A?-means

Examples of main programs calling subroutines FLASH and ELIPS for vapor-liquid and liquid-liquid separation calculations, respectively, are described in this Appendix. These are intended only to illustrate the use of the subroutines and to provide a means of quickly evaluating their performance on systems of interest. It is expected that most users will write their own main prograns utilizing FLASH and ELIPS, and the other subroutines presented in this monograph,to suit the requirements of their separation calculations. 

The n-isomer is more valuable. Recycling the iso-isomer can be used as a means of suppressing its formation. ... 

Allow vaporization of liquid in the reactor so that it can be condensed and refluxed back to the reactor as a means of removing the heat of reaction... 

Cynes, B. L., Chemical Reactions as a Means of Separation—Sulfur Removal, Marcel Dekker, New York, 1977. 

A diffusion mechanism is also used in dialysis as a means of separating colloids from crystalloids. The rate of diffusion of molecules in gels is practically the same as in water, indicating the continuous nature of the aqueous phase. The diffusion of gases into a stream of vapour is of considerable importance in diffusion pumps. 

To extend the applicability of the characterization factor to the complex mixtures of hydrocarbons found in petroleum fractions, it was necessary to introduce the concept of a mean average boiling point temperature to a petroleum cut. This is calculated from the distillation curves, either ASTM or TBP. The volume average boiling point (VABP) is derived from the cut point temperatures for 10, 20, 50, 80 or 90% for the sample in question. In the above formula, VABP replaces the boiling point for the pure component. 

As decommissioning approaches, enhanced recovery e.g. chemical flooding processes are often considered as a means of recovering a proportion of the hydrocarbons that remain after primary production. The economic viability of such techniques is very sensitive to the oil price, and whilst some are used in onshore developments they can rarely be justified offshore at current oil prices. 

Between the bit and the surface, where the torque is generated, we find the drill string (Fig. 3.9). While being mainly a means for power transmission, the drill string fulfils several other functions, and if we move up from the bit we can see what those are. 

When water is produced along with oil, the separation of water from oil invariably leaves some water in the oil. The current oil-in-water emission limit into the sea is commonly 40 ppm. Oily water disposal occurs on processing platforms, some drilling platforms, and at oil terminals. The quality of water disposed from terminals remains an area of scrutiny, especially since the terminals are often near to local habitation and leisure resorts. If the engineer can find a means of reducing the produced water at source (e.g. water shut-off or reinjection of produced water into reservoirs) then the surface handling problem is much reduced. 

The method allows variables to be added or multiplied using basic statistical rules, and can be applied to dependent as well as independent variables. If input distributions can be represented by a mean, and standard deviation then the following rules are applicable for independent variables ... 

Gas can be injected into reservoirs to supplement recovery by maintaining reservoir pressure or as a means of disposing of gas which cannot be flared under environmental legislation, and for which no market exists. 

Whilst network analysis is a useful tool for estimating timing and resources, it is not a very good means for displaying schedules. Bar charts are used more commonly to illustrate planning expectations and as a means to determine resource loading. 

De-bottlenecking is particularly important when the producing field is on plateau production, because it provides a means of earlier recovery (acceleration) of hydrocarbons, which improves the project cashflow and NPV. 

The role that a host facility plays in an incremental development project can vary tremendously. At one extreme all production and processing support may be provided by the host (such as gas lift and water treatment). On the other hand, the host may just become a means of accessing an export pipeline (if a production and processing facility is installed on the new field). 

For conventional probes, acoustic verification aims at characterizing the beam pattern, beam crossing, beam angle, sensitivity, etc., which are key characteristics in the acoustic interaction between acoustic beam and defect. For array transducers, obviously, it is also a meaning to check the acoustic capabilities of the probe. That is to valid a domain (angle beam, focus, etc.) in which the probe can operate satisfactorily. 

There is, of course, a mass of rather direct evidence on orientation at the liquid-vapor interface, much of which is at least implicit in this chapter and in Chapter IV. The methods of statistical mechanics are applicable to the calculation of surface orientation of assymmetric molecules, usually by introducing an angular dependence to the inter-molecular potential function (see Refs. 67, 68, 77 as examples). Widom has applied a mean-held approximation to a lattice model to predict the tendency of AB molecules to adsorb and orient perpendicular to the interface between phases of AA and BB [78]. In the case of water, a molecular dynamics calculation concluded that the surface dipole density corresponded to a tendency for surface-OH groups to point toward the vapor phase [79]. 

Bianco and Marmur [143] have developed a means to measure the surface elasticity of soap bubbles. Their results are well modeled by the von Szyszkowski equation (Eq. III-57) and Eq. Ill-118. They find that the elasticity increases with the size of the bubble for small bubbles but that it may go through a maximum for larger bubbles. Li and Neumann [144] have shown the effects of surface elasticity on wetting and capillary rise phenomena, with important implications for measurement of surface tension. 

Absorption spectroscopy provides a means to study particular details about a monolayer. Transmission spectroscopy is difficult because the film, which is thin, absorbs little. Gaines [1] describes multiple-pass procedures for overcoming this problem. Reflection spectroscopy in the UV-visible range has been reported for lipid monolayers [150,151] and in the IR range for oleic acid [152]. 

Density functional theory from statistical mechanics is a means to describe the thermodynamics of the solid phase with information about the fluid [17-19]. In density functional theory, one makes an ansatz about the structure of the solid, usually describing the particle positions by Gaussian distributions around their lattice sites. The free... 

Knowledge of the temperature coefficient of 0 provides a means of calculating the heat of immersion. Differentiation of Eq. X-18 yields... 

The behavior of insoluble monolayers at the hydrocarbon-water interface has been studied to some extent. In general, a values for straight-chain acids and alcohols are greater at a given film pressure than if spread at the water-air interface. This is perhaps to be expected since the nonpolar phase should tend to reduce the cohesion between the hydrocarbon tails. See Ref. 91 for early reviews. Takenaka [92] has reported polarized resonance Raman spectra for an azo dye monolayer at the CCl4-water interface some conclusions as to orientation were possible. A mean-held theory based on Lennard-Jones potentials has been used to model an amphiphile at an oil-water interface one conclusion was that the depth of the interfacial region can be relatively large [93]. 

The subject of gas adsorption is, indeed, a very broad one, and no attempt is made to give complete coverage to the voluminous literature on it. Instead, as in past chapters, the principal models or theories are taken up partly for their own sake and partly as a means of introducing characteristic data. 

Unlike most words in a glossary of tenns associated with the theoretical description of molecules, the word synnnetry has a meaning in every-day life. Many objects look exactly like their mirror image, and we say that they are syimnetrical or, more precisely, that they have reflection synnnetry. In addition to having reflection synnnetry, a pencil (for example) is such that if we rotate it tln-ough any angle about its long axis it... 

Although all real surfaces have steps, they are not usually labelled as vicinal unless they are purposely misoriented in order to create a regular array of steps. Vicinal surfaces have unique properties, which make them useful for many types of experiments. For example, steps are often more chemically reactive than terraces, so that vicinal surfaces provide a means for investigating reactions at step edges. Also, it is possible to grow nanowires by deposition of a metal onto a surface of another metal in such a way that the deposited metal diflfiises to and attaches at the step edges [3]. 

Electrons interact with solid surfaces by elastic and inelastic scattering, and these interactions are employed in electron spectroscopy. For example, electrons that elastically scatter will diffract from a single-crystal lattice. The diffraction pattern can be used as a means of stnictural detenuination, as in FEED. Electrons scatter inelastically by inducing electronic and vibrational excitations in the surface region. These losses fonu the basis of electron energy loss spectroscopy (EELS). An incident electron can also knock out an iimer-shell, or core, electron from an atom in the solid that will, in turn, initiate an Auger process. Electrons can also be used to induce stimulated desorption, as described in section Al.7.5.6. 

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