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Metal standards

BackTitrations. In the performance of aback titration, a known, but excess quantity of EDTA or other chelon is added, the pH is now properly adjusted, and the excess of the chelon is titrated with a suitable standard metal salt solution. Back titration procedures are especially useful when the metal ion to be determined cannot be kept in solution under the titration conditions or where the reaction of the metal ion with the chelon occurs too slowly to permit a direct titration, as in the titration of chromium(III) with EDTA. Back titration procedures sometimes permit a metal ion to be determined by the use of a metal indicator that is blocked by that ion in a direct titration. Eor example, nickel, cobalt, or aluminum form such stable complexes with Eriochrome Black T that the direct titration would fail. However, if an excess of EDTA is added before the indicator, no blocking occurs in the back titration with a magnesium or zinc salt solution. These metal ion titrants are chosen because they form EDTA complexes of relatively low stability, thereby avoiding the possible titration of EDTA bound by the sample metal ion. [Pg.1167]

Cold Forming. Some ABS grades have ductihty and toughness such that sheet can be cold formed from blanks 0.13—6.4 mm thick using standard metal-working techniques. Up to 45% diameter reduction is possible on the first draw subsequent redraws can yield 35%. Either aqueous or nonaqueous lubrication is required. More details are available in Reference 147. [Pg.207]

Annual Book of ASTM Standards Metals-Physical, Mechanical and Corrosion Testing... [Pg.31]

B. Back-titration. Many metals cannot, for various reasons, be titrated directly thus they may precipitate from the solution in the pH range necessary for the titration, or they may form inert complexes, or a suitable metal indicator is not available. In such cases an excess of standard EDTA solution is added, the resulting solution is buffered to the desired pH, and the excess of the EDTA is back-titrated with a standard metal ion solution a solution of zinc chloride or sulphate or of magnesium chloride or sulphate is often used for this purpose. The end point is detected with the aid of the metal indicator which responds to the zinc or magnesium ions introduced in the back-tit ration. [Pg.311]

Under similar reaction-conditions, the vanadium species V(N2)6 (139) has been isolated. In addition, a species V2(Na) (n probably = 12) was observed (139). The metal nuclearity was established by the standard, metal-concentration techniques. A comparison of the optical spectra of V(N2) and V(CO)e 128) suggested that these molecules have very similar, electronic properties, and the data clearly established that N2 is a strong, field ligand in its bonding properties. Interestingly, atomic V could be isolated in N2 matrices from 8- 12K co-... [Pg.141]

EPA. 1986b. Effluent guidelines and standards. Metal finishing point source category. U.S. Environmental Protection Agency. Code of Federal Regulations. 40 CFR 433. [Pg.286]

Effluent Guidelines and Standards Metal Finishing - Definition of Total Toxic Organics >0.01 mg/L 40 CFR 433.11 EPA 1983a... [Pg.153]

The extent of adsorption of reactive elements, e.g., metal ions, to particles can be readily determined by titrating a particle suspension or a sample of natural water containing particles with a metal ion (Fig. 11,3a) or to inverse the titration, i.e., to titrate a dilute standard metal solution with particles (Fig. 11.3b). [Pg.374]

Compounds containing sulfur and cyanide become a potential source of air pollution when treated with this system. A caustic scrubber may be required to capture the combustion products of these compounds if sulfur and cyanide levels are high enough to exceed health and safety or applicable air quality standards. Metals that are not particularly volatile are not likely to be treated effectively by the TDS. Plastic materials are not recommended for treatment since their decomposition products could cause plugging or foul surfaces. [Pg.771]

Among many fascinating properties, quasicrystals with high structural quality, such as the icosahedral AlCuFe and AlPdMn alloys, have unconventional conduction properties when compared with standard intermetallic alloys. Their conductivities can be as low as 450-200 (Qcm) [7]. Furthermore the conductivity increases with disorder and with temperature, a behaviour just at the opposite of that of standard metal. In a sense the most striking property is the so-called inverse Mathiessen rule [8] according to which the increases of conductivity due to different sources of disorder seems to be additive. This is just the opposite that happens with normal metals where the increases of resistivity due to several sources of scattering are additive. Finally the Drude peak which is a signature of a normal metal is also absent in the optical conductivity of these quasicrystals. [Pg.536]

One unit of a-D-mannosidase liberates 1 fig of p-nitrophenol from 6 mM p-nitrophenyl a-D-mannoside in 1 hr at 37° and pH 5. Protein was determined by the method of Lowry and coworkers,5 with bovine albumin as the standard. Metal analysis was performed by atomic absorption spectrophotometry. The enzyme preparation was purified to stage 5 of the original procedure (see Table V) and dialyzed at pH 8 to remove the excess of Zn2+ finally, gel chromatography was conducted at the same pH. [Pg.435]

The same method is given in BS 903 Part A3782 which also contains a national annex giving a second method for assessing the degree of corrosion when the rubber is not in contact with the metal. Zinc is used as the standard metal as this is fairly readily corroded. A strip of zinc and the rubber test piece are both suspended over distilled water in a stoppered container maintained at 50°C. After a period of three weeks, the corrosion products are removed from the zinc by immersion in chromium trioxide solution and the loss in weight used as the measure of degree of corrosion. This is a very sensitive method but even more care has to be taken than in the contact method to avoid contamination and to obtain reproducible results. [Pg.376]

A standard metal staircase and railing skirts the outer edge of the tank providing access to the tank roof. A manhole in the tank roof provides access for internal repairs. Discrete inlet and outlet lines are required to feed into the base of the tank. A pressure relief valve is... [Pg.217]

The very much lower density of polyurethanes (1.0 to 1.2g/cm3) compared to the lightest of standard metals, namely aluminum (-2.7 g/cm3), gives it great weight advantages. The difference is magnified even more when compared to steel. Parts can be made so much lighter that they can be handled with ease. [Pg.148]

From the fabrication of the capacitor we run into the problem of contacting the capacitor, which can mostly be done in two ways. The easiest way is to contact by standard metal needle probes on a probe station, however, this requires large contact areas larger than 3x3 nm2. But this also requires fully structured top and bottom electrodes as in Figure 17.6, or integrated devices, which are much more difficult to manufacture, especially for sub-micron capacitors. [Pg.332]

The separation of five metal dithizone complexes extracted from a standard metal solution, is illustrated in Fig. 4.13. [Pg.143]

Emphasis was first placed on the adsorptive behavior of Compound D on the surface of chromium because that metal has the following desirable properties (a) it is an excellent adsorbent for carboxylic acid groups (5) (b) a large body of data is available on the properties of adsorbed, monomolecular films of aliphatic (16), partially fluorinated (13), fully fluorinated (2), and chloro-fluoro carboxylic acids (2) (c) the metal surface can be readily and reproducibly cleaned by standard metal-lographic polishing techniques and (d) there is a hard, coherent, thin-film oxide on the surface (18). [Pg.34]


See other pages where Metal standards is mentioned: [Pg.330]    [Pg.222]    [Pg.361]    [Pg.459]    [Pg.1070]    [Pg.537]    [Pg.459]    [Pg.223]    [Pg.131]    [Pg.121]    [Pg.373]    [Pg.97]    [Pg.1316]    [Pg.38]    [Pg.374]    [Pg.413]    [Pg.257]    [Pg.112]    [Pg.997]    [Pg.29]    [Pg.330]    [Pg.307]    [Pg.809]    [Pg.287]    [Pg.392]    [Pg.2]    [Pg.394]    [Pg.2]    [Pg.4]    [Pg.43]    [Pg.118]   
See also in sourсe #XX -- [ Pg.69 ]




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