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Transmission Cells Liquids

Be aware that cells made from nontraditional window materials, such as zinc selenide, zinc sulfide, germanium, or other medium to high refractive index materials, will usually result in the production of interference fringes, even in the presence of the sample. [Pg.64]

A product produced by 3M, known as the IR card, uses a thin polymer film (polyethylene or PTFE) as a substitute for a traditional window. This is a relatively inexpensive method of sampling. However, if used, it is normally [Pg.64]


One of the most important factors in the selection of the sample handling technique is to attempt to analyze the sample, as it exists, without any form of chemical or physical modification. For gases and certain liquids, simple transmission cells, often with a flow-through configuration meet these requirements. [Pg.186]

Local extractive/fibre-optic-based systems. This is a development of the above where a fibre-optic-linked liquid sample transmission cell is integrated with the sample fast-loop cabinet (Figures 3.28 and 3.29). There can be multiple sample streams, take-offs and fast-loops, each with its own separate fibre-optic transmission cell. The analyser can be either local with short fibre-optic runs to the sampling cabinet(s), or remote, where a safe area location for the analyser module may be feasible, but at the cost of longer, potentially less stable fibre-optic runs. This system allows to avoid physical stream switching. [Pg.78]

An alternative to supporting the mica on an internal reflection element is to use thicker mica sheets as windows in a liquid transmission cell. The thicker mica was required to prevent the deformation or tearing of the mica when liquids were injected into the cell, but this returned us to the... [Pg.243]

A transmission cell was used in the studies reported by van Leeuwen [18,21, 30,43]. The autoclave and the transmission cell are only a few millimetres apart and the liquid is pumped with a centrifugal pump from the autoclave to the cell. The time delay between autoclave and cell can be as low as a few milliseconds. The advantage is a higher signal-to-noise ratio. The in-situ measurements on Xantphos type ligand systems showed that the only species that can be observed... [Pg.312]

The IR spectra of liquids and solutions are recorded in the transmission mode by placing the sample between two windows made of IR-transmitting material in a transmission cell. A schematic representation of a transmission cell is presented in Figure 12. The spacer placed between the two windows determines the sample thickness or cell pathlength (b in equation (13)). Transmission cells may be either demountable or sealed. In the case of demountable cells, the sample is loaded into the cell by disassembling the cell, applying the sample onto the face of one of the windows, and... [Pg.113]

Figure 6.7. Experimental set-up to measure transmission of liquid crystal cell against applied magnetic field. (Modified from DuPre, 1982.)... Figure 6.7. Experimental set-up to measure transmission of liquid crystal cell against applied magnetic field. (Modified from DuPre, 1982.)...
Figure 4 Volatile liquid vapor transmission cell. Figure 4 Volatile liquid vapor transmission cell.
In the 1970s, HP-IR for homogeneous catalysis was generally carried out in modified autoclaves, using either transmission or reflectance cells to obtain the spectrum. Typical transmission cells require the use of suitable windows built into the autoclave body which can withstand both high pressures and chemical exposures (Figure 2). The autoclave sits within the body of the IR spectrometer, and can be connected to gas and liquid supplies as... [Pg.487]

Solutions Solids may be examined in solution in transmission cells (see the section Liquids ), provided a suitable solvent is available. This can be an effective way of eliminating crystalline lattice effects. ITowever, since no solvent is transparent throughout the entire infrared region, several solvents may be required for complete solute detail, or alternatively an analytically useful difference spectrum may be generated from a single solution, provided solvent-solute interactions are minimal. Solutions offer an important presentation method for quantitative applications, although many of the best solvents are toxic and flammable and must be used with appropriate care, safety, and caution. [Pg.2235]

Vibrational spectroelectrochemical techniques, particularly Fourier transform infrared (FTIR), with the advent of less-expensive and more sensitive spectrometers, have enjoyed a great increase in popularity over the last few years. The advantages over UV-vis spectroscopy include greater specificity and enhanced information content. An IR OTTLE transmission cell with IR-transparent windows can be built by modifying a commercial liquid cell. Raman spectroscopy is also very easily carried out with an OTTLE cell, but a flow cell is more useful for SERS studies of adsorption, since the solution can be replaced without disturbing the optical alignment. [Pg.4450]

With modem sampling techniques, good quantitative infrared analysis with virtually every type of sample is practicable however, liquids are ideal for this purpose, being measured in a liquid cell of fixed thickness, either as 100% sample or diluted with solvent. In this connection it should be taken into account that there are no ideal solvents for infrared spectroscopy [35]. In addition, because absorption bands and path length can be influenced by the temperature of the transmission cell, it is advisable to control the temperature. [Pg.473]

Liquid samples are easily studied with the aid of a wide variety of liquid cells, including heatable. flow through, and variable path length cells. These cells are constructed of two infrared transparent windows with a spacer between them, thereby forming a cavity for the sample. As the samples are often strong infrared absorbers, for this spectral range the liquid transmission cell must be constructed with short optical path lengths (0.025 -1 mm). [Pg.490]

Gas cells may be considered a special form of transmission cell. The difference is primarily in the construction of the body of the cell and its extended pathlength. In essence, a traditional gas cell (short path length) is a tube (with filling ports) with windows mounted and sealed at both ends. Like liquid cells, gas cells are available in demountable (removable windows) and permanent formats (bonded windows). Materials of construction can be important, especially if corrosive gases or vapors are studied. The most inexpensive cells feature glass tubular bodies, and these are ideal for many sample types. For a more rigid construction, cell bodies made from stainless steel, Monel, and Hastelloy C are available. [Pg.65]

Perez-Marin et al. (42) significantly improved these results by using MPLS for regression purposes and SNV and detrending treatments to correct for scatter. Nufiez-Sanchez et al. (36) compared the accuracy of folded transmission in liquid milk and reflectance of dried milk NIR calibration equations to predict quality parameters of ewe s milk. The results obtained for each constituent in both NIR analysis modes showed excellent capacity for quantitative analysis with higher than 0.9. Also, the equation obtained for somatic cell count (SCC) by both methods had adequate accuracy, similar to that obtained for goat s milk by Perez-Marin et al. (42) and much higher than the model reported by Tsenkova et al. (54). [Pg.326]

It is possible to purchase variable-pathlength liquid transmission cells, which commonly have a pathlength that can be varied between 5 pm and 5 mm. A suitable sample must be chosen, preferably a neat solvent that has relatively wide peaks, the resolution of the spectrometer must be set so that the resolution parameter, p, is no greater than 0.5, and a Norton-Beer medium apodization function should be applied. A series of measurements at increasing pathlengths should yield a linear Lambert plot if the instrument is functioning correctly. Some instruments will exhibit linear Lambert plots up to 4 AU however, this is unusual, and an acceptable... [Pg.199]

Fourier Transform Mid-IR Test Apparatus—The type of apparatus suitable for use in this test method employs an IR source, an infrared transmission cell or a liquid attenuated total internal reflection cell, a scanning interferometer, a detector, an A-D converter, a microprocessor and a sample introduction system. [Pg.989]


See other pages where Transmission Cells Liquids is mentioned: [Pg.64]    [Pg.64]    [Pg.314]    [Pg.133]    [Pg.428]    [Pg.108]    [Pg.113]    [Pg.198]    [Pg.6]    [Pg.89]    [Pg.124]    [Pg.245]    [Pg.312]    [Pg.115]    [Pg.296]    [Pg.505]    [Pg.306]    [Pg.493]    [Pg.55]    [Pg.56]    [Pg.64]    [Pg.75]    [Pg.226]    [Pg.429]    [Pg.121]    [Pg.48]    [Pg.1062]    [Pg.989]    [Pg.89]   


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