations - Synonyms Acetic acid, methyl ester Chemical Formula CH3COOCH3. Observable Characteristics - Physical State (as shipped) Liquid Color Colorless Odor Slightly acrid, sweet fragrant. [Pg.249]

Eberle and Schaub (93EUP571326) describe the synthesis of a large series of 3-hydroxy-2-(2-methyl-4-prop-l-ynyl-2//-pyrazol-3-yl)acrylic acid methyl esters 26 and methoxyimino-(2-methyl-4-prop-l-ynyl-2//-pyrazol-3-yl)acetic acid methyl esters 27 by dehydrohalogenation of the corresponding chloroolefins 25 under the action of bases. In this case, the functional groups in position 5 of the pyrazole ring undergo dehydrobromination (Scheme 34). [Pg.18]

CN (5 )-.a-(2-Chlorophenyi)-6,7-dihydrothieno[3,2-c]pyridine-5(4//)-acetic acid methyl ester sulfate (1 1)... [Pg.526]

The reaction of potassium 3-amino-4-oxo-3,4-dihydroquinazoline-2-thiolate 62 with a-bromophenylacetic acid 63 resulted in the formation of (3-amino-4-oxo-3,4-dihydroquinazolin-2-ylsulfanyl)-phenyl-acetic acid methyl ester 64 which on alkali treatment and subsequent acidification resulted in the synthesis of 2-phenyl- 1-thia-4,4a,9-triaza-anthracene-3,10-dione 65 <1999JCR(S)86>. Similarly, the reaction of potassium 3-amino-5,6-dimethyl-4-oxo-3,4,4a,7a-tetrahydrothieno[2,3- pyrimidine-2-thiolate 66 with a-bromo-ester 67 resulted in the formation of 2-(3-amino-5,6-dimethyl-4-oxo-3,4,4a,7a-tetrahydrothieno[2,3- / pyrimidin-2-ylsulfanyl)-propionic acid ethyl ester 68. Subsequent treatment with alkali followed by acidification resulted in the formation of 2,3,7-trimethyl-3a,9a-dihydro-l,8-dithia-4a,5,9-triazacyclopenta[ ]naphthalene-4,6-dione 69 <2000JHC1161>... [Pg.334]

Acetic acid, methyl ester Acetic acid, ethyl ester Pentanoic acid, methylethyl ester Acetic acid, methylethyl ester Acetic acid, 3-propenyl ester Acetic acid, benzyl ester Oxalic acid, dimethyl ester Oxalic acid, diethyl ester Oxalic acid, fe(l-methylethyl) ester... [Pg.368]

AN EFFICIENT SYNTHESIS OF INDOLE-2-ACETIC ACID METHYL ESTERS... [Pg.63]

Methyl indole-2-acetate lndole-2-acetic acid, methyl ester (8) 1H-lndole-2-acetic acid, methyl ester (9) (21422-40-2). [Pg.68]

The next three procedures provide useful synthetic intermediates. A stereospecific synthesis of ETHYL (Z)-3-BROMO-2-PROPENOATE affords an alternative vinyl bromide partner for the coupling chemistry in the preceding procedure. A very simple but elegant illustration of the flash vacuum pyrolysis technique is used to prepare BENZOCYCLOBUTENONE from o-toluoyl chloride. Another member of the functionalized indole family of synthetic intermediates is presented in a four-step procedure for 5-METHOXYINDOLE-2-ACETIC ACID METHYL ESTER. [Pg.147]

S. P. Modi, R. C. Oglesby, and S. Archer 125 AN EFFICIENT SYNTHESIS OF INDOLE-2-ACETIC ACID METHYL ESTERS... [Pg.153]

Roberts, N.J., Seago, A., Carey, J.S., Freer, R., Preston, C. and Lye, G.J., Lipase catalysed resolution of the lotrafiban intermediate 2,3,4,5-tetrahydro-4-methyl-3-oxo-lJS-l,4-benzodia-zepine-2-acetic acid methyl ester in ionic hquids comparison to the industrial f-butanol process. Green Chem., 2004, 6, 475 82. [Pg.75]

Synonyms Acetic acid, methyl ester BRN 1736662 CCRIS 5846 Devoton EINECS 201-185-2 FEMA No. 2676 MeAc Methyl ethanoate NSC 405071 Tereton UN 1231. [Pg.717]

Acetic acid, methyl ester, see Methyl acetate... [Pg.1456]

Bis(/t-chlorophenyl)acetic acid, see p,p -DDT Bis(p-chlorophenyl)acetic acid, methyl ester, see... [Pg.1520]

The reaction of saccharin with sodium hydroxide results in substitution of the imide hydrogen atom of saccharin with sodium, giving a sodium salt (3.2.75). The resulting product is reacted with methyl chloroacetate, giving the saccharin-substituted acetic acid methyl ester (3.2.76). Upon reaction with sodium methoxide in dimethylsuhoxide, the product undergoes... [Pg.51]

Acetic Acid, Cupric Salt Acetic Acid, Dimethylamide Acetic Acid, Ethyl Ester Acetic Acid, Isobutyl Ester Acetic Acid, Isopropyl Ester Acetic Acid, Methyl Ester Acetic Acid, Nickel (II) Salt Acetic Acid, Propyl Ester Acetic Acid, Sec-Butyl Ester Acetic Acid, Zinc Salt Acetic Aldehyde Acetic Anhydride Acetic Ester Acetic Ether... [Pg.18]

METHYL ACETATE Acetic Acid, methyl ester Flammable Liquid, 11 1 3 0 ... [Pg.104]

Naphthalen-1 -ylmethyl-4-oxo-1 -phenyl-1,3,8-triaza-spiro[4.5]dec-3-yl)-acetic acid methyl ester, C27H29N3O3, Mr 443.54... [Pg.472]

Boc-m-Ampa-OH (56) has been prepared by Curtius rearrangement of the monoester of m-phenylenediacetic acid 54 (Scheme 17).It can probably also be obtained more rapidly through the m-bromomethyl precursor as described for the o- and p-isomers. A detailed description of the preparation of [5-(l-aminoethyl)-2-(cyclohexylmethoxy)phenyl]acetic acid methyl ester 57 has been given.175 ... [Pg.624]

Other simple chelate ligands which have been found to give six-coordinate complexes NiX2L2 are 2-acetylpyridine N-oxide oxime,2495 2-acetamidopyridine,2496 pyridine-2-(acetic acid methyl ester)2497 and -substituted 2-aminopyridine N-oxides.2498... [Pg.214]

Nitrocyanoacetic Acid Methyl Ester, NC.CH(N02) C02CH3 mw 144.09, N 19.44% lustrous ndls + HzO, mp 76° readily sol in w MeOH diffc sol in eth was obtd by oxidn of isonitrosocyano-acetic acid methyl ester with KMn04 soln. Its Hydrazine salt, C4H4N204 + H2N.NH2, crysts (from MeOH), melts at 168° and its Potassium salt, NC.C( N02K).C02.CH3, lusturous lfts, decomp at 264-66°... [Pg.367]

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