Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Shells decaying

A popular electron-based teclmique is Auger electron spectroscopy (AES), which is described in section Bl.25.2.2. In AES, a 3-5 keV electron beam is used to knock out iimer-shell, or core, electrons from atoms in the near-surface region of the material. Core holes are unstable, and are soon filled by either fluorescence or Auger decay. In the Auger... [Pg.307]

Comphcated theoretical calculations, based on filled shell (magic number) and other nuclear stabiUty considerations, have led to extrapolations to the far transuranium region (2,26,27). These suggest the existence of closed nucleon shells at Z = 114 (proton number) and N = 184 (neutron number) that exhibit great resistance to decay by spontaneous fission, the main cause of instabiUty for the heaviest elements. Eadier considerations had suggested a closed shell at Z = 126, by analogy to the known shell at = 126, but this is not now considered to be important. [Pg.226]

The effects of a rather distinct deformed shell at = 152 were clearly seen as early as 1954 in the alpha-decay energies of isotopes of californium, einsteinium, and fermium. In fact, a number of authors have suggested that the entire transuranium region is stabilized by shell effects with an influence that increases markedly with atomic number. Thus the effects of shell substmcture lead to an increase in spontaneous fission half-Hves of up to about 15 orders of magnitude for the heavy transuranium elements, the heaviest of which would otherwise have half-Hves of the order of those for a compound nucleus (lO " s or less) and not of milliseconds or longer, as found experimentally. This gives hope for the synthesis and identification of several elements beyond the present heaviest (element 109) and suggest that the peninsula of nuclei with measurable half-Hves may extend up to the island of stabiHty at Z = 114 andA = 184. [Pg.227]

There are two processes where nuclear and atomic contributions are iaterrelated. These are the emission of electrons from the atomic shells as an alternative to the emission of a photon and the emission of bremsstrahlung photons ia the P decay process. [Pg.453]

Pressure-tubes allow the separate, low-pressure, heavy-water moderator to act as a backup hesit sink even if there is no water in the fuel channels. Should this fail, the calandria shell ilsdf can contain the debris, with the decay heat being transferred to the water-filled shield tank around the core. Should the severe core damage sequence progress further, the shield tank and the concrete reactor vault significantly delay the challenge to containment. Furthermore, should core melt lead to containment overpressure, the concrete containment wall will leak and reduce the possibility of catastrophic structural failure (Snell, 1990). [Pg.405]

X. Pitting under decaying barnacles, shell fish br other deposits. ... [Pg.698]

Symmetry breaking associated with chiral phenomena is a theme that recurs across the sciences—from the intricacies of the electroweak interaction and nuclear decay [1-3] to the environmentally influenced dimorphic chiral structures of microscopic planktonic foraminifera [4, 5], and the genetically controlled preferential coiling direction seen in the shells of snail populations [6, 7]. [Pg.268]

For nuclear y-resonance absorption to occur, the y-radiation must be emitted by source nuclei of the same isotope as those to be explored in the absorber. This is usually a stable isotope. To obtain such nuclei in the desired excited meta-stable state for y-emission in the source, a long-living radioactive parent isotope is used, the decay of which passes through the Mossbauer level. Figure 3.6a shows such a transition cascade for Co, the y-source for Fe spectroscopy. The isotope has a half-life time //2 of 270 days and decays by K-capmre, yielding Fe in the 136 keV excited state ( Co nuclei capmre an electron from the K-shell which reduces the... [Pg.34]

So far, we have discussed only the detection of y-rays transmitted through the Mossbauer absorber. However, the Mossbauer effect can also be established by recording scattered radiation that is emitted by the absorber nuclei upon de-excitation after resonant y-absorption. The decay of the excited nuclear state proceeds for Fe predominantly by internal conversion and emission of a conversion electron from the K-shell ( 90%). This event is followed by the emission of an additional (mostly Ka) X-ray or an Auger electron when the vacancy in the K shell is filled again. Alternatively, the direct transition of the resonantly excited nucleus causes re-emission of a y-photon (14.4 keV). [Pg.39]

Capture, Electron—A mode of radioactive decay involving the capture of an orbital electron by its nucleus. Capture from a particular electron shell, e.g., K or L shells, is designated as "K-electron capture" or "L-electron capture."... [Pg.271]

Once uranium is incorporated into buried bone, shell, coral, or speleothems, the isotope uranium-235 decays, initially into the short-lived isotope (thorium-231) and then into long-lived protoactinium-231. Uranium-238, on the other hand, decays first into two successive short-lived isotopes (thorium-234 and protoactinium-234) and only then into a long-lived isotope, uranium-234 (see Fig. 12). The decay of uranium-235 to long-lived protoactinium-231 is used to date events up to 150,000 years in age that of uranium-234 (derived from uranium-238) to thorium-230 is of use for dating events within the time range 1000-500,000 years. [Pg.84]

It has been calculated that the decay rate of "Tc inside a star is dramatically enhanced because of /1-decay channels (Fig. 7) from thermally populated photo-excited states at high temperature [38]. The calculation was based on a simple shell model, taking into account both continum and bound state /1-decays. The... [Pg.13]

Fig. 7. Thermally populated / -decay channels from "Tc to "Ru [38], Relevant proton(n) and neutron(v) shells are shown as compartments filled with nucleons (x)... Fig. 7. Thermally populated / -decay channels from "Tc to "Ru [38], Relevant proton(n) and neutron(v) shells are shown as compartments filled with nucleons (x)...
Shell Chemical Company), exhibits a maximum at 300 nm, corresponding to that of the model chromophore anisole. The fluorescence intensity decreases monotonically with increasing concentration of 2,4-dihydroxybenzophenone (DHB) and, furthermore, decreases with time on continued excitation (274 nm) in the spectrophotometer. The fluorescence loss with time may be resolved into two exponential decays. Initially, a relatively rapid fluorescence loss is observed within 20 sec, followed by a slower loss. Loss constants for the initial (k ) and secondary (kj) exponential decays for 1.5 ym films (on glass slides) containing varying concentrations of DHB are provided in Table I (entries 1-3). The initial loss constants are seen to decrease more markedly with increasing DHB concentration than the secondary constants. [Pg.110]

What was the importance of this research result for the chirality problem One difficulty is provided by the fact that the interaction responsible for the violation of parity is in fact not so weak at all, although it only acts across a very short distance (smaller than an atomic radius). Thus, the weak interaction is not noticeable outside the atomic nucleus, except for p-decay. It would thus have either no influence on chemical reactions or only a very limited effect on chemical reactions, as these almost completely involve only interactions between the electron shells. [Pg.249]

Burns and Curtiss (1972) and Burns et al. (1984) have used the Facsimile program developed at AERE, Harwell to obtain a numerical solution of simultaneous partial differential equations of diffusion kinetics (see Eq. 7.1). In this procedure, the changes in the number of reactant species in concentric shells (spherical or cylindrical) by diffusion and reaction are calculated by a march of steps method. A very similar procedure has been adopted by Pimblott and La Verne (1990 La Verne and Pimblott, 1991). Later, Pimblott et al. (1996) analyzed carefully the relationship between the electron scavenging yield and the time dependence of eh yield through the Laplace transform, an idea first suggested by Balkas et al. (1970). These authors corrected for the artifactual effects of the experiments on eh decay and took into account the more recent data of Chernovitz and Jonah (1988). Their analysis raises the yield of eh at 100 ps to 4.8, in conformity with the value of Sumiyoshi et al. (1985). They also conclude that the time dependence of the eh yield and the yield of electron scavenging conform to each other through Laplace transform, but that neither is predicted correctly by the diffusion-kinetic model of water radiolysis. [Pg.219]


See other pages where Shells decaying is mentioned: [Pg.36]    [Pg.36]    [Pg.874]    [Pg.242]    [Pg.455]    [Pg.481]    [Pg.333]    [Pg.458]    [Pg.137]    [Pg.144]    [Pg.153]    [Pg.312]    [Pg.314]    [Pg.474]    [Pg.1036]    [Pg.1032]    [Pg.91]    [Pg.99]    [Pg.249]    [Pg.175]    [Pg.261]    [Pg.102]    [Pg.166]    [Pg.8]    [Pg.307]    [Pg.126]    [Pg.185]    [Pg.82]    [Pg.165]    [Pg.410]    [Pg.166]    [Pg.105]    [Pg.255]    [Pg.382]    [Pg.320]    [Pg.111]   
See also in sourсe #XX -- [ Pg.140 ]




SEARCH



© 2024 chempedia.info