Vinylidene resins

In 1942, various materials, such as resinous chlorinated paraffin, chlorinated rubber, chlorinated alkyd resins, and vinyl and vinylidene resins were unavailable for use in fire-retardant paints. Such chlorinated binders as were available were in critical demand for flameproofing fabrics. The present availability of such materials... 

Vinylidene Resins (Polyvinylidene Resins). These are resins in which the unit structure in the polymer molecule is (— H2C.CX2—). Here the X usually stands for F, Cl or CN radical. Examples are "Saran , "Viton A and "Gene-1132A ... 

Fluorinated ethylene-propylene resin Poly(vinylidene fluoride) Ethylene-tetrafluoroethylene copolymer Ethylene- chlorotrifluoro- ethylene copolymer Cellulose- filled Glass-fiber- reinforced... 

Fig. 4. Oxygen permeability in a vinylidene chloride copolymer film at selected levels of plasticizer (Citroflex A-4). Plasticizer level in parts pet hundred resin...

Vinylidene Chloride Copolymer Latex. Vinyhdene chloride polymers are often made in emulsion, but usuaUy are isolated, dried, and used as conventional resins. Stable latices have been prepared and can be used direcdy for coatings (171—176). The principal apphcations for these materials are as barrier coatings on paper products and, more recently, on plastic films. The heat-seal characteristics of VDC copolymer coatings are equaUy valuable in many apphcations. They are also used as binders for paints and nonwoven fabrics (177). The use of special VDC copolymer latices for barrier laminating adhesives is growing, and the use of vinyhdene chloride copolymers in flame-resistant carpet backing is weU known (178—181). VDC latices can also be used to coat poly(ethylene terephthalate) (PET) bottles to retain carbon dioxide (182). 

Vinyhdene chloride copolymers are available as resins for extmsion, latices for coating, and resins for solvent coating. Comonomer levels range from 5 to 20 wt %. Common comonomers are vinyl chloride, acrylonitrile, and alkyl acrylates. The permeability of the polymer is a function of type and amount of comonomer. As the comonomer fraction of these semicrystalline copolymers is increased, the melting temperature decreases and the permeability increases. The permeability of vinylidene chloride homopolymer has not been measured. 

The most chemical-resistant plastic commercially available today is tetrafluoroethylene or TFE (Teflon). This thermoplastic is practically unaffected by all alkahes and acids except fluorine and chlorine gas at elevated temperatures and molten metals. It retains its properties up to 260°C (500°F). Chlorotrifluoroethylene or CTFE (Kel-F, Plaskon) also possesses excellent corrosion resistance to almost all acids and alkalies up to 180°C (350°F). A Teflon derivative has been developed from the copolymerization of tetrafluoroethylene and hexafluoropropylene. This resin, FEP, has similar properties to TFE except that it is not recommended for continuous exposures at temperatures above 200°C (400°F). Also, FEP can be extruded on conventional extrusion equipment, while TFE parts must be made by comphcated powder-metallurgy techniques. Another version is poly-vinylidene fluoride, or PVF2 (Kynar), which has excellent resistance to alkahes and acids to 150°C (300°F). It can be extruded. A more recent development is a copolymer of CTFE and ethylene (Halar). This material has excellent resistance to strong inorganic acids, bases, and salts up to 150°C. It also can be extruded. 

Copolymers of acrylonitrile and vinylidene chloride have been used for many years to produce films of low gas permeability, often as a coating on another material. Styrene-acrylonitrile with styrene as the predominant free monomer (SAN polymers) has also been available for a long time. In the 1970s materials were produced which aimed to provide a compromise between the very low gas permeability of poly(vinylidene chloride) and poly(acrylonitrile) with the processability of polystyrene or SAN polymers (discussed more fully in Chapter 16). These became known as nitrile resins. 

Group of plastics whose resins are derived from the polymerization of vinylidene chloride or the copolymerization of vinylidene chloride and other unsaturated compounds. 

Another specialty area is coil coating, which involves coating metal coils by continuous operation. Modern roller systems afford speeds of up to 200 m/min. Most coils are made of cold-rolled and surface treated steel, aluminum, or alloys of the latter with manganese or magnesium. Coating systems are based on alkyd or acrylic resins, oil-free polyester, silicone-modified polyester or acrylic resin, poly(vinylidene fluoride), or poly(vinyl fluoride). Water-reducible systems, mainly based on acrylic resins, have been developed for aluminum as well as for steel coils [21-24], Drying is carried out by continuous operation in gas- or oil-heated multichamber ovens. 

To illustrate the compaction process that occurs in an extruder, a Maddock solidification [1] experiment (described in detail in Section 10.3.1) was performed using a 63.5 mm diameter machine [2]. The extruder was operated at a screw speed of 60 rpm with a poly(vinylidene chloride) copolymer (PVDC) powder. After the extruder reached a steady-state operation, screw rotation was stopped and full cooling was applied to the extruder. After several hours of cooling, the screw and PVDC resin were removed from the extruder and the density of the bed was measured using Archimedes s principle. The compaction phenomenon in the extruder is shown by the density measurements of the solid bed in Fig. 4.1. As shown in this figure, the density of the solid bed increased from the feedstock bulk density of 0.73 g/cm to nearly the solid density of 1.7 g/cmT... 

Uses Synthetic fibers and adhesives chemical intermediate in vinylidene fluoride synthesis production of poly(vinyl dichloroethylene) and LLl trichloroethane comonomer for food packaging, coating resins, and modacrylic fibers. 

Fluorocarbon Resins. This term includes polytetrafluoroethylene, polymers of chloro-trifluoroethylene (fluorothene), vinylidene fluoride (H2C CF2)j hexafluoropropylene (C3Ffl) and similar compds. These polymers are thermoplastic, inert to chemicals and oxidation. They have high heat stability, retain their useful props at both extremely low and high temps, have high electrical resistance to moisture. The materials are available as re sins, powders, and dispersions, and as films, sheets, tubes, rods and tapes. Some of them are rubber-like. Commercially available varieties are Kel-F , Teflon , Fluorel , Aclar and "Halon ... 

A study has been conducted on PBXs based on TATB using various binders such as polyurethane (Estane 5703-Goodrich), Viton-A (copolymer of vinylidene fluoride and hexafluoropropylene Du Pont), silicone resin (Chemlok), Kel-F800 [copolymer (3 1) of chlorotrifluoroethylene and vinylidene fluoride 3M Company] and Teflon [poly (tetrafluoroethylene), PTFE Du Pont] etc. and it was concluded that... 

Production of all types of vinyl resins, exclusive of plasticizers and fillers, during 1941 to 1950 are presented in Figure 2. These totals are for production of all polymers customarily classified as vinyl resins, including polyvinyl chloride, copolymers of vinyl chloride with vinyl acetate or vinylidene chloride, or modified polymers derived from them. However, the principal monomeric raw material for this field of resins is vinyl chloride. 

Vinylidene chloride-vinyl chloride copolymers were originally developed for thermoplastic molding applications, and small amounts are still used for this purpose. Extrusion of VDC-VC copolymers is the main fabrication technique for filaments, films, rods, and tubing or pipe, and involves the same concerns for thermal degradation, streamlined flow, and noncatalytic materials of construction as described for injection-molding resins. A significant application for vinylidene chloride copolymer resins is in the... 

Vinylidene chloride polymers are often made in emulsion, bul usually are isolated, clned, and used as conventional resins. Stable latices have been prepared and can be used directly for coatings. The principal applications for these materials are as barrier coatings on paper products and, more recently, on plastic films,... 

Novolac and resol cold hardening oligomers habe been used 19-75-99). In the case of resol foams the process technology is not different from that used for epoxy foams. Glass, phenolic resins, carbon, polystyrene, polyacrylonitrile and poly(vinylidene chloride) microspheres have been used as fillers ... 

PS PSF PSU PTFE PU PUR PVA PVAL PVB PVC PVCA PVDA PVDC PVDF PVF PVOH SAN SB SBC SBR SMA SMC TA TDI TEFE TPA UF ULDPE UP UR VLDPE ZNC Polystyrene Polysulfone (also PSU) Polysulfone (also PSF) Polytetrafluoroethylene Polyurethane Polyurethane Poly(vinyl acetate) Poly(vinyl alcohol) poly(vinyl butyrate) Poly(vinyl chloride) Poly(vinyl chloride-acetate) Poly(vinylidene acetate) Poly(vinylidene chloride) Poly(vinylidene fluoride) Poly(vinyl fluoride) Poly(vinyl alcohol) Styrene-acrylonitrile copolymer Styrene-butadiene copolymer Styrene block copolymer Styrene butadiene rubber Styrene-maleic anhydride (also SMC) Styrene-maleic anhydride (also SMA) Terephthalic acid (also TPA) Toluene diisocyanate Ethylene-tetrafluoroethylene copolymer Terephthalic acid (also TA) Urea formaldehyde Ultralow-density polyethylene Unsaturated polyester resin Urethane Very low-density polyethylene Ziegler-Natta catalyst... 

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