Temporal separation

Ions in a TOF analyzer are temporally separated according to mass. Thus, at the detector all ions of any one mass arrive at one particular time, and all ions of other masses arrive at a different times. Apart from measuring times of arrival, the TDC device must be able to measure the numbers of ions at any one m/z value to obtain ion abundances. Generally, in TOF instruments, many pulses of ions are sent to the detector per second. It is not unusual to record 30,000 spectra per minute. Of course, each spectmm contains few ions, and a final mass spectrum requires addition of all 30,000 spectra to obtain a representative result. 

The pulsed ions start their journeys down the TOF flight tube all at the same time they separate in the TOF analyzer according to their velocities and arrive at the TOF ion collector at different times (temporally separated). 

After the analyzer of a mass spectrometer has dispersed a beam of ions in space or in time according to their various m/z values, they can be collected by a planar assembly of small electron multipliers. There are two types of multipoint planar collectors an array is used in the case of spatial separation, and a microchannel plate is used in the case of temporal separation. With both multipoint assemblies, all ions over a specified mass range are detected at the same time, or apparently at the same time, giving these assemblies distinct advantages over the single-point collector in the analysis of very small quantities of a substance or where ions are produced intermittently during short time intervals. 

The geophyte growth strategy is thus associated with temporal separation... 

Abstract. In eukaryotic cells, replicated DNA molecules remain physically connected from their synthesis in S phase until they are separated during anaphase. This phenomenon, called sister chromatid cohesion, is essential for the temporal separation of DNA replication and mitosis and for the equal separation of the duplicated genome. Recent work has identified a number of chromosomal proteins required for cohesion. In this review we discuss how these proteins may connect sister chromatids and how they are removed from chromosomes to allow sister chromatid separation at the onset of anaphase. 

By measurement the same element, which is temporally separated in different species (e.g. GC-AAS)... 

As stated earlier, the biodegradation of azo dyes requires an anaerobic and aerobic phase for the complete mineralization. The required condition can be implemented either by spatial separation of the two sludge using a sequential anaerobic-aerobic reactor system or in one reactor in the so-called integrated anaerobic-aerobic reactor system. In recent years, combined anaerobic-aerobic treatment technologies are extensively applied in the treatment of azo dye-containing wastewaters. Table 1 lists the systems based on combined anaerobic-aerobic treatment in separate reactors. Table 2 lists SBR based on temporal separation of the anaerobic and the aerobic phase. Table 3 lists the other systems, either hybrids with aerated zones or micro-aerobic systems based on the principle of limited oxygen diffuse in microbial biofilms [91]. 

In the early 1980s, one of the authors of this chapter began to study argon matrix isolation of radical cations235 by applying the radiolytic techniques elaborated by Hamill and Shida. A central factor was the addition of an electron scavenger to the matrix which was expected to increase the yield of radical cations and the selectivity of the method. For practical reasons, X-rays replaced y-rays as a radiolytic source and argon was chosen as a matrix material because of its substantial cross section for interaction with keV photons (which presumably effect resonant core ionization of Ar). Due to the temporal separation of the process of matrix isolation of the neutral molecules and their ionization, it was possible to obtain difference spectra which show exclusively the bands of the radical cations. 

The earliest control experiments were performed in double- (or multiple-) pump and probe scheme on optical phonons generated via ISRS in transparent materials by Nelson and coworkers [24,25], Shortly later, similar experiments were carried out on coherent phonons generated in semiconductors via TDFS by Dekorsy and coworkers [26], and on those generated in semimetals via DECP by Hase and coworkers [27] (Fig. 2.1 in the previous chapter). These experiments demonstrated that the amplitude of the coherent oscillation can be controlled by varying the temporal separation At between the two pump pulses. At = nT leads to the maximum enhancement of the amplitude with an integer n and the phonon period T, while At = (n + 1/2)T results in complete cancelation. 

G(t) decays with correlation time because the fluctuation is more and more uncorrelated as the temporal separation increases. The rate and shape of the temporal decay of G(t) depend on the transport and/or kinetic processes that are responsible for fluctuations in fluorescence intensity. Analysis of G(z) thus yields information on translational diffusion, flow, rotational mobility and chemical kinetics. When translational diffusion is the cause of the fluctuations, the phenomenon depends on the excitation volume, which in turn depends on the objective magnification. The larger the volume, the longer the diffusion time, i.e. the residence time of the fluorophore in the excitation volume. On the contrary, the fluctuations are not volume-dependent in the case of chemical processes or rotational diffusion (Figure 11.10). Chemical reactions can be studied only when the involved fluorescent species have different fluorescence quantum yields. 

In B.C. they are usually separated distributionally, but intermediate forms occur in intermediate localities. In Japan they may be temporally separated.The allocation of Gymnodinium breve to Ptychodiscus depends on the presence of a pellicle. Although not seen with TEM it can be seen with light microscopy. Geographic distribution is closely linked to taxonomy for, although some toxin producers appear to be endemic in a restricted sense, closely similar forms occur elsewhere (e.g.p, brevis) or the same species may be known by different names in different regions ( Gyrodinium aureolum ). 

Within this region both types occur more or less simultaneously, with mid-to late summer maxima. However, in Ofunato Bay, Japan, there is a temporal separation, with tamarensis blooming in summer and declining in July, catenella blooming from September to November (35). 

As can be seen from the experimentally measured Fourier spectra of the time-resolved vibrations (Figure 7.12), shaping of the excitation pnlse into a mnltipnlse sequence with a temporal separation b (Figure 7.10d) allows the selective preparation... 

Because electrons are much lighter than nuclei, they move much faster. The intrinsic temporal regime for valence bond electron dynamics is the few femtosecond to several hundred attosecond timescale. Therefore, efficient and accurate control of electron dynamics requires extreme precision regarding the control field. Commonly attosecond techniques are considered to be the appropriate tools for efficient manipulation of electron motions [61-63, 111, 112]. However, attosecond pulses in the XUV region are not suited for efficient valence bond excitation (see Section 6.1). Here we demonstrate that ultrafast electron dynamics are controlled efficiently on the sub-10 as timescale employing a pair of femtosecond laser pulses with a temporal separation controllable down to zeptosecond precision [8]. 

In CAM Plants, C02 Capture and Rubisco Action Are Temporally Separated... 

In general, the results of the calculations establish that it is possible to guide the reaction to preferentially form one or the other product with high yield. Note that, unlike the original Tannor-Rice pump-dump scheme, in which the pulse sequences that favor the different products have different temporal separations, the complex optimal pulses occupy about the same time window. Indeed, the optimal pulse shape that generates one product is very crudely like a two-pulse sequence, which suggests that the mechanism of the enhancement of product formation in this case is that the time delay between the pulses is such that the wavepacket on the excited-state... 

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