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Spinning Drops

During start-up, the tensile stress difference in the test fluid will be a balance of inertial, interfacial, and drag forces [Pg.296]

Schematic of spinning drop apparatus. The shape change [Pg.297]


J. L. Cayais, R. S. Schecter, and W. H. Wade, The Measurement of Fow Intefacial Tension via the Spinning Drop Technique, Dept, of Chemistry and... [Pg.262]

The AOS and IOS surfactants discussed in this section are laboratory-prepared samples. The experiments were carried out by Borchardt [40] who used the spinning drop method throughout. Experimental details are given in the footnotes of the tables that follow. [Pg.384]

Tests were performed at 75°C using a University of Texas Model 500 spinning drop tensiometer. Active surfactant concentration in the aqueous phase prior to oil addition was 0.50% wt. The Kem River crude oil was from the Patricia Lease. The pH of the deionized water surfactant solutions was 8. The pH of the aqueous NaCl surfactant solutions was 9.5 unless otherwise noted. values represent the average deviation of two or three measurements at different times (0.75-1 h apart). D.I., deionized. [Pg.385]

Tests were performed at 75°C using a University of Texas Model 500 spinning drop tensiometer. Active surfactant concentration in the aqueous phase prior to addition of the oil phase was 0.5% wt. Interfacial tension values are the average of duplicate or triplicate determinations. [Pg.391]

The dynamic interfacial tension behavior of reacting acidic oil-alkaline solutions has been studied for both an artificially acidified synthetic oil and a real crude oil at various concentrations [131,132] with either a drop volume tensiometer or a spinning drop tensiometer. [Pg.224]

The spinning drop technique measures the shape of the oil drop in the flooding solution in a capillary tube. An automatic measuring system has been developed by combining a video-image analysis, an automatic recording system, and a computer for calculation of the interfacial tension [1865]. [Pg.224]

S. D. Ball. Comparison of transient interfacial tension behaviours of oiUalkaline systems as measured by the drop volume and spinning drop tensiometers. PhD thesis, Ottawa Univ, 1995. [Pg.354]

T. Yamazaki, K. Aso, H. Okabe, and Y. Akita. Automatic continuous-measuring system of interfacial tension by spinning drop technique. In Proceedings Volume. SPE Asia Pacific Conf (Yokohama, Japan, 4/25 /26), 2000. [Pg.478]

Oil/water interfacial tensions were measured for a number of heavy crude oils at temperatures up to 200°C using the spinning drop technique. The influences of spinning rate, surfactant type and concentration, NaCI and CaCI2 concentrations, and temperature were studied. The heavy oil type and pH (in the presence of surfactant) had little effect on interfacial tensions. Instead, interfacial tensions depended strongly on the surfactant type, temperature, and NaCI and CaCL concentrations. Low interfacial tensions (<0.1 mN/m) were difficult to achieve at elevated temperatures. [Pg.327]

Equipaent and Procedures. Crude o iI/aqueous i nterfac ia I tens i ons were measured using a spinning drop tensiometer built at the Alberta Research Council and designed for operation at elevated temperatures [211. The main difficulty in operating at elevated temperatures was the wear on the bearing improved operation was... [Pg.330]

It has been reported by Celik and Somasundaran T381 that the interaction of divalent (and trivalent) cations with sulfonate surfactants causes surfactant precipitation followed by dissolution of the precipitate at higher concentrations. The precipitate redissolution phenomenon is not observed with monovalent ions. Indeed, some surfactant precipitation in the spinning drop tube was observed above concentrations corresponding to the first minimum of Figure 8 it is not known whether redissolution took place at higher concentrations resulting in the second tension minimum. [Pg.340]

Modifications of the conventional spinning drop tensiometer were required for operating at temperatures up to 200°C. Measurements carried out with heavy oil samples required the use of D20 instead of H20 to maintain a sufficient density difference between oil and water. For accurate measurements, considerable care must be used to ensure that heavy oil drops do not lag behind the rotation of the capillary tube in the tensiometer. Also, repeatability of measurements conducted with chemically ill-defined substances may be hampered by the inhomogeneity of the oil drops. [Pg.343]

The interfacial shear viscosities are measured by the deep channel viscous traction surface viscometer (5) at the Illinois Institute of Technology. The oil-water equilibrium tensions are measured by either the spinning drop or the du Nouy ring (6) method. [Pg.367]

Interfacial Tension (IFT) Measurements. All IFT measurements were done using a University of Texas Model 300 Spinning Drop Interfacial Tensiometer. The basic principle is to introduce a drop (about 2 p ) of an oil sample into a glass capillary tube (1.5 mm I.D., 78 mm long) filled with the aqueous medium. The tube is then spun about its main axis. The oil drop will elongate to a length determined by the IFT value of the system. Details of the theory and application can be found elsewhere (15.16). According to the equipment manufacturer, the formula used to calculate IFT value is ... [Pg.380]

The values of Ys> Yw> Ysw were measured by spinning drop interfacial tensiometry (SDIT) as described in the Experimental Section. The values of Y Y s were obtained by the SDIT method using a polyethylene glycol (PEG), Jeffox PEG-300... [Pg.253]

Surface and interfacial tension measurements were made at 40° C with a Model 300 Spinning Drop Tensiometer obtained from the University of Texas at Austin, Chemistry Department. [Pg.265]

The pendant drop method was satisfactory for low Yqw values,. e. 0.02 mN/m. Typical data are given in Table III. In the systems where ultra-low yij values have been reported by other methods (like spinning drop), the pendant drop needs further investigations before it can be applied, since this would require syringes with much smaller diameters (J. e. 10 mm). As regards the theoretical analyses, we cannot find any concern why pendant drop should have any limitations for such studies. (Same is valid for spinning drop method). [Pg.338]

Provides measuring techniques of contact angle, surface tension, interfacial tension, and bubble pressure. Suitable methods for both static and dynamic inteifacial tension of liquids include du Nous ring, Wilhelmy plate, spinning drop, pendant drop, bubble pressure, and drop volume techniques. Methods for solids include sessile drop, dynamic Wilhelmy, single fiber, and powder contact angle techniques. [Pg.646]

Figure 13.15 Spinning drop method to measure the interfacial tension between two liquids. Figure 13.15 Spinning drop method to measure the interfacial tension between two liquids.
The Young-Laplace equation forms the basis for some important methods for measuring surface and interfacial tensions, such as the pendant and sessile drop methods, the spinning drop method, and the maximum bubble pressure method (see Section 3.2.3). Liquid flow in response to the pressure difference expressed by Eqs. (3.6) or (3.7) is known as Laplace flow, or capillary flow. [Pg.61]

For emulsions, the interfacial tension is usually of most interest. Here, the du Noiiy ring, Wilhelmy plate, drop volume, pendant, or sessile drop methods are the most commonly used. The spinning drop or captive drop techniques are applicable to the very low interfacial tensions encountered in the enhanced oil recovery and microemulsion fields. The maximum droplet pressure technique can be used when there is little or no density contrast between the phases, such as in bitumen-water systems at elevated temperature. [Pg.62]

Figure 3.12 Illustration of a spinning drop apparatus (the syringe is removed after placing the drop in the spinning tube). Figure 3.12 Illustration of a spinning drop apparatus (the syringe is removed after placing the drop in the spinning tube).
Cayias, J.L. Schechter, R.S. Wade, W.H. The Measurement of Low Interfacial Tension via the Spinning Drop Technique in Adsorption at Interfaces, Mittal, K.L. (Ed.), American Chemical Society Washington, 1975, pp. 234-247. [Pg.405]

What is the mechanism of spins dropping down from the state to the a state and fanning out around the two cones, and what determines the rates (R = HT and/ 2 = 1/72) of NMR relaxation These processes are intimately tied to the motion of molecules as they tumble ( reorient ) in solution in their rapid Brownian motion, and measurement of the NMR relaxation parameters T and T2 can even give us detailed information about molecular dynamics (motion) from the point of view of each spin in the molecule. A simplified model... [Pg.170]


See other pages where Spinning Drops is mentioned: [Pg.238]    [Pg.199]    [Pg.332]    [Pg.330]    [Pg.330]    [Pg.335]    [Pg.338]    [Pg.340]    [Pg.238]    [Pg.283]    [Pg.361]    [Pg.296]    [Pg.62]    [Pg.68]    [Pg.165]    [Pg.166]    [Pg.166]    [Pg.187]    [Pg.188]   
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See also in sourсe #XX -- [ Pg.70 ]

See also in sourсe #XX -- [ Pg.296 , Pg.297 ]




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