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Nitrocyanoacetic acid methyl ester

Nitrocyanoacetic Acid Methyl Ester, NC.CH(N02) C02CH3 mw 144.09, N 19.44% lustrous ndls + HzO, mp 76° readily sol in w MeOH diffc sol in eth was obtd by oxidn of isonitrosocyano-acetic acid methyl ester with KMn04 soln. Its Hydrazine salt, C4H4N204 + H2N.NH2, crysts (from MeOH), melts at 168° and its Potassium salt, NC.C( N02K).C02.CH3, lusturous lfts, decomp at 264-66°... [Pg.367]

Nitrocyanoacetyl Hydrazide, NC.CH(N02).C0 NH.NH2 mw 144.09 N 38.89% col ndls (+HzO) or yel anhyd prisms, mp >285° was obtd by reacting hydrazine hydrate with either the hydrazine salt or K salt of nitrocyanoacetic acid methyl ester. It forms several salts. The Hydrazine salt, C3H4N303 + H2N.NH2, occurs as colorless or om-red crysts, the orn-red salt sinsters at 185-95° decomp at 200° the Potassium salt, KC3H3N403, col prisms, explodes on heating... [Pg.367]


See other pages where Nitrocyanoacetic acid methyl ester is mentioned: [Pg.532]    [Pg.367]    [Pg.532]    [Pg.367]   
See also in sourсe #XX -- [ Pg.3 , Pg.584 ]




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Nitrocyanoacetic acid

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