Shear properties, plastics

In addition to the ISO 175 [39] standard for chemical degradation assessment for all plastics, the aerospace standard. EN 6063 [40] uses microscopic assessment of microcracks following immersion in the test environment. A particular test. EN 6030 [41], used in this industry is for the assessment of the effect of chemical paint stripper using the 45 tensile test for shear properties. 

Torsional test n. A test for determining shear properties of plastics, such as shear modulus, based on measuring the torques required to twist a specimen through a prescribed arc. 

Reinforced plastics, particularly laminates, are anisotropic (i.e., their properties differ depending on the direction of measurement). For example, a laminate made of fabric has physical properties controlled by the weave of the fabric and the number and density of the threads in the warp and fill directions. Both of these values are different from the values of the z or thickness direction. This is clearly evident in the shear properties. Thermal expansion and thermal conductivity properties are also anisotropic, hi the x, y, and z planes of the laminate, the thermal expansion values differ. Even the reinforcing fibers themselves may have anisotropic properties. 

Mechanical Machining Methods. The inherent pliability and shear properties of plastics, particularly of thermoplastics, makes them highly amenable to shaping with traditional tools such as saws, drills, planes, shapers, lathes, sanders, and millers. The materials are easily cut by steel tools, which are harder than any plastic. For this reason, mock-up designs are often initially constructed as plastic models rather than as metal constructs, allowing design engineers to test various physical properties, such as aerodynamic stability and wind resistance, that are directly related only to the shape of the structure and not to the materials used. 

D 4274 DETERMINATION OF HYDROXYL IN POLYOLS D 4321 DETERMINATION OF PACKAGE YIELD D 4385 CLASSIFYING VISUAL DEFECTS PULTRUDEDS D 4475 HORIZONTAL SHEAR OF PLASTIC RODS D 4476 FLEXURAL PROPERTIES PULTRUDED RODS D 4508 CHIP IMPACT... 

If, however, the stress applied to the solid exceeds its elastic limit, the response is plastic deformation. This deformation persists when the stress is removed, and the unstressed solid no longer has its original properties. Plastic deformation is a kind of hysteresis, and is caused by such microscopic behavior as the slipping of crystal planes past one another in a crystal subjected to shear stress, and conformational rearrangements about single bonds in a stretched macromolecular fiber. Properties of a solid under plastic deformation depend on its past history and are not unique functions of a set of independent variables an equation of state does not exist. 

One simple rheological model that is often used to describe the behavior of foams is that of a Bingham plastic. This appHes for flows over length scales sufficiently large that the foam can be reasonably considered as a continuous medium. The Bingham plastic model combines the properties of a yield stress like that of a soHd with the viscous flow of a Hquid. In simple Newtonian fluids, the shear stress T is proportional to the strain rate y, with the constant of proportionaHty being the fluid viscosity. In Bingham plastics, by contrast, the relation between stress and strain rate is r = where is... 

Mechanical properties of plastics can be determined by short, single-point quaUty control tests and longer, generally multipoint or multiple condition procedures that relate to fundamental polymer properties. Single-point tests iaclude tensile, compressive, flexural, shear, and impact properties of plastics creep, heat aging, creep mpture, and environmental stress-crackiag tests usually result ia multipoint curves or tables for comparison of the original response to post-exposure response. 

Urethanes are processed as mbber-like elastomers, cast systems, or thermoplastic elastomers. The elastomer form is mixed and processed on conventional mbber mills and internal mixers, and can be compression, transfer, or injection molded. The Hquid prepolymers are cast using automatic metered casting machines, and the thermoplastic peUets are processed like aU thermoplastic materials on traditional plastic equipment. The unique property of the urethanes is ultrahigh abrasion resistance in moderately high Shore A (75—95) durometers. In addition, tear, tensUe, and resistance to many oUs is very high. The main deficiencies of the urethanes are their resistance to heat over 100°C and that shear and sliding abrasion tend to make the polymers soft and gummy. 

A wide variety of nonnewtonian fluids are encountered industrially. They may exhibit Bingham-plastic, pseudoplastic, or dilatant behavior and may or may not be thixotropic. For design of equipment to handle or process nonnewtonian fluids, the properties must usually be measured experimentally, since no generahzed relationships exist to pi e-dicl the properties or behavior of the fluids. Details of handling nonnewtonian fluids are described completely by Skelland (Non-Newtonian Flow and Heat Transfer, Wiley, New York, 1967). The generalized shear-stress rate-of-strain relationship for nonnewtonian fluids is given as... 

Suspensions of fine sohds may have pseudoplastic or plastic-flow properties. When they are in laminar flow in a stirred vessel, motion in remote parts of the vessel where shear rates are low may become negligible or cease completely. To compensate for this behavior of slurries, large-diameter impellers or paddles are used, with (D /Df) > 0.6, where Df is the tank diameter. In some cases, for example, with some anchors, > 0.95 Df. Two or more paddles may be used in deep tanks to avoid stagnant regions in slurries. 

Australia, is the doyen of materials scientists who study the elastic and plastic properties of minerals under hydrostatic pressure and also phase stability under large shear stresses (Paterson 1973). J.-P. Poirier, in Paris, a professor of geophysics, was trained as a metallurgist one of his special skills is the use of analogue materials to help understand the behaviour of inaccessible high-pressure polymorphs, e.g., CaTi03 perovskite to stand in for (Mg, FelSiOi in the earth s mantle (Poirier 1988, Besson el al. 1996). 

The existence of yield stress Y at shear strains seems to be the most typical feature of rheological properties of highly filled polymers. A formal meaing of this term is quite obvious. It means that at stresses lower than Y the material behaves like a solid, i.e. it deforms only elastically, while at stresses higher than Y, like a liquid, i.e. it can flow. At a first approximation it may be assumed that the material is not deformed at all, if stresses are lower than Y. In this sense, filled polymers behave as visco-plastic media with a low-molecular and low-viscosity dispersion medium. This analogy is not random as will be stressed below when the values of the yield stress are compared for the systems with different dispersion media. The existence of yield stress in its physical meaning must be correlated with the strength of a structure formed by the interaction between the particles of a filler. 

Rheology is the science that deals with the deformation and flow of matter under various conditions. The rheology of plastics, particularly of TPs, is complex but understandable and manageable. These materials exhibit properties that combine those of an ideal viscous liquid (with pure shear deformations) with those of an ideal elastic solid (with pure elastic deformation). Thus, plastics are said to be viscoelastic. 

Torsion property As noted, the shear modulus is usually obtained by using pendulum and oscillatory rheometer techniques. The torsional pendulum (ASTM D 2236 Dynamic Mechanical Properties of Plastics by Means of a Torsional Pendulum Test Procedure) is a popular test, since it is applicable to virtually all plastics and uses a simple specimen readily fabricated by all commercial processes or easily cut from fabricated products. 

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