Current-transient

Fig. 5. Various current transients obtained by a time-of-fligbt method (a) nondispersive transport (b) dispersive transport and (c) analysis of disperse...

According to the Scher-MontroU model, the dispersive current transient (Fig. 5b) can be analyzed in a double-log plot of log(i) vs log(/). The slope should be —(1 — ct) for t < and —(1 + a) for t > with a sum of the two slopes equal to 2, as shown in Figure 5c. For many years the Scher-MontroU model has been the standard model to use in analyzing dispersive charge transport in polymers. 

A. (i) ob is the current transient during changeover from y to a in an open transient condition. 

Note Since the surge impedance of a circuit is normally very high, as noted in Section 17.8, it is the voltage transient that is the cause of concern in the above case than the current transient. 

A switched static device (particularly a thyristor) produces voltage and current transients similar to inductive or... 

Cuncnt imiisieiits A similar situation will arise wheti a switching ON operation of the rectifier unit occurs hen it is a thyristor rectifier. Under load conditions, the stored magnetic energy in the incoming supply system, which can be the feeding transformer and the line reactances similar to a fault condition discussed earlier, may cause a current transient which can be expressed by... 

The characteristic shown also suggests that the MPCBs can withstand current transients up to 100 times the rated current (or the current setting) and hence are capable of switching a capacitor and protecting them against overloads. 

This can be defined by the most severe external fault at which the schetne will remain inoperative. It should also remain inoperative in healthy conditions. That is it should be immune to the momentary voltage or current transients and normal harmonic contents in the circulating current. Series LC-filter circuits are generally provided with the relay coil to suppress the harmonics and to detect the fault current more precisely. 

Each of these two procedures can be varied by proceeding from a low to a high current density (or potential) or from a high to a low current density (or potential) the former is referred to as forward polarisation and the latter as reverse polarisation. Furthermore, there are a number of variations of the potentiostatic technique, and in the potentiokinetic method the pwtential of the electrode is made to vary continuously at a predetermined rate, the current being monitored on a recorder in the pulse method the electrode is given a pulse of potential and the current transient is determined by means of an oscilloscope. 

Solution The resulting current transients (sampled after 2 min) lead to the following standards additions plot ... 

The differential capacitance method cannot be used for reactive metals, such as transition metals in aqueous solutions, on which the formation of a surface oxide occurs over a wide potential re ion. An immersion method was thus developed by Jakuszewski et al. 3 With this technique the current transient during the first contact of a freshly prepared electrode surface with the electrolyte is measured for various immersion potentials. The electrode surface must be absolutely clean and discharged prior to immersion.182-18 A modification of this method has been described by Sokolowski et al. The values of obtained by this method have been found to be in reasonable agreement with those obtained by other methods, although for reactive metals this may not be a sufficient condition for reliability. 

As shown in Fig. 25, an example of the extrapolation of the current transient obtained from the potential sweep yields the critical potential after ascertaining that the data obtained are independent of the sweep rate. Figure 26 exhibits the results of the critical pitting potential measurement for the majority salt of NaCl and the minority ion of Ni2+when the concentration of NaCl is varied under the condition of constant Ni2+ionic concentration. From the plot in Fig. 26, it follows that... 

After a constant potential step beyond the pitting potential is applied to a nickel electrode in NaCl solution, the current transient shown in Fig. 39 is observed. The J vs. 1/VT plot according to Eq. (104) is shown in Fig. 40. From the linear portion corresponding to Eq. (104), the slope of the plot can be described as a function of the surface coverage 6 of the passive film in the following... 

By electrodeposition of CuInSe2 thin films on glassy carbon disk substrates in acidic (pH 2) baths of cupric ions and sodium citrate, under potentiostatic conditions [176], it was established that the formation of tetragonal chalcopyrite CIS is entirely prevalent in the deposition potential interval -0.7 to -0.9 V vs. SCE. Through analysis of potentiostatic current transients, it was concluded that electrocrystallization of the compound proceeds according to a 3D progressive nucleation-growth model with diffusion control. 

Figure 6.2 (a) Stripping chronoamperometry current transients for the oxidation of a saturated... 

Figure 6.11 Stripping chronoamperometric current transients on stepped Rh single-crystal surfaces, (a) Full transients obtained on the four different surfaces at F = 0.65 V (with respect to an RHE), in 0.5 M H2SO4. (b) Initial parts of the transients in (a).

Housmans and Koper [2003] have carried out a detailed analysis of the chronoam-perometric transients on a series of stepped single-crystal electrodes using reaction models very similar to those used in Franaszczuk et al. [1992] and Jarvi and Stuve [1998]. The expression that they used to model the current transient was... 

Without the direct pathway contribution, this equation may either yield an increasing or decreasing current transient, depending on the value of A ox/ dec- If this ratio is larger than 4, i.e., if methanol decomposition is slow compared with CO oxidation, then the current is predicted to increase with time. Experimentally, this simation has been observed for a low methanol concentration and an almost perfect Pt(l 11) electrode [Housmans and Koper, 2003], which both lead to a low methanol decomposition rate. Typically, however, current transients decrease with time, suggesting that the rate... 

Bergehn M, Herrero E, Fehu JM, Wasberg M, 1999. Oxidation of CO adlayers on Pt(111) at low potentials an impinging jet study in H2SO4 eIectrol3fte with mathematical modehng of the current transients. J Electroanal Chem 467 74-84. 

In this section, we will present and discuss cyclic voltammetry and potential-step DBMS data on the electro-oxidation ( stripping ) of pre-adsorbed residues formed upon adsorption of formic acid, formaldehyde, and methanol, and compare these data with the oxidative stripping of a CO adlayer formed upon exposure of a Pt/ Vulcan catalyst to a CO-containing (either CO- or CO/Ar-saturated) electrolyte as reference. We will identify adsorbed species from the ratio of the mass spectrometric and faradaic stripping charge, determine the adsorbate coverage relative to a saturated CO adlayer, and discuss mass spectrometric and faradaic current transients after adsorption at 0.16 V and a subsequent potential step to 0.6 V. 

In order to distinguish more clearly between effects induced by the varying potential and kinetic contributions, the continuous oxidation of the three Cj molecules was followed at a constant potential after the potential step. The corresponding faradaic and mass spectrometric (m/z = 44) current transients recorded after 3 minutes adsorption at 0.16 V and a subsequent potential step to 0.6 V (see Section 13.2) are reproduced in Figs. 13.5-13.7. In all cases, the faradaic current exhibits a small initial spike, which is associated with double-layer charging when stepping the electrode potential to 0.6 V. 

Figure 13.5 Potential-step electro-oxidation of formic acid on a Pt/Vulcan thin-film electrode (7 p,gptcm, geometric area 0.28 cm ) in 0.5 M H2SO4 solution containing 0.1 M HCOOH upon stepping the potential from 0.16 to 0.6 V (electrol)Te flow rate 5 p,L s at room temperature). (a) Solid line, faradaic current transients dashed line, partial current for HCOOH oxidation to CO2. (b) Solid line, m/z = 44 ion current transients gray line, potential-step oxidation of pre-adsorbed CO derived upon HCOOH adsorption at 0.16 V, in HCOOH-ftee H2SO4 solution.

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