Substrate, honeycomb

Cordierite [12182-53-5] Mg Al Si O g, is a ceramic made from talc (25%), kaolin (65%), and Al O (10%). It has the lowest thermal expansion coefficient of any commercial ceramic and thus tremendous thermal shock resistance. It has traditionally been used for kiln furniture and mote recently for automotive exhaust catalyst substrates. In the latter, the cordierite taw materials ate mixed as a wet paste, extmded into the honeycomb shape, then dried and fired. The finished part is coated with transition-metal catalysts in a separate process. 

Catalytic Support Body Monolithic Honeycomb Unit. The terms substrate and brick are also used to describe the high geometric surface area material upon which the active coating material is placed. Monolithic honeycomb catalytic support material comes in both ceramic and metallic form. Both are used in automobile catalysts and each possesses unique properties. A common property is a high geometric surface area which is inert and does not react with the catalytic layer. 

Cera.mic, The ceramic substrate is made from a mixture of siUcon dioxide, talc, and kaolin to make the compound cordierite [12182-53-5]. Cordierite possesses a very low coefficient of thermal expansion and is thermal-shock resistant. The manufacturing process involves extmding the starting mixture (which is mixed with water and kneaded into a sort of dough) through a complex die to form the honeycomb stmcture. The extmded piece is dried and fired in a kiln to form the cordierite. The outside or circumferential dimension is formed by the die, and the length is cut later with a ceramic saw. 

The process has been commercially implemented in Japan since 1977 [1] and a decade later in the U.S., Germany and Austria. The catalysts are based on a support material (titanium oxide in the anatase form), the active components (oxides of vanadium, tungsten and, in some cases, of molybdenum) and modifiers, dopants and additives to improve the performance, especially stability. The catalyst is then deposited over a structured support based on a ceramic or metallic honeycomb and plate-type structure on which a washcoat is then deposited. The honeycomb form usually is an extruded ceramic with the catalyst either incorporated throughout the stmcture (homogeneous) or coated on the substrate. In the plate geometry, the support material is generally coated with the catalyst. 

The heart of an adsorbent wheel system is a rotating cylinder containing the adsorbent. Figure 16-60 illustrates two types horizontal and vertical. In some adsorbent wheels, the adsorbent particles are placed in basket segments (a multitude of fixed beds) to form a horizontal wheel that rotates around a vertical axis. In other instances, the adsorbent is integral to the monolithic wheel or coated onto a metal, paper, or ceramic honeycomb substrate. These monolithic or... 

The nanoreplication of functional nanostructures has also been achieved through other block copolymer-templated structures. De Boer et al. [35] applied honeycomb-structured films of rod-coil block copolymer as patterned templates to replicate hexagonally packed arrays of aluminum cups on the substrate surfaces (Fig. 10b). Nguyen et al. [237] embedded semiconducting polymers in the channels of oriented hexagonal nanoporous silica and used this nanoscale architecture to control the energy transfer for potential optoelectronic applications. 

On the other hand, following the development of hybrid combustor configurations that prevent operation of the catalyst module at temperatures above 900-1000 °C, the major drawback of metallic monoliths, namely the limited maximum operating temperature, has been overcome. Accordingly, honeycombs made of metal foils have been adopted in GT catalytic combustors in view of their excellent thermal shock resistance and thermal conductivity properties [9]. In addition, metallic substrates are a promising option for the fabrication of microcombustors. 

Tronconi et al. [46] developed a fully transient two-phase 1D + 1D mathematical model of an SCR honeycomb monolith reactor, where the intrinsic kinetics determined over the powdered SCR catalyst were incorporated, and which also accounts for intra-porous diffusion within the catalyst substrate. Accordingly, the model is able to simulate both coated and bulk extruded catalysts. The model was validated successfully against laboratory data obtained over SCR monolith catalyst samples during transients associated with start-up (ammonia injection), shut-down (ammonia... 

Let us first explore the selected STM example concerning the molecular system cyclotrimeric terthiophenediacetylene shown in Fig. 4.11 (Mena-Osteritz Bauerle, 2001). The synthesis of this molecule was discussed in Section 2.5 (Fig. 2.17). When a solution of the cyclotrimeric terthiophenediacetylene macrocycle in C6H3CI3 is brought onto a freshly cleaved HOPG substrate, spontaneous formation of a SAM is found with honeycomb ordering at the solution/HOPG interface. 

A popular substrate for solid-liquid interface studies is hopg. Cleaving the crystal perpendicular to the c-axis leads to the well-defined honeycomb-structured basal plane (Fig. 3). 

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