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Wright studies

Further information to help determine the CS2 oxidation mechanism comes from photochemical studies. Kondratiev and Yakovlevairradiated 16-55 torr CS2 in the presence of 40-100 torr O2 with light at 2000 A. The primary products were CS and S atoms. The major final products were SO2 and OCS, the latter undergoing further oxidation. Wright studied the isothermal, room temperature oxidation initiated by flash photolysis, as well as the flash photolysis of pure CS2. After flashing pure CS2, he observed the absorption spectra of CS and S2. The S2 disappeared rapidly, following second-order kinetics. CS was removed at the walls. In the presence of oxygen, the S2 was diminished, but its rate of disappearance was unaffected. SO2 and S2O absorption spectra were also... [Pg.57]

Wynder, E.L. and G.F Wright Studies on the identification of carcinogens in cigarette tar Proc. Am. Assoc. [Pg.1433]

Thus the glass electrode-vacuum tube pH measuring machine made its way into the literature. The novelty of the Elder and Wright study led to its early publication. [Pg.284]

The general task is to trace the evolution of the third order polarization of the material created by each of the above 12 Raman field operators. For brevity, we choose to select only the subset of eight that is based on two colours only—a situation that is connnon to almost all of the Raman spectroscopies. Tliree-coloiir Raman studies are rather rare, but are most interesting, as demonstrated at both third and fifth order by the work in Wright s laboratory [21, 22, 23 and 24]- That work anticipates variations that include infrared resonances and the birth of doubly resonant vibrational spectroscopy (DOVE) and its two-dimensional Fourier transfomi representations analogous to 2D NMR [25]. [Pg.1186]

Chen P C, Hamilton J P, Zilian A, Labuda M J and Wright J C 1998 Experimental studies for a new family of infrared four wave mixing spectroscopies Appl. Spectrosc. 52 380-92... [Pg.1226]

More information has appeared concerning the nature of the side reactions, such as acetoxylation, which occur when certain methylated aromatic hydrocarbons are treated with mixtures prepared from nitric acid and acetic anhydride. Blackstock, Fischer, Richards, Vaughan and Wright have provided excellent evidence in support of a suggested ( 5.3.5) addition-elimination route towards 3,4-dimethylphenyl acetate in the reaction of o-xylene. Two intermediates were isolated, both of which gave rise to 3,4-dimethylphenyl acetate in aqueous acidic media and when subjected to vapour phase chromatography. One was positively identified, by ultraviolet, infra-red, n.m.r., and mass spectrometric studies, as the compound (l). The other was less stable and less well identified, but could be (ll). [Pg.222]

M. M. Markowit2 and E. W. De2melyk, A. Study of the Application ofEithium Chemicals to Air Regeneration Techniques in Manned Sealed Environments, AMRL-TDR-64-1, Wright-Patterson Air Force Base, Ohio, Feb. 1964. [Pg.489]

Previously Wright had studied asymptotic relations between the coefficients in two generating functions related by the formula equation... [Pg.133]

Many studies of such acid-base equilibria of substituted benzenediazonium ions have been reported since the first investigation by Wittwer and Zollinger (1954), namely by Lewis and Suhr (1958 a), Littler (1963), Ritchie and Wright (1971 a, 1971 b), Machackova and Sterba (1972 a), Beranek et al. (1973), Jahelka et al. (1973 a), Vir-tanen and Kuokkanen (1977), BagaPs group (Luchkevich et al., 1986 and references therein), and in DMSO by Petrov et al. (1973). [Pg.92]

Wang C. H., Wright R. B. Effect of density on the Raman scattering of molecular fluids. I. A detailed study of the scattering polarization, intensity, frequency shift, and spectral shape in gaseous N2, J. Chem. [Pg.292]

As has already been stated, the carotenoids are lipophilic and are therefore absorbed and transported in association with the lipoprotein particles. In theory, this fortuitous juxtaposition of lipid and carotenoid should confer protection on the lipid through the antioxidant properties of the carotenoid. No doubt some antioxidant protection is afforded by the presence of the carotenoids derived from the diet. However, with one or two exceptions, human supplementation studies have not supported a role for higher dose carotenoid supplements in reducing the susceptibility of the low-density lipoproteins to oxidation, either ex vivo or in vivo (Wright et al, 2002 Hininger et al, 2001 Iwamoto et al, 2000). [Pg.112]

Stevenson DE, JN Wright, M Akhtar (1988) Mechanistic consideration of P-450 dependent enzyme reactions studies on oestriol biosynthesis. J Chem Soc Perkin Trans I 2043-2052. [Pg.145]

Effect of glass composition on cement properties As we have indicated previously, two types of glass have been used in dental silicate cements the obsolete oxide glass and the modem fluoride glass. Only four studies on glass composition and its relationship to cement property have been published (Wright, 1919 Crepaz, 1951 Manly et al.. [Pg.238]

Wright, J. W. (1919). A study of some dental cements. Journal of Dental Research, 1, 35-60. [Pg.282]

X-Ray irradiation of quartz or silica particles induces an electron-trap lattice defect accompanied by a parallel increase in cytotoxicity (Davies, 1968). Aluminosilicate zeolites and clays (Laszlo, 1987) have been shown by electron spin resonance (e.s.r.) studies to involve free-radical intermediates in their catalytic activity. Generation of free radicals in solids may also occur by physical scission of chemical bonds and the consequent formation of dangling bonds , as exemplified by the freshly fractured theory of silicosis (Wright, 1950 Fubini et al., 1991). The entrapment of long-lived metastable free radicals has been shown to occur in the tar of cigarette smoke (Pryor, 1987). [Pg.248]

One eritical factor that has been neglected in considering mechanisms of cardiac fatalities is the timeframe for various types of toxicities. For example, a majority of cocaine-related fatalities and near fatalities reported from emergency rooms are attributed to one or more types of cardiac ischemic or hypertensive episodes (Isner et al. 1986). Thus, these studies may discount the cocaine-induced arrhythmias and conduction defects as important direct causes of fatalities. Yet, if coroner reports are used as data sources (Virmani et al. 1988 Wetli and Wright 1979 Mittleman and Wetli 1984), there are great numbers of deaths in which pulmonary effusion and lack of evidence for coronary occlusion, acute myocardial infarction, or... [Pg.328]


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See also in sourсe #XX -- [ Pg.139 ]

See also in sourсe #XX -- [ Pg.10 , Pg.11 , Pg.12 ]




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