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Solvents hydrogen fluoride

During evaporation of solvent hydrogen fluoride, an exothermic reaction between residual ketone and bromine trifluoride set in and accelerated to explosion. [Pg.103]

In this solvent, hydrogen fluoride acts as a base, because it raises the concentration of the anion of the solvent. This is rather different to the reaction of HF in water, where is acts as an acid. [Pg.131]

Production of hydrogen fluoride from reaction of Cap2 with sulfuric acid is the largest user of fluorspar and accounts for approximately 60—65% of total U.S. consumption. The principal uses of hydrogen fluoride are ia the manufacture of aluminum fluoride and synthetic cryoHte for the Hall aluminum process and fluoropolymers and chlorofluorocarbons that are used as refrigerants, solvents, aerosols (qv), and ia plastics. Because of the concern that chlorofluorocarbons cause upper atmosphere ozone depletion, these compounds are being replaced by hydrochlorofluorocarbons and hydrofluorocarbons. [Pg.137]

Anhydrous hydrogen fluoride is an excellent solvent for ionic fluorides (Table 3). The soluble fluorides act as simple bases, becoming fully ionized and increasing the concentration of HF 2- Foi example,... [Pg.194]

Direct Fluorination. This is a more recently developed method for the synthesis of perfluorinated compounds. In this process, fluorine gas is passed through a solution or suspension of the reactant in a nonreactive solvent such as trichlorotrifluoroethane (CFC-113). Sodium fluoride may also be present in the reaction medium to remove the coproduct hydrogen fluoride. There has been enormous interest in this area since the early 1980s resulting in numerous journal pubHcations and patents (7—9) (see Fluorine compounds, organic-direct fluorination). Direct fluorination is especially useful for the preparation of perfluoroethers. [Pg.298]

Bromo or chloro-2,6-difluoropyridines can be prepared in 50% yield by diasotization of the corresponding 3-halo-2,6-diarninopyridine in ammonium fluoride—hydrogen fluoride solvent (371). 5-Chloro-2,3-difluoropyridine [89402-43-7], a precursor to the herbicide pyroxofop [105512-06-9], was synthesized by a multistep sequence based on aHyl chlorodifluoroacetate [118337-48-7], C1CF2C02-CH2CH=CH2 (415). [Pg.336]

Olefins are carbonylated in concentrated sulfuric acid at moderate temperatures (0—40°C) and low pressures with formic acid, which serves as the source of carbon monoxide (Koch-Haaf reaction) (187). Liquid hydrogen fluoride, preferably in the presence of boron trifluoride, is an equally good catalyst and solvent system (see Carboxylic acids). [Pg.563]

Isopropylnaphthalenes can be prepared readily by the catalytic alkylation of naphthalene with propjiene. 2-lsopropylnaphthalene [2027-17-0] is an important intermediate used in the manufacture of 2-naphthol (see Naphthalenederivatives). The alkylation of naphthalene with propjiene, preferably in an inert solvent at 40—100°C with an aluminum chloride, hydrogen fluoride, or boron trifluoride—phosphoric acid catalyst, gives 90—95% wt % 2-isopropylnaphthalene however, a considerable amount of polyalkylate also is produced. Preferably, the propylation of naphthalene is carried out in the vapor phase in a continuous manner, over a phosphoric acid on kieselguhr catalyst under pressure at ca 220—250°C. The alkylate, which is low in di- and polyisopropylnaphthalenes, then is isomerized by recycling over the same catalyst at 240°C or by using aluminum chloride catalyst at 80°C. After distillation, a product containing >90 wt % 2-isopropylnaphthalene is obtained (47). [Pg.487]

Acid-cataly2ed hydroxylation of naphthalene with 90% hydrogen peroxide gives either 1-naphthol or 2-naphthiol at a 98% yield, depending on the acidity of the system and the solvent used. In anhydrous hydrogen fluoride or 70% HF—30% pyridine solution at — 10 to + 20°C, 1-naphthol is the product formed in > 98% selectivity. In contrast, 2-naphthol is obtained in hydroxylation in super acid (HF—BF, HF—SbF, HF—TaF, FSO H—SbF ) solution at — 60 to — 78°C in > 98% selectivity (57). Of the three commercial methods of manufacture, the pressure hydrolysis of 1-naphthaleneamine with aqueous sulfuric acid at 180°C has been abandoned, at least in the United States. The caustic fusion of sodium 1-naphthalenesulfonate with 50 wt % aqueous sodium hydroxide at ca 290°C followed by the neutralization gives 1-naphthalenol in a ca 90% yield. [Pg.497]

A substantial portion of fhe gas and vapors emitted to the atmosphere in appreciable quantity from anthropogenic sources tends to be relatively simple in chemical structure carbon dioxide, carbon monoxide, sulfur dioxide, and nitric oxide from combustion processes hydrogen sulfide, ammonia, hydrogen chloride, and hydrogen fluoride from industrial processes. The solvents and gasoline fractions that evaporate are alkanes, alkenes, and aromatics with relatively simple structures. In addition, more complex... [Pg.44]

Alkyl fluorides have been prepared by reaction between elementary fluorine and the paraffins, by the addition of hydrogen fluoride to olefins, by the reaction of alkyl halides with mercurous fluoride, with mercuric fluoride, with silver fluoride, or with potassium fluoride under pressure. The procedure used is based on that of Hoffmann involving interaction at atmospheric pressure of anhydrous potassium fluoride with an alkyl halide in the presence of ethylene glycol as a solvent for the inorganic fluoride a small amount of olefin accompanies the alkyl fluoride produced and is readily removed by treatment with bromine-potassium bromide solution. Methods for the preparation of alkyl monofluorides have been reviewed. ... [Pg.43]

Toxic Reactions of the Skin Irritation is the most common reaction of the skin. Skin irritation is usually a local inflammatory reaction. The most common skin irritants are solvents dehydrating, oxidizing, or reducing compounds and cosmetic compounds. Acids and alkalies are common irritants. Irritation reactions can be divided into acute irritation and corrosion. Necrosis of the surface of the skin is typical for corrosion. Acids and alkalies also cause chemical burns. Phenols, organotin compounds, hydrogen fluoride, and yellow phosphorus may cause serious burns. Phenol also causes local anesthesia, in fact it has been used as a local anesthetic in minor ear operations such as puncture of the tympanous membrane in cases of otitis. ... [Pg.307]

Anhydrous hydrogen fluoride adds across carbon-carbon double and triple bonds and to other unsaturated systems, but wide variations of solvent, catalyst, temperature, and conditions are required with different substrates. [Pg.54]

Diazoketones [57] and esters [5S] react with hydrogen fluoride in organic solvents to give a-fluoroketones or esters, pyndinium poly(hydrogen fluoride) offers a convenient medium for the reaction (equation 13) [9]... [Pg.60]

Selective fluonnation in polar solvents has proved commercially successful in the synthesis of 5 fluorouracil and its pyrimidine relatives, an extensive subject that will be discussed in another section Selective fluonnation of enolates [47], enols [48], and silyl enol ethers [49] resulted in preparation of a/phn-fluoro ketones, fieto-diketones, heta-ketoesters, and aldehydes The reactions of fluorine with these functionalities is most probably an addition to the ene followed by elimination of fluonde ion or hydrogen fluoride rather than a simple substitution In a similar vein, selective fluonnation of pyridmes to give 2-fluoropyridines was shown to proceed through pyridine difluondes [50]... [Pg.109]


See other pages where Solvents hydrogen fluoride is mentioned: [Pg.81]    [Pg.207]    [Pg.207]    [Pg.174]    [Pg.207]    [Pg.156]    [Pg.81]    [Pg.207]    [Pg.207]    [Pg.174]    [Pg.207]    [Pg.156]    [Pg.305]    [Pg.179]    [Pg.182]    [Pg.210]    [Pg.329]    [Pg.137]    [Pg.195]    [Pg.236]    [Pg.277]    [Pg.293]    [Pg.320]    [Pg.326]    [Pg.335]    [Pg.336]    [Pg.336]    [Pg.340]    [Pg.496]    [Pg.431]    [Pg.432]    [Pg.478]    [Pg.425]    [Pg.435]    [Pg.448]    [Pg.454]    [Pg.61]    [Pg.103]   
See also in sourсe #XX -- [ Pg.258 ]




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