SEARCH Articles Figures Tables ALDEHYDES AND KETONES NUCLEOPHILIC ADDITION TO THE CARBONYL GROUP Acid catalysts increase the reactivity of a carbonyl group Activating the carbonyl derivative Activation of the carbonyl Activation of the carbonyl group Activation of the carbonyl substrate Addition to the Carbonyl Bond Addition to the Carbonyl Group Affecting the Carbonyl Group Aldehyde An organic compound containing the carbonyl group bonded to at least one Aldehydes and Ketones The Carbonyl Group Alkane picosecond carbon-hydrogen bond cleavage at the iridium carbonyl center Alkylating the a-Carbon of Carbonyl Compounds Alkylation with Carbonyl Compounds The Prins Reaction Attack by Enolates on the Carbonyl Function Aldol Condensation Between the Same Metals in Carbonyls and Their Derivatives By Alan Cox 2 Reduction of the Carbonyl Group CAS REGISTRY NUMBERS AND SYNONYMS FOR THE CARBONYL HALIDES Calculation of the Conjugated Carbonyl Contents Carbonyl Chemistry 2 Reactions at the a Position Carbonyl Condensation Reactions in Synthesis The Robinson Annulation Reaction Carbonyl Condensations The Aldol Reaction Carbonyl Condensations with Enamines The Stork Reaction Carbonyl Groups Located on the Same Ring Carbonyl reduction by the Cannizzaro reaction Carboxylic Acids with a Carbonyl Group at the 3-Position Can Be Decarboxylated Characteristics of the Carbonyls Chemistry of the Metal Carbonyls Compounds containing the carbonyl group Conjugate Carbonyl Additions The Michael Reaction Deoxygenation of the Carbonyl Group Dihydro Derivatives Containing a Carbonyl Group in the Ring Dihydro Derivatives without a Carbonyl Group in the Ring ELECTRONIC STRUCTURE OF THE CARBONYL HALIDES Electron Affinities of Organic Carbonyl Compounds by the ECD Electronic effect on the destabilization of carbonyl and Electrophilicity of the carbonyl carbon atom Elongation through the Aldonolactone Carbonyl Group Enolisation, the first stage of carbonyl reactions Enolizable Carbonyl Compounds the Haloform Reaction Free Radical Methods for the Synthesis of Carbonyl Compounds From the reactions of carbonyl difluoride or formyl fluoride General Remarks on the Electronic Structure of Nickel Carbonyl Hydrogen Abstraction by Groups Other Than the Carbonyl Hydrogenation of the Carbonyl Group In the synthesis of, carbonyl difluoride Iridium Reactivity in the Methanol Carbonylation Reaction Isolated Double Bonds in the Presence of a Carbonyl Group Key Steps in the Mechanism of Carbonylation Processes LUMO of the carbonyl group Mechanistic Pathways in the Catalytic Carbonylation of Methanol by Rhodium and Mechanistic Pathways in the Catalytic Carbonylation of Methanol by Rhodium and Iridium Mechanistic Pathways in the Catalytic Carbonylation of Methanol by Rhodium and Iridium Complexes Methylation of carbonyl compounds by the Wittig Microwave-Promoted Carbonylations Using the Solvent as a Source of Carbon Monoxide Nature of the Ylide and Carbonyl Compound Nature of the carbonyl groups Nucleophilic addition to the carbonyl group Nucleophilic attack at the carbonyl group Nucleophilic substitution at the carbonyl group Other Developments Originating from the Study of Metal Carbonyls Other Reactions at the Carbonyl Carbon Atom Oxidation of Alcohols to Carbonyl Compounds with Activated Dimethyl Sulfoxide via Alkoxysulfonium Ylides. The Swern, Moffatt, and Related Oxidations Oxidation of the Carbonyl Functionality Photochemical reactions of the carbonyl group Photocycloadditions of the Carbonyl Group Polarization of the carbonyl double Poly in the synthesis of, carbonyl difluoride Preparation of the Metal Carbonyls Protection for the Carbonyl Group Reaction at the Carbonyl Group Reactions at the Carbonyl Carbon of Acid Derivatives Reactions at the Carbonyl Group—Adding or Removing One Carbon Atom Reactions at the Carbonyl Group—Oxidation and Reduction Reactions at the Metal Carbonyl Group Reactions at the a Carbon of Carbonyl Compounds Enols and Enolates Reactions of the Carbonyl Group Reactivity of the Carbonyl Group Reduction of the carbonyl group Reversal of the Carbonyl Group Polarity (Umpolung) Selectivity in the Reduction of Carbonyl Derivatives Containing a Chiral Carbon Some Acid-Base-catalyzed Reactions of the Carbonyl Group Structure and Bonding The Carbonyl Group Structure of the Carbonyl Group Substitution Products of the Group VIB Metal Carbonyls Substitution Reactions of Carbonyl Compounds at the a Carbon Substitution at the carbonyl group Substitutions at the Carbonyl Group Reactions of Carboxylic Acids and Derivatives Survey of the Cationic Metal Carbonyls and Their Properties by Groups THE PREPARATION OF CARBONYL DIBROMIDE The Alkyne Cobalt Carbonyl Complexes The Carbonyl Bond The Carbonyl Group The Carbonyl Ligand The Carbonyl ene Reaction The Carbonylation of Methanol Catalyzed by Rhodium Complexes in Solution The Carbonylative Heck Reaction The Exchange of Carbonyl Compounds with Water The Formation of Oxetanes from Carbonyls and Olefins The Intensities of Carbonyl Absorptions The Metal Carbonyls The Photochemistry of Carbonyl Compounds The Physical Properties of Carbonyl Compounds The Reactions of Carbonyl Compounds with Hydride Ion The Relative Reactivities of Carbonyl Compounds The Role of Proximal, Lewis Basic Functional Groups in Carbonyl Reduction The Stereochemistry of Carbonyl Reduction The Wittig and Related Carbonyl Olefination Reactions The carbonyl analogy The interaction of carbonyl-containing compounds with organometallic reagents The structures of carbonyls and related compounds Thermo- and Photochemical Reactions of Carbonyl Compounds in the Solid State Transformations of the Carbonyl Functions Transposition of the Carbonyl Group