Tensile properties composites

Baji, A., Mai, Y.W., Wong, S.C., Abtahi, M. and Chen, P. 2010. Electrospinning of polymer nanofibers Effects on oriented morphology, structures and tensile properties. Composites ScL Technol. 70 703-718. 

In the late 1980s, new fully aromatic polyester fibers were iatroduced for use ia composites and stmctural materials (18,19). In general, these materials are thermotropic Hquid crystal polymers that are melt-processible to give fibers with tensile properties and temperature resistance considerably higher than conventional polyester textile fibers. Vectran (Hoechst-Celanese and Kuraray) is a thermotropic Hquid crystal aromatic copolyester fiber composed of -hydroxyben2oic acid [99-96-7] and 6-hydroxy-2-naphthoic acid. Other fully aromatic polyester fiber composites have been iatroduced under various tradenames (19). 

Those stmctural variables most important to the tensile properties are polymer composition, density, and cell shape. Variation with use temperature has also been characterized (157). Flexural strength and modulus of rigid foams both increase with increasing density in the same manner as the compressive and tensile properties. More specific data on particular foams are available from manufacturers Hterature and in References 22,59,60,131 and 156. Shear strength and modulus of rigid foams depend on the polymer composition and state, density, and cell shape. The shear properties increase with increasing density and with decreasing temperature (157). 

Bisphenol A diglycidyl ether [1675-54-3] reacts readily with methacrylic acid [71-49-4] in the presence of benzyl dimethyl amine catalyst to produce bisphenol epoxy dimethacrylate resins known commercially as vinyl esters. The resins display beneficial tensile properties that provide enhanced stmctural performance, especially in filament-wound glass-reinforced composites. The resins can be modified extensively to alter properties by extending the diepoxide with bisphenol A, phenol novolak, or carboxyl-terrninated mbbers. 

Table 9. Tensile properties of PPS composites. All the fiber fractions are in weight percents. Data on Specimens a and b arc taken from. Modem Plastic Encyclopedia 96, Mid-Nov 1995 Issue.

Another example of favorable synergistic effects in ionomer/homopolymer blends is evident from a study of the tensile properties of blends of an SPS ionomer with PS. Over most of the composition range these two polymers are incompatible. For small additions of the SPS ionomer to PS, TEM studies of cast thin films show that... 

Table 2 Tensile Properties of Extruded Blends and Composites...

The tensile properties of the extruded blends and composites are presented in Table 2. Compared to the neat PP, a clear reinforcement was achieved after twin-screw blending. The reinforcing effect was even more pronounced with the higher take-up speed (H), evidently due to the extremely fibrillar morphology, as seen in Fig. 3. 

Supply is related to cost. If basic materials become scarce, changes will follow. Thus constraints in the petroleum supply may affect the polymer industry, which is based almost entirely on petrochemicals. We can look for expanded use of paper-based materials to provide factors such as bulk, tensile properties, and thermal resistance combined with the low weights of proper barrier materials. Composites will continue to grow in quantity and complexity. 

Finer dispersion of silica improves the mechanical and dynamic mechanical properties of the resultant composites. Figure 3.11a and b compares the tensile properties of the acrylic copolymer and terpolymers in the uncross-hnked and cross-linked states, respectively. 

Among the main molecular structural variables in EPDMs that are stipulated by catalyst systems and that affect the vulcanizate tensile properties we may mention molecular weight (MW) and MWD, degree of unsaturation (LG=C 1) and its distribution in the polymer, composition (C S) and monomer sequence length distribution along molecular chains, and long-chain branching if present. Effect of... 

Even though the first report about the synthesis of crystallizable ABC triblock copolymers was published in 1978 for PS-fo-PB-fo-PCL copolymers [114], in that work only a preliminary study of the tensile properties was performed, without considering the crystallizability of the materials. It was only 20 years later, when the preparation of these materials was reconsidered and optimized, that triblock copolymers with relatively narrow molecular weight distributions were obtained [115], a requisite which is indispensable for the generation of well-defined morphologies. To illustrate the complexity and richness of semicrystalline ABC triblock copolymers, PS-fc-PB-fc-PCL triblock copolymers have been chosen. These copolymers have been prepared with a wide composition range (with PCL contents from 11 to 77%) and they have been compared with PS-fc-PCL and PB-fo-PCL diblock copolymers [29,98, 115-118]. 

ISO 527-4, Plastics - Determination of tensile properties - Part 4 Test conditions for isotropic and orthotropic fibre-reinforced plastic composites, 1997. 

Fu SY, Lauke B, Mader E, Yue CY, Hu X. Tensile properties of short-glass-fiber- and short-carbon-fiber-reinforced polypropylene composites. Composites Part A Applied Science and Manufacturing. 2000 31(10) 1117-25. 

ISO 527-4 1997 Plastics - Determination of tensile properties - Part 4 Test conditions for isotropic and orthotropic fibre-reinforced plastic composites ISO 527-5 1997 Plastics - Determination of tensile properties - Part 5 Test conditions for unidirectional fibre-reinforced plastic composites ISO 1798 1997 Flexible cellular polymeric materials - Determination of tensile strength and elongation at break... 

ASTM D 3039 (1982). Test method for tensile properties of fiber-resin composites. 

Flexural strengths tend to be higher than tensile strengths in SMC composites. Elexural load-deflection modulus values are nonlinear, which indicates the occurrence of microcracking even at low loading. In general, flexural properties follow the same trends as the tensile properties and are affected by fiber content, fiber lengths, type, and orientation. 

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