Solitary

By this process, 4-methylselenazole (2 R = CH3, R = R" = H) could be obtained by the reaction of hydrocyanic acid and hydrogen selenide with chloroacetone. This is the solitary selenazole unsubstituted in the 2-position that is known. The yield, however, was only 2.5% calculated on the chloroacetone used. 

This is followed by hydrolysi.s of the ester moieties with potassium carbonate and reesterification of the carboxy moiety with diazomethane to produce intermediate 65. The solitary free alcoholic hydroxyl at C-9 is oxidized with Collins reagent and the silyl ether groups are removed with acetic acid to give enprostil (63) [15]. 

Sdfabac, var- trifolLilum, known in India as kadda mulla, differs from the ocher varieties in bav ing solitary flowers, the calyx of wbieb is divided mio a large number of segmeuts, and tbe leaves I P. and fi.O.ft. (J916I, 36. 

A third reason is that Gibbs made no effort to promote or popularize his results. He seems to have been a solitary, self-contained, and self-sufficient thinker, confident in his ability, who worked at his own unhurried pace, neither needing nor wanting feedback from others. An attitude of detachment from the work of his students plus his own solitary habit of work is undoubtedly responsible for the fact that Gibbs founded no school or group of students to develop his ideas and exploit his discoveries. 

Solitons A mathematically appealing model of real particles is that of solitons. It is known that in a dispersive linear medium, a general wave form changes its shape as it moves. In a nonlinear system, however, shape-preserving solitary solutions exist. 

Vants represent the one of the simplest - and therefore, most persuasive - examples of emergence of high-level structures from low-level dynamics. Discovered by Langton [lang86], vants live on a two-dimensional Euclidean lattice and come in two flavors, red and bine. Each vant c an move in any of four directions (E,W,N,S). Each lattice site is either empty or contains one of two types of food, green food or yellow food. Vants arc fundamentally solitary creatures so that there is a strict conservation of the number of vants. 

H- and 3//-Azepines are generally unstable in aqueous acid solution and the few examples of simple azepinium salts, namely perchlorates,77 bromides,105 picrates35201 and a solitary iodide,105 have been prepared under nonaqueous conditions. The fractional crystallization of oxalate salts has been used for the separation of mixtures of 4- and 6-substituted 3f/-azepines,66 and 3,6-di-tm-butyl- and 2,5-di-tert-butyl-3//-azepine, on treatment with tetrafluoroboric acid in acetonitrile, are converted quantitatively into their crystalline tetrafluoroboratc salts.70... 

Anthozoa. Anthozoans are plant-shaped polyps, either solitary or colonial, completely lacking the medusoid stage. They are found along coastal waters and include the luminescent genera Renilla (the sea pansies), Cavernularia (the sea cactuses), and Ptilosarcus and Pennatula (the sea pens). Bioluminescent anthozoans emit light by a luciferin-luciferase reaction that involves coelenterazine as the... 

Thyroid autonomy appears as a solitary toxic nodule or toxic multinodular goitre. In toxic thyroid, the nodule s synthesis and secretion of thyroid hormones is autonomous from the thyroid-stimulating hormone (TSH), which is produced in the pituitary gland. Accordingly TSH is suppressed and the extranodular thyroid tissue is functionally downregulated. Thyroid autonomy occurs frequently in iodine-deficient countries, whereas it is much less common in iodine-sufficient areas. Constitu-tively activating mutations in the TSH receptor and in the Gs a protein are the major molecular aetiology of toxic thyroid nodules. 

But if pi is the pressure which would be exerted by the i-th gas in solitary confinement in the volume Y, we have ... 

The density p of the mixture is obviously equal to and the density pt of the i-th constituent when in solitary confinement in the same volume is hence, from (9) and (11) ... 

Solitary or multiple violaceous or brown flat-topped papules resembling lesions of lichen planus. 

Mastocytomas and diffuse cutaneous mastocytosis are further manifestations of cutaneous mastocytosis (CM) [9]. Solitary mastocytomas are common in children. Most are present at birth or develop in infancy. These lesions are flat or mildly elevated, well demarcated, solitary yellowish red-brown plaques or nodules, typically 2-5 cm in diameter. Diffuse cutaneous mastocytosis is a rare disorder characterized by diffuse mast cell infiltration of large areas of the skin that presents in infants in the first year of life. Severe edema and leathery indurations of the skin leads to accentuation of skin folds (pseudo-lichenified skin) and a peau-dbrange-like appearance. Systemic complications include hypotension and gastrointestinal hemorrhage. Infants and young children with considerable mast cell infiltration of the skin sometimes exhibit blister formation in the first 3 years of life. MPCM and other forms of CM have been classified in a consensus nomenclature (table 1) [10]. 

There are solitary examples of other alditol phosphates as components of this class of polymers. Arabinitol 1-phosphate is part of the S. pneumoniae type 17F capsular polysaccharide. o-Glucitol 6-phosphate is a component of the group-specific polysaccharide from group B Streptococcus, which has a most unusual, ramified structure. In a polysaccharide from Nocardia... 

A seizure is accompanied by a burst of spikes in the EEG. Between these so-called iclal phases are solitary EEG interictal spikes. Each of them represents the field potential associated with a burst of action potentials in a group of neurons within the epileptic focus (Fig. 16.2). 

The large numbers of opioid receptors in areas of the brainstem such as the solitary tract and adjacent areas are probably related to respiratory effects of opiates, cough suppression and nausea and vomiting. Opiates acting in the brainstem reduce the sensitivity of the respiratory centres to pC02 and this is the most common cause of death from overdose with street use of opiates. 

S5mthetic resin-embedded alfalfa samples were oven dried at 65 °C for 24 h and cut at 40-90 nm. The slides were analyzed using a JEOL 2010-F TEM prepared with field emission gun, EDS, and a high angle annular dark field detector for the analysis of solitary nanoparticles. 

It should be mentioned here that Sn sites are not considered to be the solitary source for OHad, which could be adsorbed on Pt sites owing to the influence of adjunct Sn atoms [Stamenkovic et al., 2005], The promotional effect of Sn was later confirmed on a PtSn/C nanocatalyst [Arenz et al., 2005], which exhibits similar behavior that was assigned primarily to the formation of reactive OH species at much lower potential than on pure Pt catalysts. Based on these findings, the bifunctional effect was unambiguously confirmed for Pt-Sn surfaces, where Sn sites serve as a source of oxygenated species that boost CO oxidation at low potentials and allow these surfaces to be employed as CO-tolerant catalysts. 

Primary syphilis Usually manifests as a solitary, painless chancre. Primary syphilis develops at the site of infection... 

CXR reveals a solitary nodule in right lower lobe. 

Surgery plays a key role in the management of patients with brain metastases, particularly patients whose systemic disease is well controlled and in those with solitary lesions. Surgery also may benefit patients with multiple metastatic sites who have a single dominant lesion with current or impending neurologic sequelae. 

Elder stems with their pith removed make a nesting site for solitary bees. This is helpful near fields of alfalfa, where the presence of bees aids plant pollination. Elder s summer flowers provide an important source of nectar for many insects. Swallow-tailed... 

Bacon, Francis. Francis Bacon - The Making of Gold. Experiment Solitary, touching the Making of Gold. rhttp //www. levitv.com/alchemv/bacongld.htmll. 

Figure 7.4 Summary of some of the wide array of afferent and efferent connections of midbrain dopaminergic neurons (SN/A9, RRF/A8, and VTA/A10 in center of figure). This emphasizes their potential involvement in coordination of seemingly disparate behaviors inclusive of the sleep-wake state of the organism. Abbreviations BP, blood pressure BST, bed nucleus of the stria terminalis CEA, central nucleus of the amygdala MEA, midbrain extrapyramidal area NTS, nucleus of the solitary tract O2, oxygen tension PPN, pedunculopontine tegmental nucleus RRF, retrorubral field SN, substantia nigra VTA, ventral tegmental area.

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