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Stability experimental methods

From the discussion presented of reactions in solids, it should be apparent that it is not practical in most cases to determine the concentration of some species during a kinetic study. In fact, it may be necessary to perform the analysis in a continuous way as the sample reacts with no separation necessary or even possible. Experimental methods that allow measurement of the progress of the reaction, especially as the temperature is increased, are particularly valuable. Two such techniques are thermo-gravimetric analysis (TGA) and differential scanning calorimetry (DSC). These techniques have become widely used to characterize solids, determine thermal stability, study phase changes, and so forth. Because they are so versatile in studies on solids, these techniques will be described briefly. [Pg.266]

In order to determine the stability constants for a series of complexes in solution, we must determine the concentrations of several species. Moreover, we must then solve a rather complex set of equations to evaluate the stability constants. There are several experimental techniques that are frequently employed for determining the concentrations of the complexes. For example, spectrophotometry, polarography, solubility measurements, or potentiometry may be used, but the choice of experimental method is based on the nature of the complexes being studied. Basically, however, we proceed as follows. A parameter is defined as the average number of bound ligands per metal ion, N, which is expressed as... [Pg.677]

Connors, K. A. (1987). Binding Constants The Measurement of Molecular Complex Stability. Wiley, New York. An excellent discussion of the theory of molecular association as well as the experimental methods and data treatment. Deals with the association of many types of species in addition to metal complexes. Highly recommended. [Pg.692]

Rossotti, F. J. C., and Rossotti, H. (1961). Determination of Stability Constants. McGraw-Hill, New York. Probably the most respected treatise on stability constants and experimental methods for their determination. [Pg.692]

A large number of techniques have been used to investigate the thermodynamic properties of solids, and in this section an overview is given that covers all the major experimental methods. Most of these techniques have been treated in specialized reviews and references to these are given. This section will focus on the main principles of the different techniques, the main precautions to be taken and the main sources of possible systematic errors. The experimental methods are rather well developed and the main problem is to apply the different techniques to systems with various chemical and physical properties. For example, the thermal stability of the material to be studied may restrict the experimental approach to be used. [Pg.308]

The initiation of the cationic polymerisation of alkenes is examined in detail by means of simple thermodynamic concepts. From a consideration of the kinetic requirements it is shown that the ideal initiator will yield a stable, singly charged anion and a cation with a high reactivity towards the monomer by simple, well defined reactions. It must also be adequately soluble in the solvent of choice and for the experimental method to be used. The calculations are applied to carbocation salts as initiators and a method of predicting their relative solubilities is described. From established and predicted data for a variety of carbocation salts the position of their ion molecule equilibria and their reactivity towards alkenes are examined by means of Born-Haber cycles. This treatment established the relative stabilities of a number of anions and the reason for dityl, but not trityl salts initiating the polymerisation of isobutene. [Pg.189]

This part includes a discussion of the main experimental methods that have been used to study the energetics of chemical reactions and the thermodynamic stability of compounds in the condensed phase (solid, liquid, and solution). The only exception is the reference to flame combustion calorimetry in section 7.3. Although this method was designed to measure the enthalpies of combustion of substances in the gaseous phase, it has very strong affinities with the other combustion calorimetric methods presented in the same chapter. [Pg.83]

Calculation, thermodynamic optimization of phase diagrams. The knowledge of phase equilibria, phase stability, phase transformations is an important reference point in the description and understanding of the fundamental properties of the alloys and of their possible technological applications. This interest has promoted a multi-disciplinary and multi-national effort dedicated not only to experimental methods, but also to techniques of optimization, calculation and prediction of... [Pg.68]

Carbon atoms in organic molecules are most often neutral. Positively charged carbocations have attracted the interest of synthetic organic chemists, because of their use as intermediates in reactions leading to formation of carbon-carbon bonds. Our work on carbocations has focused on defining the stability of these species as intermediates of solvolysis reactions, through the determination of rate and equilibrium constants for these stepwise reactions (Scheme 1). This has led to the development of experimental methods to characterize these parameters for carbocations that are sufficiently stable to form in aqueous solution. [Pg.310]

The preceding section summarized basicity results obtained from the stability constants of 7r-complexes and EDA-complexes. These results can only reflect a qualitative gradation of the basicity. If one moves from these complexes to u-complexes, then exact values for the basicity of unsaturated compounds can be obtained by measuring the formation equilibria of the proton addition complexes in strongly acid solutions. The experimental methods and the calculations have been described in Sections III, A-C. [Pg.271]

The free energy is calculated from the stability constant, which can be determined by a number of experimental methods that measure some quantity sensitive to a change in concentration of one of the reactants. Measurement of pH, spectroscopic absorption, redox potential, and distribution coefficient in a solvent extraction system are all common techniques. [Pg.110]

In addition to these limited procedures a number of experimental methods (vibrational spectroscopy, dipole moment measurements, electron diffraction, NMR, etc.) have been employed to determine the relative stabilities of these complexes.11,23 Intense effort has been directed towards establishing some kind of correlation between NMR parameters and stability of the borane complexes. The chemical shifts alone rarely show good correlation. However, complexation shifts (the chemical shift difference between the free and complexed borane or ligand) and various spin-spin coupling constants correlate better with calorimetric data, especially for ligands or boranes belonging to structurally similar series (Table 2).10,24... [Pg.83]

Related classes of gitonic superelectrophiles are the previously mentioned protoacetyl dications and activated acyl cationic electrophiles. The acyl cations themselves have been extensively studied by theoretical and experimental methods,22 as they are intermediates in many Friedel-Crafts reactions. Several types of acyl cations have been directly observed by spectroscopic methods and even were characterized by X-ray crystal structure analysis. Acyl cations are relative weak electrophiles as they are effectively stabilized by resonance. They are capable of reacting with aromatics such as benzene and activated arenes, but do not generally react with weaker nucleophiles such as deactivated arenes or saturated alkanes. [Pg.153]

We studied Cl-MIT inclusion complexes, with a view to evaluating their thermal stability and the degree to which they release Cl-MIT into water. As a result, it was clear that the inclusion complex (23) with 4,4 -ethylidenebisphenol (21) is the most efficient complex for commercial use. The experimental method is detailed below. [Pg.211]

A technology, which has allowed producing of fullerene molecular-colloidal water solutions (FWS), has made new step for the biological applications of fullerenes. Such technology is now available [4], and CeoFWS produced by means of it is highly stable (8-24 months and longer) and finely dispersed without any stabilizers. The fact that this colloid consists of individual molecules of Ceo and the water only has been proved earlier by means of different experimental methods. [Pg.152]

Formation of metal-organic compound co-condensates presents a peculiar problem, which is difficult to study. Most experimental methods are inapplicable to the study of the processes that take place at the instant of cocondensation. This brings to the fore theoretical approaches. The state of the art of computational quantum-chemical methods makes it possible to adequately describe the structure of organometallic compounds and estimate their stability and, sometimes, reactivity. [Pg.705]


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