Thermoplastic polyester properties

Ticona Corp., Florence, KY, Celanex Thermoplastic Polyester-Properties and Processing. http //www.Ticona.com. 2010. 

Properties Poly(aryl ether), unfilled Polycarbonate Thermoplastic polyester ... 

A wide variety of thermoplastics have been used as the base for reinforced plastics. These include polypropylene, nylon, styrene-based materials, thermoplastic polyesters, acetal, polycarbonate, polysulphone, etc. The choice of a reinforced thermoplastic depends on a wide range of factors which includes the nature of the application, the service environment and costs. In many cases conventional thermoplastic processing techniques can be used to produce moulded articles (see Chapter 4). Some typical properties of fibre reinforced nylon are given in Table 3.2. 

Polyesters are one of the most versatile classes of polymers ever produced, covering a wide range of properties and applications. Polyesters are present in fibers, engineering thermoplastics, and high-performance polymers as well as in thermosetting resins and elastomers. Table 2.1 lists the chemical structure, abbreviations, and uses of some commercially important thermoplastic polyesters. 

Polyester polyols, 25 464 468 Polyester resin(s), 11 302 coating resins, 7 104-106 cyclopentadiene and dicyclopentadiene applications, 8 230 flammability of, 20 115-116 properties in powder coating, 7 43t standard test methods for, 20 11 It unreinforced, 10 187t weathering of, 20 116 Polyester resin-based powder coatings, organic titanium compounds in, 25 125 Polyester resin composites, 26 762-763 Polyester resin formulations ingredients of, 20 96t unsaturated, 15 511-512 Polyesters, 10 185-189, 497 12 655-656. See also Thermoplastic polyesters Unsaturated polyesters acid resistance of, 20 7-8 antioxidant applications, 3 121 aromatic ionic, 23 722 based on 1,4-cyclohexanedimethanol, 12 674-675... 

The primary crystalline polymer based on CHDM is the terephthalate, poly(1,4-cyclohexylenedimethylene terephthalate) (PCT). This polyester was originally developed for fiber applications but has since found wider utility as a reinforced polymer for injection molding and (when copolymerized with a small amount of isophthalic acid) as a material for crystallized food packaging trays. The key property of PCT which sets it apart from other thermoplastic polyesters in these latter applications is its melting point. 

Table 15.2 Selected properties of 30% glass-fiber-reinforced (GFR) thermoplastic polyester composites [15-17]...

Poly(butylene terephthalate) (PBT) is a semicrystalline, thermoplastic polyester which is completely analogous to PET except that it has a longer, more flexible butylene chain linkage which imparts a rapid crystallization rate, thus making PBT well suited to injection moulding processes. This polyester is used widely for electrical and electronic components due to its high temperature resistance and good electrical properties (Chapter 8). 

ISO 23711 2003 Elastomeric seals - Requirements for materials for pipe joint seals used in water and drainage applications - Thermoplastic elastomers ISO 14910-1 1997 Plastics - Thermoplastic polyester/ester and polyether/ester elastomers for moulding and extrusion - Part 1 Designation system and basis for specifications ISO 14910-2 1997 Plastics - Thermoplastic polyester/ester and polyether/ester elastomers for moulding and extrusion - Part 2 Preparation of test specimens and determination of properties... 

Eigure 6 shows the stiffness of Ecoflex /PLA blends depending on the PLA amount. PLA today is a thermoplastic polymer made from renewable raw materials and is available on industrial scale. Blending the completely different thermoplastic polyesters - stiff and brittle PLA with soft and flexible Ecoflex - a whole range of different material properties can be accessed, depending on the ratio of both polymers. 

POLYCYCLO-ITEXYLENE-Dl METHYLENE TEREPHTHALATE. PCT is 1,4-cyclohexvlene-dimethylene terephthalate and is a high-temperature. semicrystalline thermoplastic polyester. PCT possesses excellent thermal properties. Injection molding is the predominant method of processing glass fiber-reinforced grades of PCT. It is widely used for... 

The decorative laminates described in the previous chapter are made with selected thermosetting resins while resins of this type can be moulded and extruded by methods similar to those outlined in the present and the next chapter the materials employed for these processes predominantly are thermoplastic. Many such plastics can be moulded and extruded under suitable conditions, the most important in terms of quantities used being those that combine properties satisfactory for the purpose with convenience in pro-cessing-especially the polyolefins (polyethylene and polypropylene), poly(vinyl chloride), and styrene polymers and blends. Other plastics with special qualities, such as better resistance to chemical attack, heat, impact, and wear, also are used—including acetals (polyformaldehyde or polyoxymethylene), polyamides, polycarbonates, thermoplastic polyesters like poly(ethylene terephtha-late) and poly(butylene terephthalate), and modified poly(phenylene oxide),... 

The moisture resistance properties of filled molding compounds are enhanced by the treatment of the fillers with silane adhesion promoters prior to compounding. Silane promoters on wollastonite fillers in thermoplastic polyester molding compounds (50 percent filled) will improve the flexural strength after 16 h in 50°C water by as much as 40 percent. Silane-treated silica fillers have been found to significantly increase the moisture resistance of epoxy adhesives used in the electronics industry for chip, surface-mounted, and printed-circuit processes.8... 

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