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Synergism processes

Direct conversion of methane to ethane and ethylene (C2 hydrocarbons) has a large implication towards the utilization of natural gas in the gas-based petrochemical and liquid fuels industries [ 1 ]. CO2 OCM process provides an alternative route to produce useful chemicals and materials where the process utilizes CO2 as the feedstock in an environmentally-benefiting chemical process. Carbon dioxide rather than oxygen seems to be an alternative oxidant as methyl radicals are induced in the presence of oxygen. Basicity, reducibility, and ability of catalyst to form oxygen vacancies are some of the physico-chemical criteria that are essential in designing a suitable catalyst for the CO2 OCM process [2]. The synergism between catalyst reducibility and basicity was reported to play an important role in the activation of the carbon dioxide and methane reaction [2]. [Pg.213]

This chapter discusses the apphcation of femtosecond lasers to the study of the dynamics of molecular motion, and attempts to portray how a synergic combination of theory and experiment enables the interaction of matter with extremely short bursts of light, and the ultrafast processes that subsequently occur, to be understood in terms of fundamental quantum theory. This is illustrated through consideration of a hierarchy of laser-induced events in molecules in the gas phase and in clusters. A speculative conclusion forecasts developments in new laser techniques, highlighting how the exploitation of ever shorter laser pulses would permit the study and possible manipulation of the nuclear and electronic dynamics in molecules. [Pg.1]

The extractant is a commercial mixture of mono- and dioctyl phenyl phosphoric acid (OPPA). It is used in conjuction with tributyl phosphate (TBP). Stripping is by ammonium carbonate solution. The mixture shows synergism. Uranium is extracted in the tetravalent state. The process is much less expensive and possesses a higher extracting power than D2EHPA-TOPO combination. [Pg.552]

The similarity between the mechanism of destruction and some of the common optimum operating conditions in the case of different advanced oxidation techniques point towards the synergism between these methods and fact that combination of these advanced oxidation processes should give better results as compared to individual techniques [70]. This indeed is applicable to hydrodynamic cavitation as well and there have been reports where hydrodynamic cavitation has been combined with other advanced oxidation processes with great success. [Pg.97]

FBAs applied in combination may show a synergistic effect. Synergism is, at present, only of commercial interest with polyester brighteners. This phenomenon is discussed further in section 11.10. Conversely, the presence of a trace impurity in an FBA formulation may greatly reduce its effectiveness. In industrial laboratories much time and effort is expended in developing processes to minimise the content of such impurities or even to eliminate them completely. [Pg.307]

Microwave heating has already been used in combination with some other (unconventional activation processes. Such a combination might have a synergic effect on reaction efficiencies or, at least, enhance them by combining their individual effects. Application of MW radiation to ultrasound-assisted chemical processes has been recently described by some authors [18, 19]. Mechanical activation has also been successfully combined with MW heating to increase chemical yields of several reactions [1]. [Pg.463]

D) Oxidative addition (insertion). In the limit of strong synergism, the H—H bond can be broken and two new M—H bonds formed. Although termed oxidative addition, this reaction does not necessarily deplete the metal of electron density (i.e., oxidize the metal). Rather, this reaction is fundamentally an insertion of the metal into the H—H bond. In the process, a lone pair of electrons at the metal and the electron pair of the H—H bond are uncoupled and then recoupled to form two M—H bonds. Whether synergistic H2 coordination or insertion prevails depends largely on the relative... [Pg.489]

Safety review An effective but less formal type of HAZOP study. The results are highly dependent on the experience and synergism of the group reviewing the process. [Pg.431]

Rotational suspension separation encapsulation process, 16 450 Rotational viscometers, 21 731-737 computers in, 21 732 operation of, 21 736 Rotations, of molecules cause of color, 7 326t, 328 Rotavirus vaccine, 25 496 Rotaxanes, 17 61, 24 31, 33, 51 as molecular computers, 24 60 Rotenone (Chem-Fish Synergized,... [Pg.811]

Synergism It may be defined as the process whereby two different reagents when employed together are capable of extracting a metal ion with a distinct and marked efficiency, in comparison to a condition when the same two reagents are used individually . [Pg.400]

The use of zwitterionic surfactants commercially has increased dramatically in recent years (U because of their unique properties, such as compatibility and synergism when used in conjunction with most other types of surfactants. This type of surfactant is used in textile processing aids, cosmetic products, cleaning agents, and as antistatic agents. The sulfobetaines have been found to be very good lime soap disperants ( ). [Pg.49]


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