Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Typing of acids and bases

C17-0038. Prepare a table listing the various types of acids and bases and the identifying features of each. [Pg.1262]

New polar organic mode a. Type of acid and base... [Pg.67]

There s no easy, foolproof way to decide whether something is an acid or a base. Fortunately, there are only a few types of acids and bases you will encounter in biochemistry. Notice that all bases will be more negatively charged than the acids they came from. [Pg.255]

Fig. 9. Plots of logio ft versus ApK for proton transfer between various types of acids and bases. Fig. 9. Plots of logio ft versus ApK for proton transfer between various types of acids and bases.
Comparison of Various Types of Acid and Base Catalysts in the Mutarotation of D-Glucose ... [Pg.23]

Table 1 shows the three possible types of acids and bases and examples of corresponding molecules. These types of acids and bases lead to nine possible acid-base adducts. Five of these combinations, namely n n, n-a, n-u, n-a, and rr-rr, yield the addition type complexes whereas the other four combinations lead to adducts with displacement [23]. For example, the interaction of PMMA in chloroform results in the formation of an n-cr acid base adduct. PMMA is a Lewis base due to the nonbonding electron doublets from the oxygen in the C = 0 group whereas the aeceptor site in chloroform is its C H antibonding a orbital. [Pg.104]

The graph below shows the neutralization curve for 100 mL of 0.100 M acid with 0.100 M base. Which letter represents the equivalence point What type of acid and base produced this curve ... [Pg.593]

Additional examples of acid- and base-catalyzed reactions of this type are giveh 1ft equations (23)-(32). [Pg.74]

Examples through illustrate the two main types of equilibrium calculations as they apply to solutions of acids and bases. Notice that the techniques are the same as those introduced in Chapter 16 and applied to weak acids in Examples and. We can calculate values of equilibrium constants from a knowledge of concentrations at equilibrium (Examples and), and we can calculate equilibrium concentrations from a knowledge of equilibrium constants and initial concentrations (Examples, and ). [Pg.1228]

Catalytic transformations can be divided on the basis of the catalyst-type - homogeneous, heterogeneous or enzymatic - or the type of conversion. We have opted for a compromise a division based partly on type of conversion (reduction, oxidation and C-C bond formation, and partly on catalyst type (solid acids and bases, and biocatalysts). Finally, enantioselective catalysis is a recurring theme in fine chemicals manufacture, e.g. in the production of pharmaceutical intermediates, and a separate section is devoted to this topic. [Pg.30]

Since the rates of acid and base catalyzed reactions are sensitive to variations in the solution pH, it is instructive to consider the types of behavior that can be observed in aqueous solution in the laboratory. The disso-... [Pg.222]

Early attempts to fathom organic reactions were based on their classification into ionic (heterolytic) or free-radical (homolytic) types.1 These were later subclassified in terms of either electrophilic or nucleophilic reactivity of both ionic and paramagnetic intermediates - but none of these classifications carries with it any quantitative mechanistic information. Alternatively, organic reactions have been described in terms of acids and bases in the restricted Bronsted sense, or more generally in terms of Lewis acids and bases to generate cations and anions. However, organic cations are subject to one-electron reduction (and anions to oxidation) to produce radicals, i.e.,... [Pg.194]

In the study of chemistry the results of observations on the transformations and properties of many materials are encountered. Schemes that provide structure to the information concerning this type of chemistry go a long way toward systematizing its study. One such approach is that of the chemistry of acids and bases. Closely related to the chemistry of acids and bases is the study of solvents other than water, the chemistry of nonaqueous solvents (see Chapter 10). In this chapter, several areas of acid-base chemistry and their application to reactions of inorganic substances will be described. [Pg.289]

As we have seen, the Lewis theory of acid-base interactions based on electron pair donation and acceptance applies to many types of species. As a result, the electronic theory of acids and bases pervades the whole of chemistry. Because the formation of metal complexes represents one type of Lewis acid-base interaction, it was in that area that evidence of the principle that species of similar electronic character interact best was first noted. As early as the 1950s, Ahrland, Chatt, and Davies had classified metals as belonging to class A if they formed more stable complexes with the first element in the periodic group or to class B if they formed more stable complexes with the heavier elements in that group. This means that metals are classified as A or B based on the electronic character of the donor atom they prefer to bond to. The donor strength of the ligands is determined by the stability of the complexes they form with metals. This behavior is summarized in the following table. [Pg.313]

Decide what type and concentration of acid and base you will add to your systems. Dilute solutions of strong acids and bases work well. [Pg.569]

There are a number of limitations on the Brpnsted relationship. First of aU, the relation holds only for similar types of acids (or bases). For example, carboxylic acids may have a different a values compared to sulfonic acids or phenols. Because charge, and likewise solvation, can greatly influence the reaction rate, deviations of net charge from one catalyst to another can also influence Brpnsted plots. Another limitation on this relationship relates to temperature. Reaction rates and the corresponding dissociation constants for the acids must all be measured at the same temperature (and, most rigorously, in the same solvent). For some systems, this may prove infeasible. A third limitation is that the reaction must indeed be subject to general acid (or base) catalysis. For certain catalysts, deviations from a linear relationship may indicate other modes of action beyond general acid/... [Pg.100]

Understanding the behavior of acids and bases is essential to every branch of science having anything to do with chemistry. In analytical chemistry, we almost always need to account for the effect of pH on analytical reactions involving complex formation or oxidation-reduction. pH can affect molecular charge and shape—factors that help determine which molecules can be separated from others in chromatography and electrophoresis and which molecules will be detected in some types of mass spectrometry. [Pg.105]

James and Martin (49) reported on visual and automatic titration methods capable of detecting microgram quantities of acids and bases. This type of detection has the distinction of being the first type of detector used in gas-liquid chromatography. Electronically modified designs for improving the automation of the detector are possible. [Pg.284]

Acids and bases are two of the most common types of substances in the laboratory and the everyday world. We need to know how to recognize them, what their characteristic reactions are, and why they are such important chemicals. We shall see that keeping the concentrations of acids and bases in plant and animal cells within certain limits is necessary for the survival of individual organisms, and controlling the acidity of rain, of natural waters such as lakes and rivers, and of municipal water supplies is necessary to sustain human societies. [Pg.593]

What is it that makes an acid an acid and a base a base We first raised those questions in Section 4.5, and we now take a closer look at some of the concepts that chemists have developed to describe the chemical behavior of acids and bases. We ll also apply the principles of chemical equilibrium discussed in Chapter 13 to determine the concentrations of the substances present in aqueous solutions of acids and bases. An enormous amount of chemistry can be understood in terms of acid-base reactions, perhaps the most important reaction type in all of chemistry. [Pg.612]

We ve seen on numerous occasions that the neutralization reaction of an acid with a base produces water and a salt. But to what extent does a neutralization reaction go to completion We must answer that question before we can make pH calculations on mixtures of acids and bases. Let s look at four types of neutralization reactions (1) strong acid-strong base, (2) weak acid-strong base, (3) strong acid-weak base, and (4) weak acid-weak base. [Pg.664]

Separations and Analyses. After removal of trace amounts of acids and bases from the <200° C distillates by extraction methods (16), a chromatographic separation with silica gel provided a check for the presence of olefins. No olefins were detected thus, the acid- and base-free distillates were analyzed by ASTM D2789-71, Standard Method of Test for Hydrocarbon Types in Low Olefinic Gasoline by Mass Spectrometry. The separation and analysis scheme for this distillate is shown in Figure 2. [Pg.11]

Qualitative and quantitative aspects of the Lewis theory of acids and bases, and practical applications of Lewis acids, are discussed in a series of monographs [1,4-6,30-46] and reviews [47-49], The following aspects are taken into account (a) electronic configuration of acceptors (A = M MX are generally metal and boron salts), (b) nature of anions (usually halides), (c) peculiarities of thin structure of donors (B are generally the compounds containing N, P, As, Sb O, S, Se, Te F, Cl, Br, I atoms) their electronic structure, spatial accessibility, and mutual position of donor centers. Moreover, the nature of X, order of binding of A and B in formation of adducts of type AB , nature of solvents, and evaluation of AH or AG of the processes (1.1)—(1.5) [31,48] should also be considered. [Pg.6]

Chemical reactions, in particular complex formation, can be classified as acid-base ones the resulting products can be examined as complexes of the type Lewis acids and bases. [Pg.7]

There is another common way to classify chemical reactions acid-base reactions, oxidation-reduction reactions, and reactions of more complicated types (beyond the scope of this book). Acid-base reactions are considered to involve the reactions of hydrogen ions with hydroxide ions. The reactions of acids and bases will be taken up in this section, and a more sophisticated view of these reactions is presented in Chapter 19. Oxidation-reduction reactions involve the transfer of electrons from one substance to another. Many combination reactions, many decomposition reactions, all single substitution reactions, and all combustion reactions are of this type, but more complex examples are presented in Chapters 16 and 17. [Pg.237]


See other pages where Typing of acids and bases is mentioned: [Pg.252]    [Pg.14]    [Pg.252]    [Pg.14]    [Pg.175]    [Pg.244]    [Pg.210]    [Pg.43]    [Pg.151]    [Pg.87]    [Pg.952]    [Pg.8]    [Pg.138]    [Pg.45]    [Pg.31]    [Pg.152]    [Pg.153]    [Pg.190]    [Pg.710]    [Pg.557]    [Pg.69]    [Pg.251]    [Pg.98]    [Pg.233]   
See also in sourсe #XX -- [ Pg.73 ]




SEARCH



Acidity, types

Acids types

Types of acids and bases

Types of acids and bases

© 2024 chempedia.info