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Acetates olefinic

Cupric Chloride can be used as a reoxidant in the vinyl acetate synthesis but other products are also produced. In fact, with increasing Cu(II) concentration, the side products can easily be made the major products 16>. The side products are chloro acetates and diacetates and they probably arise from a reaction of the palladium acetate-olefin adduct with cupric chloride or acetate. [Pg.13]

Thus, a large number of substances with the structural features shown above may form peroxides. However, these substances do not present a peroxide hazard to the same extent. The tendency of organic compounds to form peroxides decreases according to their structures as follows ethers and acetals > olefins > halogenated olefins > vinyl compounds > dienes > aUcynes > alkylbenzenes > isoparaffins > alkenyl esters > secondary alcohols > ketones > aldehydes > ureas and amides. [Pg.77]

Solution polymerization n. A polymerization process in which the monomer, or mixture of monomers, and the polymerization initiators are dissolved in a non-monomeric solvent at the beginning of the polymerization reaction. The liquid is usually also a solvent for the resulting polymer or co-polymer. Solution polymerization is most advantageous when the resulting polymeric solutions are to be used for coatings, lacquers, or adhesives. Vinyl acetate, olefins, styrene, and methyl methacrylate are the monomers most often employed. Odian GC (2004) Principles of polymerization. John Wiley and Sons Inc., New York. Elias HG (2003) An introduction to plastics. John Wiley and Sons, New York. Solomon DH (1969) Kinetics and... [Pg.902]

Olefin Copolymers Molded EVA (ethylene vinyl acetate) Olefin Copolymers Molded lonomer ABS Resins Molded, Extruded Medium impact Polyester Thermosets Cast Rigid 0.003 0.003 0.003—0.006 0.003—0.04... [Pg.1358]

Formyl pyrrole 86 was arylated with a series of electron-deficient aryl chlorides in the presence of a palladium—Ai-heterocyclic carbene complex. The catalyst complexes were found to he air stable and delivered the pyrrole products in moderate to good yields with loadings as low as 1% (13BJOC303). Jiao and Bach reported the direct C—H alkylation of electron-deficient pyrroles (87) with a palladium catalyst and norbornene yields were very good and the alkyl partner was tolerant of a wide variety of substituents including esters, acetals, olefins, and nitriles (13AG(I)6080). [Pg.163]

Figure 2.48 Syngas uptake curves for hydroformylation with mixtures of styrene, allyl cyanide, and vinyl acetate (olefin/catalyst = 30 000 1 L/Rh = 1.2 1 80 °C, toluene, CO/Hj = 1 1, 1.034 MPa). (Adapted from Ref. [16].)... Figure 2.48 Syngas uptake curves for hydroformylation with mixtures of styrene, allyl cyanide, and vinyl acetate (olefin/catalyst = 30 000 1 L/Rh = 1.2 1 80 °C, toluene, CO/Hj = 1 1, 1.034 MPa). (Adapted from Ref. [16].)...
Vinyl acetate, olefins, styrene, and methyl methacrylate are the monomers most often employed. (Odian GC (2004) Principles of polymerization. Wiley, New York ... [Pg.677]

Hierarchical (or mesoporous) zeolites became the focus of the review by Christensen et al. [7]. The main reason behind the development of hierarchical zeolites is to achieve heterogeneous catalysts with an improved porous structure and thereby enhanced performance in alkylation of benzene with alkenes, alkylation, and acylation of other compounds, methanol conversion into hydrocarbons, aromatization processes, isomerization of paraffins, cracking of diverse substrates and raw materials (naphtha, aromatic compounds, hexadecane, vacuum gas oil, and some polymers), and hydrotreating. The reactions that are of interest from the point of view of fine chemicals synthesis occurring on hierarchical zeohtes include aldol condensation, esterification, acetalization, olefin epoxidation, and Beckmarm rearrangement. [Pg.313]

Scheme 2.20 Reaction of alcohol, acetal, olefin, and amide bearing adjacent amine group. Scheme 2.20 Reaction of alcohol, acetal, olefin, and amide bearing adjacent amine group.
Certain features of the addition of acetyl nitrate to olefins in acetic anhydride may be relevant to the mechanism of aromatic nitration by this reagent. The rapid reaction results in predominantly cw-addition to yield a mixture of the y -nitro-acetate and y5-nitro-nitrate. The reaction was facilitated by the addition of sulphuric acid, in which case the 3rield of / -nitro-nitrate was reduced, whereas the addition of sodium nitrate favoured the formation of this compound over that of the acetate. As already mentioned ( 5.3. i), a solution of nitric acid (c. i 6 mol 1 ) in acetic anhydride prepared at — 10 °C would yield 95-97 % of the nitric acid by precipitation with urea, whereas from a similar solution prepared at 20-25 °C and cooled rapidly to —10 °C only 30% of the acid could be recovered. The difference between these values was attributed to the formation of acetyl nitrate. A solution prepared at room... [Pg.83]

Thallium(III) acetate reacts with alkenes to give 1,2-diol derivatives (see p. 128) while thallium(III) nitrate leads mostly to rearranged carbonyl compounds via organothallium compounds (E.C. Taylor, 1970, 1976 R.J. Ouelette, 1973 W. Rotermund, 1975 R. Criegee, 1979). Very useful reactions in complex syntheses have been those with olefins and ketones (see p. 136) containing conjugated aromatic substituents, e.g. porphyrins (G. W. Kenner, 1973 K.M. Smith, 1975). [Pg.129]

This oxidation process for olefins has been exploited commercially principally for the production of acetaldehyde, but the reaction can also be apphed to the production of acetone from propylene and methyl ethyl ketone [78-93-3] from butenes (87,88). Careflil control of the potential of the catalyst with the oxygen stream in the regenerator minimises the formation of chloroketones (94). Vinyl acetate can also be produced commercially by a variation of this reaction (96,97). [Pg.52]

Acid—Base Chemistry. Acetic acid dissociates in water, pK = 4.76 at 25°C. It is a mild acid which can be used for analysis of bases too weak to detect in water (26). It readily neutralizes the ordinary hydroxides of the alkaU metals and the alkaline earths to form the corresponding acetates. When the cmde material pyroligneous acid is neutralized with limestone or magnesia the commercial acetate of lime or acetate of magnesia is obtained (7). Acetic acid accepts protons only from the strongest acids such as nitric acid and sulfuric acid. Other acids exhibit very powerful, superacid properties in acetic acid solutions and are thus useful catalysts for esterifications of olefins and alcohols (27). Nitrations conducted in acetic acid solvent are effected because of the formation of the nitronium ion, NO Hexamethylenetetramine [100-97-0] may be nitrated in acetic acid solvent to yield the explosive cycl o trim ethyl en etrin itram in e [121 -82-4] also known as cyclonit or RDX. [Pg.66]

Olefins add anhydrous acetic acid to give esters, usually of secondary or tertiary alcohols propjiene [115-07-1] yields isopropyl acetate [108-21-4], isobutjiene [115-11-7] gives tert-huty acetate [540-88-5]. Minute amounts of water inhibit the reaction. Unsaturated esters can be prepared by a combined oxidative esterification over a platinum group metal catalyst. Eor example, ethylene-air-acetic acid passed over a palladium—Hthium acetate catalyst yields vinyl acetate. [Pg.66]

Prospective Processes. There has been much effort invested in examining routes to acetic acid by olefin oxidation or from ethylene, butenes, or j -butyl acetate. No product from these sources is known to have reached the world market the cost of the raw materials is generally prohibitive. [Pg.69]

C with low conversion (10—15%) to limit dichloroalkane and trichloroalkane formation. Unreacted paraffin is recycled after distillation and the predominant monochloroalkane is dehydrochlorinated at 300°C over a catalyst such as nickel acetate [373-02-4]. The product is a linear, random, primarily internal olefin. [Pg.459]

Pentaerythritol is used in self-extinguishing, non dripping, flame-retardant compositions with a variety of polymers, including olefins, vinyl acetate and alcohols, methyl methacrylate, and urethanes. Phosphoms compounds are added to the formulation of these materials. When exposed to fire, a thick foam is produced, forming a fire-resistant barrier (see Elame retardants) (84—86). [Pg.466]

Calcium carbide has been used in steel production to lower sulfur emissions when coke with high sulfur content is used. The principal use of carbide remains hydrolysis for acetylene (C2H2) production. Acetylene is widely used as a welding gas, and is also a versatile intermediate for the synthesis of many organic chemicals. Approximately 450,000 t of acetylene were used aimuaHy in the early 1960s for the production of such chemicals as acrylonitrile, acrylates, chlorinated solvents, chloroprene, vinyl acetate, and vinyl chloride. Since then, petroleum-derived olefins have replaced acetylene in these uses. [Pg.166]

The latest of three ethylene recovery plants was started in 1991. Sasol sold almost 300,000 t of ethylene in 1992. Sasol also produces polypropylene at Secunda from propylene produced at Sasol Two. In 1992 Sasol started constmction of a linear alpha olefin plant at Secunda to be completed in 1994 (40). Initial production is expected to be 100,000 t/yr pentene and hexene. Sasol also has a project under constmction to extract and purify krypton and xenon from the air separation plants at Sasol Two. Other potential new products under consideration at Sasol are acrylonitrile, acetic acid, acetates, and alkylamines. [Pg.168]

In acetic acid solvent, ethylene gives 1,3-propanediol acetates (46) and propylene gives 1,3-butanediol acetates (47). A similar reaction readily occurs with olefinic alcohols and ethers, diolefins, and mercaptans (48). [Pg.492]

Sulfonated styrene—divinylbensene cross-linked polymers have been appHed in many of the previously mentioned reactions and also in the acylation of thiophene with acetic anhydride and acetyl chloride (209). Resins of this type (Dowex 50, Amherljte IR-112, and Permutit Q) are particularly effective catalysts in the alkylation of phenols with olefins (such as propylene, isobutylene, diisobutylene), alkyl haUdes, and alcohols (210) (see Ion exchange). Superacids. [Pg.564]

The principal chemical markets for acetylene at present are its uses in the preparation of vinyl chloride, vinyl acetate, and 1,4-butanediol. Polymers from these monomers reach the consumer in the form of surface coatings (paints, films, sheets, or textiles), containers, pipe, electrical wire insulation, adhesives, and many other products which total biUions of kg. The acetylene routes to these monomers were once dominant but have been largely displaced by newer processes based on olefinic starting materials. [Pg.393]

The synthesis of 2,4-dihydroxyacetophenone [89-84-9] (21) by acylation reactions of resorcinol has been extensively studied. The reaction is performed using acetic anhydride (104), acetyl chloride (105), or acetic acid (106). The esterification of resorcinol by acetic anhydride followed by the isomerization of the diacetate intermediate has also been described in the presence of zinc chloride (107). Alkylation of resorcinol can be carried out using ethers (108), olefins (109), or alcohols (110). The catalysts which are generally used include sulfuric acid, phosphoric and polyphosphoric acids, acidic resins, or aluminum and iron derivatives. 2-Chlororesorcinol [6201-65-1] (22) is obtained by a sulfonation—chloration—desulfonation technique (111). 1,2,4-Trihydroxybenzene [533-73-3] (23) is obtained by hydroxylation of resorcinol using hydrogen peroxide (112) or peracids (113). [Pg.491]

PMMA is not affected by most inorganic solutions, mineral oils, animal oils, low concentrations of alcohols paraffins, olefins, amines, alkyl monohahdes and ahphatic hydrocarbons and higher esters, ie, >10 carbon atoms. However, PMMA is attacked by lower esters, eg, ethyl acetate, isopropyl acetate aromatic hydrocarbons, eg, benzene, toluene, xylene phenols, eg, cresol, carboHc acid aryl hahdes, eg, chlorobenzene, bromobenzene ahphatic acids, eg, butyric acid, acetic acid alkyl polyhaHdes, eg, ethylene dichloride, methylene chloride high concentrations of alcohols, eg, methanol, ethanol 2-propanol and high concentrations of alkahes and oxidizing agents. [Pg.262]


See other pages where Acetates olefinic is mentioned: [Pg.91]    [Pg.169]    [Pg.41]    [Pg.418]    [Pg.141]    [Pg.437]    [Pg.662]    [Pg.91]    [Pg.169]    [Pg.41]    [Pg.418]    [Pg.141]    [Pg.437]    [Pg.662]    [Pg.193]    [Pg.353]    [Pg.76]    [Pg.191]    [Pg.191]    [Pg.258]    [Pg.388]    [Pg.166]    [Pg.321]    [Pg.293]    [Pg.385]    [Pg.76]    [Pg.323]    [Pg.343]    [Pg.367]   
See also in sourсe #XX -- [ Pg.90 , Pg.225 ]




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