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The Edge Region

The Edge Region. - The X-ray near edge structure, or XANES, may be considered as a combination of two contributions. [Pg.5]

These features may be used as indicators of types of metal [Pg.5]

There have also been reports that the intensity of a white-line at the absorption edge may be correlated with the [Pg.5]

A note of caution is indicated though by some empirical observations on the L edge white-line intensities in some lanthanide compounds.In these compounds the white-lines at the L(II) and L(III) edges will be associated with 2p to 5d transitions. Even in lanthanide compounds, in which covalency and d orbital participation in bonding is much less pronounced than for transition elements, then the ligand type (and/or coordination number) also cause variation in these intensities. [Pg.6]

Attempts to calculate the spectrum profiles in this region below are relatively rare. Of particular note is an ab [Pg.6]


Equation (17) is plotted in Fig. 55 for the glycerin him (solid line) and the hexadecane him (dotted line) in the contact region (x r). Clearly, a rapid decrease in the values of the boiling point in the edge region can be found. The calcu-... [Pg.59]

Melroy and co-workers88 recently reported on the EXAFS spectrum of Pb underpotentially deposited on silver (111). In this case, no Pb/Ag scattering was observed and this was ascribed to the large Debye-Waller factor for the lead as well as to the presence of an incommensurate layer. However, data analysis as well as comparison of the edge region of spectra for the underpotentially deposited lead, lead foil, lead acetate, and lead oxide indicated the presence of oxygen from either water or acetate (from electrolyte) as a backscatterer. [Pg.302]

Figure 9.21 Auger spectra of cobalt-doped MoS2 crystals taken at a) the basal plane and b) the edge regions (from Chianelli el ul. [72]). Figure 9.21 Auger spectra of cobalt-doped MoS2 crystals taken at a) the basal plane and b) the edge regions (from Chianelli el ul. [72]).
Thus, for deep levels it is possible that the region x2 — X in which they are effective as traps is substantially less than the total depletion layer thickness W. For the case of a current transient the effect of the edge region is to change the expression given by Eq. (18) to (Grimmeiss, 1977)... [Pg.15]

For a p+-n junction where the edge region is negligible, x, = 0 and x2 = W so that D = 2 and Eq. (25) reduces to Eq. (18). Analogous corrections must also be considered for capacitance transients results for the Schottky diode case have, for instance, been given by Noras and Szawelska (1982). [Pg.15]

The ozone behaviour on 550 K has been in August similar to July. On the 475 K surface ozone has declined both inside and on the edge region of the vortex, but only the linear ozone trend on the edge region is statistically significant -0,12 ppmV/year (se 0,04). On the 435 K surface there is no trend detectable in August. [Pg.229]

The goal of present numerical code development is, therefore, to treat all the other, predictable, physical components of the model accurately. This applies, in particular, for the atomic, molecular and surface processes, which largely control the plasma flow and plasma energy content in the important near target region. If that can be achieved, then the unknown anomalous cross field transport can be separated and isolated computationally, and can then perhaps be determined experimentally even in the edge region. [Pg.31]

The peculiarities of plasma flow in the edge region of magnetic confinement fusion machines result from the strong stiffness of the equations (very different timescales within one problem), the inherently (at least) two-dimensional nature of the flow (on multiple connected domains), the extreme anisotropy (by a factor 106) in the flow, the strongly nonlinear dependence of the transport coefficients on the flow parameters, the large number of species (equations) to be considered simultaneously, and the nonlocal nature... [Pg.31]

Currently only Monte Carlo approaches can handle the wide range of surface geometries, reflection models and support complex atomic and molecular processes that occur in real fusion edge plasmas. Therefore the neutral particle transport (ionization, dissociation, etc.) as well as impurity ion transport in the edge region of fusion plasmas is often treated by Monte Carlo simulation on a kinetic level. [Pg.32]

Despite the fact that the substrate layer itself is not directly visualized in this experiment, it is clear that the enz3mies are localized primarily at the edge region of one bilayer. The position of the top bilayer of the POPC multilayer can easily be inferred as it is outlined by a high local concentration of enzymes, and it is this area that is reduced over time due to enz3miatic activity. The experiments also show a non-uniform distribution of the labeled aPLAl along the layer edge. Importantly, areas with a faster retraction of... [Pg.504]


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The Edge

The Region

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