Viscometer system

The automation of the HPGPC/Viscometer system is achieved by interfacing the differential refractometer (DRI) and viscosity detector to a microcomputer for data acquisition. The raw data subsequently, are transferred to a minicomputer (DEC PDP-ll/HiI) for storage and data analysis. Details of the instrument automation are given elsewhere.(6)... 

Details of the data analysis for the GPC/Viscometer system have been reviewed by Ouano.(T ) The data reduction scheme is summarized in Figure 2 and briefly will be discussed here. The intrinsic viscosity of the effluent at a given retention volume [n](v) is determined from the DRI and continuous viscosity detector responses according to the following equation... 

In a previous paper (16) the hardware design of the SEC/Viscometer system used in this work has been described. The effects of operational variables, e.g. pump pulsations, flow rate and flow irregularities on the performance of the viscometer and the enhancement of the signal-to-noise ratio by using mechanical dampers also has been described. Our current work has focused on the development, implementation and application of automated data... 

A pressurized direct-drive concentric cylinder viscometer system (Figure 3-21) was used to obtain shear rate versus shear stress data on a tomato puree at several fixed temperatures between 76 and 120°C (Figure 3-22), and temperature versus apparent viscosity data at several shear rates on a 4% waxy rice (WR) starch dispersion during gelatinization over the temperature range 30 to 110°C (Figure 3-23) (Rao et al., 1998). The drive motor, torque unit, and concentric cylinder unit and temperature control vessel of a Haake RV2 viscometer system (Haake Inc.) were placed in a chamber (PRC) that could be pressurized to 0.2 MPa (two atmospheres). The temperature control vessel was insulated to minimize heat loss. A eopper-constantan (36 gage wires) thermocouple plaeed in the well of the inner eoneentric eylinder measured the temperature of the test sample. 

Figure 3-21 Pressurized Viscometer System for Obtaining Data at High Temperatures (From Liao, 1998).

In Chapter 4 the development of axisymmetric models in which the radial and axial components of flow field variables remain constant in the circumferential direction is discussed. In situations where deviation from such a perfect symmetry is small it may still be possible to decouple components of the equation of motion and analyse the flow regime as a combination of one- and two-dimensional systems. To provide an illustrative example for this type of approximation, in this section we consider the modelling of the flow field inside a cone-and-plate viscometer. 

Since viscometer drainage times are typically on the order of a few hundred seconds, intrinsic viscosity experiments provide a rapid method for evaluating the molecular weight of a polymer. A limitation of the method is that the Mark-Houwink coefficients must be established for the particular system under consideration by calibration with samples of known molecular weight. The speed with which intrinsic viscosity determinations can be made offsets the need for prior calibration, especially when a particular polymer is going to be characterized routinely by this method. 

Solvent system CMC concentration, g/350 cm Minimum viscometer dial reading at 600 rpm Maximum filtrate volume, 3 cm... 

With several springs, which function as torque gauges, and a number of spindles, viscosities can be measured up to 10 mPa-s with the Brookfield viscometer. The shear rates depend on the model and the sensor system they are ca 0.1 100 for the disk spindles, <132 for concentric cylinders, and <1500 for the cone—plate forlow viscosity samples. Viscosities at very low (ca 10 — 1 )) shear rates can be measured with the concentric... 

The Nametre Rotary B rotational viscometer measures torque in terms of the current needed to drive the d-c motor at a given speed while a material is under test. The standard sensors are coaxial cylinders or Brookfield disk-type spindles, but a cone—plate system is also available. The viscosity range for the coaxial cylinder sensors is 5 to 5 x 1(T mPa-s, and the maximum shear rate is 200. ... 

The Ravenfield model BS viscometer is a wide shear rate range iastmment with several possible measurement systems cone—plate, parallel plates, concentric cylinders, and taper plug. The last gives shear rates of up to 10 , and the cone—plate of up to 8 x lO". The viscosity range is... 

Although the viscometers discussed above are used in laboratories, there are other viscometers in the supply system that are available for local use. These viscometers can be... 

Figure 11 shows the reference floe diameter for viscometers as a function of shear stress and also the comparison with the results for stirred tanks. The stress was determined in the case of viscosimeters from Eq. (13) and impeller systems from Eqs. (2) and (4) using the maximum energy density according to Eq. (20). For r > 1 N/m (Ta > 2000), the disintegration performance produced by the flow in the viscosimeter with laminar flow of Taylor eddies is less than that in the turbulent flow of stirred tanks. Whereas in the stirred tank according to Eq. (4) and (16b) the particle diameter is inversely affected by the turbulent stress dp l/T, in viscosimeters it was found for r > 1.5 N/m, independently of the type (Searle or Couette), the dependency dp l/ pi (see Fig. 11). 

Another electrical measurement useful in detecting flocculation in aniso-metric particles is the response of dielectric constant to shear. The alignment along streamlines of flow which results from laminar shear in a viscometer decreases the dielectric constant of the system if the dipole moment lies along the long axis of the particle. Another way in which this phenomenon can be meas-... 

The q(T) can be independently measured by a viscometer and the value of y is determined by the PCS measurement at a certain temperature (typically 21 22 °C). Under the condition that the hydrodynamic diameter of the probe molecule is constant in the temperature range examined, we can obtain the temperature of the confocal area. It is worth noting that the present method estimates average temperature inside the confocal volume of the microscopic system because ECS provides the average value of the translational diffusion velocity over multiple fluorescent molecules passing through the sampling area. 

Magnetic resonance imaging has enabled the development of a completely novel type of viscometer. This technique is based on the capacity of MRI to accurately measure velocity profiles in opaque liquids. Its potential applications include many systems of industrial relevance, such as polymer melts and slurries. The data presented here clearly show that a wide range of fluid behaviors can be measured. 

In the SI system, the theoretical unit of v is m2/s or the commonly used Stoke (St) where 1 St = 0.0001 m2/s = 100 cSt = 100 centiStoke. Similarly, 1 centiStoke = 1 cSt = 0.000001 m2/s = 0.01 Stoke = 0.01 st. The specific gravity of water at 20.2°C (68.4°F) is almost 1. The kinematic viscosity of water at 20.2°C (68.4°F) is for all practical purposes equal to 1 cSt. For a liquid, the kinematic viscosity will decrease with higher temperature. For a gas, the kinematic viscosity will increase with higher temperature. Another commonly used kinematic viscosity unit is Saybolt universal seconds (SUS), which is the efflux time required for 60 mL of petroleum product to flow through the calibrated orifice of a Saybolt universal viscometer, as described by ASTM-D88. Therefore, the relationship between dynamic viscosity and kinematic viscosity can be expressed as... 

Rheological measurements. Routine viscosity measurements were made with a Wells-Brookfield micro-cone and plate viscometer, or a Brookfield LVT(D) viscometer with UL adapter. Viscosity-temperature profiles were obtained using the latter coupled via an insulated heating jacket to a Haake F3C circulator and PG100 temperature programmer or microcomputer and suitable interface. Signals from the viscometer and a suitably placed thermocouple were recorded on an X-Y recorder, or captured directly by an HP laboratory data system. 

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