Structured attribute

Feitknecht has examined the corrosion products of zinc in sodium chloride solutions in detail. The compound on the inactive areas was found to be mainly zinc oxide. When the concentration of sodium chloride was greater than 0-1 M, basic zinc chlorides were found on the corroded parts. At lower concentrations a loose powdery form of a crystalline zinc hydroxide appeared. A close examination of the corroded areas revealed craters which appeared to contain alternate layers and concentric rings of basic chlorides and hydroxides. Two basic zinc chlorides were identified, namely 6Zn(OH)2 -ZnClj and 4Zn(OH)2 ZnCl. These basic salts, and the crystalline zinc hydroxides, were found to have layer structures similar in general to the layer structure attributed to the basic zinc carbonate which forms dense adherent films and appears to play such an important role in the corrosion resistance of zinc against the atmosphere. The presence of different reaction products in the actual corroded areas leads to the view that, in addition to action between the major anodic and cathodic areas as a whole, there is also a local interaction between smaller anodic and cathodic elements. 

The diffuse nature of orexinergic projections is consistent with combined patterns of expression of the two orexin receptors, which is widespread but differential and often complementary within and even outside the CNS. OX2Rs are found primarily in structures attributed to control of sleq)-wake functions, whereas OXIRs are more abundant in limbic structures controlling aspects of feeding, autonomic outflow, energy homeostasis, and to a lesser extent also REM-sleq). 

Manley-Harris and Richards (Missoula, Montana) have compiled a comprehensive account of the dianhydrides of D-fructose and related compounds, more than 30 in all. These compounds, several of which are of importance in the sugar industry, have in the past presented significant problems in their chemical characterization. Their chemistry was surveyed as early as 1945 by McDonald in Volume 2 of this series, and discussed again in Volume 22 by Verstraeten. The current article furnishes detailed NMR data for each of the anhydrides, providing definitive reference data for accurate identification and correlation with earlier literature, where erroneous structural attributions are rather frequent. 

The experimental and predicted values of r] (centipoise) are shown in Figure 3.4. From this close correlation we infer that the structural attribute is influential on the viscosity. This relationship leads to the expectation that a second liquid could be defined in part by the fn attribute, at least as far as the... 

Enzyme reactions, like all chemical events, are dynamic. Information coming to us from experiments is not dynamic even though the intervals of time separating observations may be quite small. In addition, much information is denied to us because of technological limitations in the detection of chemical changes. Our models would be improved if we could observe and record all concentrations at very small intervals of time. One approach to this information lies in the creation of a model in which we know all of the concentrations at any time and know something of the structural attributes of each ingredient. A class of models based on computer simulations, such as molecular dynamics, Monte Carlo simulations, and cellular automata, offer such a possibility. 

Wu, B., Davey, G. E., Nazarov, A. A., Dyson, P. J. Davey, C. A. Specific DNA Structural Attributes Modulate Platinum Anticancer Drug Site Selection and Cross-Link Generation. Nucleic Acids Res. 39, 8200-8212 (2011). 

For developing new drugs => to discover molecules with structural attributes that enhance certain medical effects or reduce undesired side effects => e.g. Crixivan (an HIV protease inhibito, Chapter 2). 

The ultimate goal of structural genomics is to provide a complete three-dimensional description of any gene product. Also, as the structures of more and more proteins of known function are elucidated, it should become increasingly possible to link specific functional attributes to specific structural attributes. As such, it may prove ultimately feasible to predict protein function if its structure is known, and vice versa. 

Different types of industries require different characteristics to be taken into account, because in model-based planning the real decision situation must be represented adequately, as the solution will otherwise not provide any benefit. Along the lines of Meyr and Stadtler [3], the characteristics of different supply chains can be classified into functional attributes (procurement type, production type, distribution type, and sales type) and structural attributes (topography of a supply chain, integration, and coordination). 

Performance Indices Quality Factors Optimum E1LB Critical micelle concentration (CMC) Soil solubilization capacity Krafft point (ionic surfactants only) Cloud point (nonionic surfactants only) Viscosity Calcium binding capacity Surface tension reduction at CMC Dissolution time Material and/or structural attributes... 

Some quality factors, especially secondary ones, depend directly on material or structural attributes of the product. These product quality factors are often arbitrary and can only be qualitatively evaluated by panels of consumers or experts. Convenience for use, product stability, and ability for human skin protection are all examples of these quality factors. Each arbitrary performance index has specific relationships with the material/structural attributes. In such cases, the desirable quality factor can be realized by directly changing the formulation without concerning any of the performance indices. An example can be that to make a laundry detergent product more convenient to use, the product form can be changed from powder to tablet. Another example is that to make a highly biodegradable product, surfactants with less branching should be used. 

Table 3. Relationship between selected performance indices and material or structural attributes.

Performance index Related material or structural attributes Relationship... 

Product-centered Process Synthesis and Developoment Detergents Table 12. Examples of dependence of structural attributes on operating variables. 

II. Structural Attribute-Material Property-Product Attribute Relationships... 

Customer delight is a key requirement for consumer products. For example, the hand-feel of a fabric is an important measure of its quality. There exist many challenges to determine these quality factors in a more scientific way. However, even if only a semi-quantitative measurement can be devised, this can yield insights on how the underlying material or structural attributes control the quality factor. These insights can in turn be used to formulate innovative products. 

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