Vertical media

A comparison of horizontal and vertical media is given by Mallinson [11], He shows that most of the signal from either type of medium comes from the region nearest the surface and that the behaviors of horizontal and vertical media approach each other as the bit frequency becomes high. Although the media themselves may not differ fundamentally in the maximum attainable storage density, there may be differences between the total head-disk assemblies when the head designs for the two... 

The substrate was also found to influence the properties of the electrolessly deposited vertical media CoNiMnP, CoNiReMnP, and CoNiReP. The c-axis orientation had a larger degree of perpendicular orientation for films deposited on electroless NiP than for those deposited on Cu foil, presumably because of the smaller roughness of the former substrate [43]. The double-layer (magnetically soft interface, magnetically hard bulk) properties of CoNiReP deposited on a NiMoP underlayer [57] have already been discussed. 

Since vertical recording is not yet being employed in disk files, the electrochemical deposition of perpendicular materials is still at an exploratory stage. Electroplated vertical media are uncommon. In some cases, the vertical media are modifications of materials used as horizontal media. In others, the vertical medium is produced by introducing a strong shape anisotropy. 

Vertical media with very high coercivities can be produced by plating into alumina pores [112], Some of these media are too hard to be easily written with present heads. Tailoring of the pore size can be used to obtain structures with the desired Hc [115, 116], however. Recording characteristics of disks have been determined [112-114, 116] such media show excellent promise as vertical recording media. In addition, structures with electrodeposited Fe in the pores were tested in life-tests at elevated temperatures and humidity and in corrosive atmospheres. They were found to perform satisfactorily. 

Fig. 8. Schematic representation of a vertical media fabricated by electrodeposition of a ferromagnetic metal into the pores of alumina cells formed by anodization of an Al disk [107]. (Reprinted by permission of The Electrochemical Society).

Electrolessly deposited vertical media are generally CoNiP alloys containing Mn or Re or both. The Ni is added to lower the Ms and hence to lower the demagnetizing... 

Another potential vertical medium is not a continuous thin film, but rather an assembly of metal particles deposited in well defined pores in an alumina film on Al [109-117]. The shape anisotropy of the particles gives the desired vertical anisotropy. In producing such structures, the proper conditions for the anodization of the Al disk and for the subsequent control of pore size are as important as the conditions of metal deposition. The structures of such disks are discussed in detail below. 

Disk Filters A disk filter is a vacuum filter consisting of a number of vertical disks attached at intervals on a continuously rotating horizontal hollow central shaft (Fig. 18-127). Rotation is by a gear drive. Each disk consists of 10 to 30 sectors of metal, plastic, or wood, ribbed on both sides to support a filter cloth and provide drainage via an outlet nipple into the central shaft. Each sector may be replaced individually. The filter medium is usually a cloth bag slipped over the sectors and sealed to the discharge nipple. For some heavy-duty applications on ores, stainless-steel screens may be used. 

A few variations on the standard fermenter have been attempted, but none has become popular. An obsolete design in which the fermenter was rotated to aerate the medium is shown in Fig. 24-5. Performance was unsatisfactory, and the units were turned on end, with spargers and agitation added. One of the largest fermenters used for antibiotics is a horizontal cylinder with several agitators, as in Fig. 24-6. Multiple agitator motors and shafts have also been used with vertical cylindiic vessels. 

Let us examine some batch results. In trials in which 5 mL of a dye solution was added by pipet (with pressure) to 10 mL of water in a 25-mL flask, which was shaken to mix (as determined visually), and the mixed solution was delivered into a 3-mL rectangular cuvette, it was found that = 3-5 s, 2-4 s, and /obs 3-5 s. This is characteristic of conventional batch operation. Simple modifications can reduce this dead time. Reaction vessels designed for photometric titrations - may be useful kinetic tools. For reactions that are followed spectrophotometrically this technique is valuable Make a flat button on the end of a 4-in. length of glass rod. Deliver 3 mL of reaction medium into the rectangular cuvette in the spectrophotometer cell compartment. Transfer 10-100 p.L of a reactant stock solution to the button on the rod. Lower this into the cuvette, mix the solution with a few rapid vertical movements of the rod, and begin recording the dead time will be 3-8 s. A commercial version of the stirrer is available. 

Repeat the above steps for dissociation of HCl in waU (label the vertical axis aqueous phase energy). T1 energies contained in this sequence have been obtaine by calculating the effect a polar medium like water won have on the dissolved species. How many energy minin are there What species do these minima correspond t(... 

The results of Petree and Small are summarized in [29]. These coils present a solid vertical face, with the coils vertical but impressed in the plates for flow of the heating or cooling medium. They take the place of vertical baffles, and are more solid obstructions to through flow in die vessel than individual vertical coils. Usually four or six banks are used. 

For horizontal thermosiphon/natural units the boiling fluid is almost always on the shell side, with the heating medium in the tubes. In the vertical units the reboiling of the fluid is in the tubes. For kettle units, the boiling is in the shell. ColUns suggests a rule of thumb that if the viscosity of the reboUer is less than 0.5 centipoise (cp), the vertical thermosiphon should be considered, but when the viscosity is more than 0.5 cp, the horizontal reboUer is probably more economical. 

Natural circulation reboilers are effective and convenient units for process systems operating under pressure. They are usable in vacuum applications but must be applied with care, because the effect of pressure head (liquid leg) on the boiling point of the fluid must be considered. The temperature difference between the heating medium and boiling point of the fluid may be so small as to be impractical, regardless of the tube length in a vertical unit. 

Loop Tests Loop test installations vary widely in size and complexity, but they may be divided into two major categories (c) thermal-convection loops and (b) forced-convection loops. In both types, the liquid medium flows through a continuous loop or harp mounted vertically, one leg being heated whilst the other is cooled to maintain a constant temperature across the system. In the former type, flow is induced by thermal convection, and the flow rate is dependent on the relative heights of the heated and cooled sections, on the temperature gradient and on the physical properties of the liquid. The principle of the thermal convective loop is illustrated in Fig. 19.26. This method was used by De Van and Sessions to study mass transfer of niobium-based alloys in flowing lithium, and by De Van and Jansen to determine the transport rates of nitrogen and carbon between vanadium alloys and stainless steels in liquid sodium. 

The H-type cell devised by Lingane and Laitinen and shown in Fig. 16.9 will be found satisfactory for many purposes a particular feature is the built-in reference electrode. Usually a saturated calomel electrode is employed, but if the presence of chloride ion is harmful a mercury(I) sulphate electrode (Hg/Hg2 S04 in potassium sulphate solution potential ca + 0.40 volts vs S.C.E.) may be used. It is usually designed to contain 10-50 mL of the sample solution in the left-hand compartment, but it can be constructed to accommodate a smaller volume down to 1 -2 mL. To avoid polarisation of the reference electrode the latter should be made of tubing at least 20 mm in diameter, but the dimensions of the solution compartment can be varied over wide limits. The compartments are separated by a cross-member filled with a 4 per cent agar-saturated potassium chloride gel, which is held in position by a medium-porosity sintered Pyrex glass disc (diameter at least 10 mm) placed as near the solution compartment as possible in order to facilitate de-aeration of the test solution. By clamping the cell so that the cross-member is vertical, the molten... 

Elutriation differs from sedimentation in that fluid moves vertically upwards and thereby carries with it all particles whose settling velocity by gravity is less than the fluid velocity. In practice, complications are introduced by such factors as the non-uniformity of the fluid velocity across a section of an elutriating tube, the influence of the walls of the tube, and the effect of eddies in the flow. In consequence, any assumption that the separated particle size corresponds to the mean velocity of fluid flow is only approximately true it also requires an infinite time to effect complete separation. This method is predicated on the assumption that Stokes law relating the free-falling velocity of a spherical particle to its density and diameter, and to the density and viscosity of the medium is valid... 

Figure 4.50. Cumulative dissolution results. Two experimental tablet formulations were tested against each other in a dissolution test in which tablets are immersed in a stirred aqueous medium (number of tablets, constructional details and operation of apparatus, and amount of medium are givens). Eighty or more percent of the drug in either formulation is set free within 10 minutes. The slow terminal release displayed by formulation B could point towards an unwanted drug/excipient interaction. The vertical bars indicate ymean - with Sy 3%. A simple linear/exponential model was used to approximate the data for the strength 2 formulation. Strengths I and 3 are not depicted but look very similar.

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