Thermal compressor

Compression evaporation could be defined as an evaporation process in which part, or all, of the evaporated vapor is compressed by means of a suitable compressor to a higher pressure level and then condensed the compressed vapor provides part of all of the heat required for evaporation. Compression evaporation is frequently called recompression evaporation. All compression methods use the vapors from the evaporator and recycle them to the heating side of the evaporator. Compression can be achieved with mechanical compressors or with thermal compressors. Thermal compression uses a steam jet to compress a fraction of the overhead vapors with high pressure steam. Mechanical compression uses a compressor driven by a mechanical drive (electric motor or steam turbine) to compress all the overhead vapors. 

The Vuilleumier refrigeration cycle has frequently been described as a Stirling cycle with a thermal compressor instead of a mechanical compressor. Recently, it has generated much interest in the area of spacecraft applications where the advantages of long-lifetime operation, low acoustical noise, and minimal wear of moving parts have been extensively examined. 

For air compressors Operating safety Thermal stability, Volatility Resistance to oxidation Extreme pressure and anti-wear (compressors) properties Low coking tendency (hot reciprocating compressors)... 

Like steam injection, in-situ combustion is a thermal process designed to reduce oil viscosity and hence improve flow performance. Combustion of the lighter fractions of the oil in the reservoir is sustained by continuous air injection. Though there have been some economic successes claimed using this method, it has not been widely employed. Under the right conditions, combustion can be initiated spontaneously by injecting air into an oil reservoir. However a number of projects have also experienced explosions in surface compressors and injection wells. 

Phosphate ester fluids are the most fire resistant of moderately priced lubricants, are generally excellent lubricants, and are thermally and oxidatively stable up to 135°C (38). Fire-resistant iadustrial hydrauHc fluids represent the largest volume commercial use. AppHcations are made ia air compressors and continue to grow for aircraft use (tributyl and/or an alkyl diaryl ester) and ia hydrauHc control of steam turbiaes ia power generation (ISO 46 esters). 

Miscellaneous Commercial Applications. Dimer acids are components of "downweU" corrosion inhibitors for oil-drilling equipment (see Petroleum Corrosion and corrosion inhibitors). This may account for 10% of current dimer acid use (71). The acids, alkyl esters, and polyoxyalkylene dimer esters are used commercially as components of metal-working lubricants (see Lubrication). Dimer esters have achieved some use in specialty lubricant appHcations such as gear oils and compressor lubricants. The dimer esters, compared to dibasic acid esters, polyol esters and poly(a-olefin)s, are higher in cost and of higher viscosity. The higher viscosity, however, is an advantage in some specialties, and the dimer esters are very stable thermally and can be made quite oxidatively stable by choice of proper additives. 

Mechanical Expanders Reciprocating expanders are very similar in concept and design to reciprocating compressors. Generally these units are used with inlet pressures of 4 to 20 MPa. These machines operate at speeds up to 500 rpm. The thermal efficiencies (actual enthalpy difference/maximum possible enthalpy difference) range from about 75 percent for small units to 85 percent for large machines. 

The Intercooled Regenerative Reheat Cycle The Carnot cycle is the optimum cycle between two temperatures, and all cycles try to approach this optimum. Maximum thermal efficiency is achieved by approaching the isothermal compression and expansion of the Carnot cycle or by intercoohng in compression and reheating in the expansion process. The intercooled regenerative reheat cycle approaches this optimum cycle in a practical fashion. This cycle achieves the maximum efficiency and work output of any of the cycles described to this point. With the insertion of an intercooler in the compressor, the pressure ratio for maximum efficiency moves to a much higher ratio, as indicated in Fig. 29-36. 

The operation of a motor at a rated load may be for an unlimited period to reach thermal equilibrium (Figure 3.1) and possible applictilions are pumps, blowers, fans and compressors. 

Most ethylene plants operate continuously with the expanders operating at or near design conditions. If necessary, due to their unique design characteristics, radial inflow turboexpanders can accommodate a wide range of process conditions without significant losses in thermal or mechanical efficiency. Expanders may be loaded with booster compressors, gear-coupled generators, dynamometers, or other in-plant mechanical equipment such as pumps. In ethylene plants, turboexpanders are typically used in eitlier post-boost or pre-boost applications. 

When combining compressors, expanders, and turbines, the speeds, thermal expansions, and thrust loads on shaft systems exist at different magnitudes and directions. These must be managed and accommodated with skill and experience. 

To obtain a more accurate relationship between the overall thermal efficiency and the inlet turbine temperatures, overall pressure ratios, and output work, consider the following relationships. For maximum overall thermal cycle efficiency, the following equation gives the optimum pressure ratio for fixed inlet temperatures and efficiencies to the compressor and turbine ... 

The condensing steam turbine has a relatively low thermal efficiency because about two-thirds of the steam enthalpy is lost to cooling water in the condenser. Expensive boiler feedwater treatment is required to remove chlorides, salts, and silicates, which can be deposited on the blades causing premature failure. The blades are already under erosion conditions because of water drops present in the condensing steam. Even with these disadvantages, the condensing turbine is still selected, especially in a process that requires very large compressor drivers and relatively low amounts of process steam. 

---