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Thermodynamic Formulations of Transition State Theory

Theoretical calculations are less fundamental and rigorous for solution reactions. This is a consequence of the difficulty of calculating partition functions in solution. The main focus for solution reactions has been on the thermodynamic formulation of transition state theory. [Pg.265]

Answer. The thermodynamic formulation of transition state theory (Section 4.4 and Equations (4.39) and (4.40)) is... [Pg.290]

The thermodynamic formulation of transition state theory is useful in considerations of reactions in solution when one is examining a particular class of reactions and wants to extrapolate kinetic data obtained for one reactant system to a second system in which the same functional groups are thought to participate (see Section 7.4). For further discussion of the predictive applications of this approach and its limitations, consult the books by Benson (60) and Laidler (61). Laidler s kinetics text (39) and the classic by Glasstone et al. (55) contain additional useful background material. [Pg.103]

From a comparison of the Arrhenius equation and the thermodynamic formulation of transition state theory of unimolecular reactions, it is seen that the Ea is related to the enthalpy of activation (A// ) and the A-factor is related to the entropy of activation (AS ) ... [Pg.591]

The early to mid 1930s was a time of intensive activity in the formulation of transition-state theory (TST). Laidler and King [1] have provided an excellent review of the early history of TST, tracing the development of rate theories using treatments based upon thermodynamics, kinetic theory, and statistical mechanics, and focusing on Eyring s 1935 contribution to the formulation of TST [2]. A snapshot of the state of the development of TST and some of the controversy surrounding it in 1937 is captured in volume 34 of the Transactions of the Faraday... [Pg.42]

The thermodynamic formulation of reaction rates is also particularly useful in discussing rates in ideal solutions. Indeed, the concept of collision between molecules and the derivations of the kinetic theory of gases seem to be useless in the condensed state. Yet, the results of transition-state theory are not limited to the treatment of ideal gas mixtures. In particular, these results can also be couched in the language of the colU on theory. This may appear surprising since the concept of collision in condensed phases is not a fruitful one. Yet it is found that normal reactions in solution exhibit a rate constant described by (2.5.3) with a probability factor P close to unity. [Pg.56]

Quantitative estimates of E are obtained the same way as for the collision theory, from measurements, or from quantum mechanical calculations, or by comparison with known systems. Quantitative estimates of the A factor require the use of statistical mechanics, the subject that provides the link between thermodynamic properties, such as heat capacities and entropy, and molecular properties (bond lengths, vibrational frequencies, etc.). The transition state theory was originally formulated using statistical mechanics. The following treatment of this advanced subject indicates how such estimates of rate constants are made. For more detailed discussion, see Steinfeld et al. (1989). [Pg.143]

A well defined theory of chemical reactions is required before analyzing solvent effects on this special type of solute. The transition state theory has had an enormous influence in the development of modern chemistry [32-37]. Quantum mechanical theories that go beyond the classical statistical mechanics theory of absolute rate have been developed by several authors [36,38,39], However, there are still compelling motivations to formulate an alternate approach to the quantum theory that goes beyond a theory of reaction rates. In this paper, a particular theory of chemical reactions is elaborated. In this theoretical scheme, solvent effects at the thermodynamic and quantum mechanical level can be treated with a fair degree of generality. The theory can be related to modern versions of the Marcus theory of electron transfer [19,40,41] but there is no... [Pg.284]

The thermodynamic formulation of the transition state theory (TST), as applied to a unimolecular reaction described symbolically by... [Pg.135]

V.2.1 Centroid transition state theory. A third methodology, is to construct approximate theories for dynamical properties, which make use of only thermodynamic quantities. In analogy with classical TST, Gillan, Voth and coworkers have formulated and studied a quantum TST which is based on the centroid potential of mean force Wc (q) ... [Pg.29]

For some reactions, especially those involving large molecules, it might be difficult to determine the precise structure and energy levels of the activated complex. In such cases, it can be useful to phrase the transition-state theory result for the rate constant in thermodynamic terms. It does not bring any new information but an alternative way of interpreting the result. This formulation leads to an expression where the preexponential factor is related to an entropy of activation that, at least qualitatively, can be related to the structure of the activated complex. We will encounter the thermodynamic formulation again in Chapter 10, in connection with chemical reactions in solution, where this formulation is particularly useful. [Pg.161]

The rate constant can be expressed by using molecular, statistical mechanical, and thermodynamical quantities, functions, and formulations. For instance, in the transition state theory of chemical reactions for an elementary reaction... [Pg.570]

The thermodynamic transition-state theory (TTST) is utilized for the elementary steps within the Langmuir-Hinshelwood-Hougen-Watson (LHHW) framework to develop rate expressions for liquid-phase catalytic reactions in terms of activities for the family of tertiary alkyl ethyl ethers. The TTST formulation also provides a rationale for the extrathermodynamic correlations (ETC) observed. [Pg.559]

Transition state theory, if valid, can also be used to determine the tightness or looseness of the transition state molecular configuration as compared to that of the reactants. When transition state theory is formulated in thermodynamic terms it is found that the high pressure Arrhenius A- factor is given by... [Pg.59]

Having analyzed the role of the standard state with reference to Eqs. (2-70) and (2-71), we continue the thermodynamic formulation of the transition-state theory by considering the temperature dependence of the rate constants in terms of the parameters of absolute rate theory. For reactions in the gas phase, rate constants are normally expressed in terms of concentration units so that the equilibrium constant X in Eq. (2-71) also is in concentration units. However, the standard state normally employed for gases is 1 atm. The relationship between the equilibrium constant expressed in terms of concentration, X/, and the equilibrium constant expressed in terms of pressures, Xp, for ideal gases is... [Pg.57]

Equation (9) is valid if, as in the case of reaction (3), the partial orders of the reagents in the forward and reverse reactions equal their molecularities (i.e., the number of species involved in the process). This is true for all elementary reactions and, depending on the mechanism, for some composite reactions also. According to the thermodynamic formulation of conventional transition-state theory, the rate constant of an elementary reaction is given by ... [Pg.608]

An important area of application for QM methods has been determining and describing reaction pathways, energetics, and transition states for reaction processes between small species. QM-derived first and second derivatives of energy calculated at stable and saddle points on PES can be used under statistical mechanics formulations [33, 34] to yield enthalpies and free energies of structures in order to determine their reactivity. Transition state theory and idealized thermodynamic relationships (e.g., AG[Po—>P] = kTln[P/Po]) allow temperature and pressure regimes to be spanned when addressing simple gas phase and gas-surface interactions. [Pg.7]

From a chemical viewpoint, bond scission under stress is a particular case of a un-imolecular dissociation reaction whose rate is enhanced by mechanical stress. As such, it could be treated with Eyring s transition-state theory [Eq. (37)], which permits one to bring the treatment of rate processes within the scope of thermodynamic arguments. By combining de Boer s thermodynamic formulation and the transition-state theory, Tobolsky and Eyring in 1943 developed the rate theory for thermally activated fracture of polymeric threads. When put into an Arrhenius-... [Pg.815]

Another way of calculating the reaction rate constant is by means of the transition state theory (TST). This theory was developed simultaneously in 1935 by Eyring [5] and by Evans and Polanyi [6]. There exist different formulations of the TST, but only the thermodynamical formulation will be described herein. [Pg.6]

Max Trautz in 1916 and Wilham Lewis in 1918 developed mathematical expressions that allowed the formulation of a collision theory for pre-exponential factors. In 1936 Henry Eyring, and almost independently, Michael Polanyi and M.G Evans came to develop the transition state theory, having as its bases thermodynamics and statistical mechanics. [Pg.4]


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See also in sourсe #XX -- [ Pg.140 , Pg.141 , Pg.142 , Pg.143 , Pg.144 , Pg.265 , Pg.269 , Pg.269 , Pg.270 , Pg.271 ]




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